Aging dynamics and e ective temperature in polymers and gels
dissipation theorem in aging materials is presented. The fluctuation dissipation relation are measured on the dielectric properties of a gel (Laponite) and of a ...
Aging dynamics and eective temperature in polymers and gels S. Ciliberto Ecole Normale Supérieure de Lyon, Laboratoire de Physique , C.N.R.S. UMR5672, 46, Allée d'Italie, 69364 Lyon Cedex 07, France 22 juillet 2006
Résumé We rst introduce the general features of aging and several experimental aspects of the aging dynamics. We brie y describe several experimental procedures, based on the response function, which have been useful to study memory and rejuvenation eects in various materials. The experimental analysis of the violation of the uctuationdissipation theorem in aging materials is presented. The uctuation dissipation relation are measured on the dielectric properties of a gel (Laponite) and of a polymer glass (polycarbonate). For the gel it is found that during the transition from a uid-like to a solid-like state the uctuation dissipation theorem is strongly violated. The amplitude and the persistence time of this violation are decreasing functions of frequency. A very similar behavior is observed in polycarbonate after a quench below the glass transition temperature. In both cases the origin of this violation is a highly intermittent dynamics characterized by large uctuations. The relevance of these results for recent models of aging are discussed.
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