[EN] - FLUIDIRAM 742 - 2015-02-09

Feb 9, 2015 - H304 : May be fatal if swallowed and enters airways. H318 : Causes serious eye damage. H410 : Very toxic to aquatic life with long lasting ...
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SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006

Product:

Page: 1 / 8

FLUIDIRAM 742

Date 09.02.2015 (Cancel and replace : 22.09.2011)

SDS No.: 352179-005 (Version 4.0 )

1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING 1.1. Identification of the product Identification of the mixture: FLUIDIRAM 742

1.2. Relevant identified uses of the substance or mixture and uses advised against Use of the Substance/Mixture :

Anticaking agent for mineral based fertilisers.

1.3. Details of the supplier of the safety data sheet Supplier

E-mail address 1.4. Emergency telephone number

CECA Tensio-Actifs de Spécialités Adresse postale : 89 Boulevard National 92250 LA GARENNE-COLOMBES FRANCE Téléphone : +33 (0)1 49 00 38 00 Télécopie : +33 (0)1 49 00 38 01 http://www.cecachemicals.com [email protected]

+33 1 49 00 77 77 European emergency phone number : 112 (24/7) National Chemical Emergency Centre Tel: 01865 407 333 (24/7) 2. HAZARDS IDENTIFICATION 2.1. Classification of the substance or mixture Classification (REGULATION (EC) No 1272/2008): Aspiration hazard, 1, H304 Serious eye damage, 1, H318 Acute aquatic toxicity, 1, H400 Chronic aquatic toxicity, 2, H411 Classification according to EU Directives 1999/45/EC :

N; R50/53 Xn; R65 Additional information: For the full text of the R, H, EUH-phrases mentioned in this Section, see Section 16.

2.2. Label elements Label elements (REGULATION (EC) No 1272/2008): Hazardous components which must be listed on the label: Distillates (petroleum), solvent-dewaxed heavy paraffinic; Baseoil -- unspecified amines, hydrogenated tallow alkyl

Hazard pictograms:

Signal word:

Danger

CECA SA Quick-FDS [17208-54883-03729-011442] - 2015-02-10 - 15:14:43

89 Boulevard National - 92250 LA GARENNE-COLOMBES - FRANCE

Product: SDS No.: 352179-005 (Version 4.0 )

Page: 2 / 8 Date 09.02.2015 (Cancel and replace : 22.09.2011)

FLUIDIRAM 742

Hazard statements: H304 : May be fatal if swallowed and enters airways. H318 : Causes serious eye damage. H410 : Very toxic to aquatic life with long lasting effects.

Precautionary statements: Prevention: P273 : Avoid release to the environment. P280 : Wear protective gloves/ protective clothing/ eye protection/ face protection. Response: P305 + P351 + P338 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 : Immediately call a POISON CENTER or doctor/ physician. P331 : Do NOT induce vomiting. Disposal: P501 : Dispose of contents/ container to an approved incineration plant.

2.3. Other hazards

Physical and chemical hazards: No special risks of flammability or explosion.

3. COMPOSITION/INFORMATION ON INGREDIENTS 3.2. Mixtures 1

Chemical nature of the mixture : Preparation based on fatty amines derivatives. Hazardous components (according to Regulation (EC) No. 1907/2006) : 1

2

Chemical Name & REACH Registration Number

Distillates (petroleum), solvent-dewaxed heavy paraffinic (N° ANNEX: 649-474-00-6)

EC-No.

CAS-No.

Concentration

265-169-7

64742-650

> 50 %



68551-291

1.000 mg/l No effect up to the limit of solubility ALKYLAMINES : NOEC, 96 h (Algae) : 0,008 mg/l (Method: OECD Test Guideline 201) Aquatic toxicity / Long term toxicity: Fish: DISTILLATES (PETROLEUM), SOLVENT-DEWAXED HEAVY PARAFFINIC : NOEC, 7 d (Pimephales promelas (fathead minnow)) : > 5.000 mg/l Aquatic invertebrates: DISTILLATES (PETROLEUM), SOLVENT-DEWAXED HEAVY PARAFFINIC : NOEC, 21 d (Daphnia magna (Water flea)) : > 1.000 mg/l (Method: OECD Test Guideline 202 - Part 2, Reproduction inhibition) ALKYLAMINES : NOEC, 21 d (Daphnia (water flea)) : 0,013 mg/l (Method: OECD Test Guideline 211, reproduction) 12.2. Persistence and degradability :

Biodegradation (In water):

Based on the available information, it is not possible to conclude on the hasard potential of this mixture.

DISTILLATES (PETROLEUM), SOLVENT-DEWAXED HEAVY PARAFFINIC : Not readily biodegradable. 6 % after 28 d (Method: OECD Test Guideline 301 B) ALKYLAMINE DERIVATIVES : Readily biodegradable ALKYLAMINES :

CECA SA Quick-FDS [17208-54883-03729-011442] - 2015-02-10 - 15:14:43

89 Boulevard National - 92250 LA GARENNE-COLOMBES - FRANCE

Product: SDS No.: 352179-005 (Version 4.0 )

Page: 7 / 8 Date 09.02.2015 (Cancel and replace : 22.09.2011)

FLUIDIRAM 742

Readily biodegradable

12.3. Bioaccumulative potential : Bioaccumulation:

Based on the available information, it is not possible to conclude on the hasard potential of this mixture.

ALKYLAMINES : Bioconcentration factor (BCF): 173 12.4. Mobility in soil - Distribution among environmental compartments: No data available. 12.5. Results of PBT and vPvB assessment : None.

12.6. Other adverse effects:

Global warming potential (GWP):

Not relevant (due to the chemical structure)

Ozone depletion potential:

Not relevant (due to the chemical structure)

13. DISPOSAL CONSIDERATIONS 13.1. Waste treatment: Disposal of product:

The product should not be allowed to enter drains, water courses or the soil. Incinerate in suitable incineration plant, observing local authority regulations.

Disposal of packaging:

Must be dumped or incinerated in accordance with local regulations. According to the European Waste Catalogue, Waste Codes are not product specific, but application specific. Waste codes should be assigned by the user based on the application for which the product was used.

14. TRANSPORT INFORMATION

Regulation

UN number

ADR

3082

ADN

3082

RID

3082

IATA Cargo

3082

IATA Passenger

3082

IMDG

3082

Proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.(Alkylamines derivatives) ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Alkylamines derivatives) ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. Environmentally hazardous substance, liquid, n.o.s. (Alkylamines derivatives) Environmentally hazardous substance, liquid, n.o.s. (Alkylamines derivatives) ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Alkylamines derivatives)

Environmentally hazardous

Class

Label

PG

9

9

III

9

9

III

yes

9

9

III

yes

9

9MI

III

yes

9

9MI

III

yes

9

9

III

Marine pollutant(Alkyla mines derivatives)

Other information

yes

EmS Number: F-A, S-F Mark: MP

15. REGULATORY INFORMATION Safety data sheets: according to Regulation (EC) No. 1907/2006 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture: Listed in: EU. REACH, Annex XVII, Marketing and Use Restrictions (Regulation 1907/2006/EC): Distillates (petroleum), solvent-refined heavy paraffinic; Baseoil -- unspecified: Distillates (petroleum), solvent-dewaxed heavy paraffinic; Baseoil -- unspecified: Lubricating oils; Baseoil -- unspecified EU. REACH, Annex XVII, Appendix 2, Entry 28 - Carcinogens: Category 1B (Table 3.1)/Category 2 (Table 3.2). (Regulation 1907/2006/EC): Distillates (petroleum), solvent-refined heavy paraffinic; Baseoil -- unspecified: Distillates (petroleum), solvent-dewaxed heavy paraffinic; Baseoil -- unspecified: Lubricating oils; Baseoil -- unspecified UK REGULATION Chip3: Chemical (Hazard Information and Packaging for Supply) Regulations 2002

CECA SA Quick-FDS [17208-54883-03729-011442] - 2015-02-10 - 15:14:43

89 Boulevard National - 92250 LA GARENNE-COLOMBES - FRANCE

Product: SDS No.: 352179-005 (Version 4.0 )

FLUIDIRAM 742

Page: 8 / 8 Date 09.02.2015 (Cancel and replace : 22.09.2011)

15.2. Chemical Safety Assessment: None.

16. OTHER INFORMATION

Full text of R, H, EUH-phrases referred to under sections 2 and 3 R38 R41 R48/22 R50 R50/53 R53 R65 H304 H315 H318 H373 H400 H410 H411

Irritating to skin. Risk of serious damage to eyes. Harmful: danger of serious damage to health by prolonged exposure if swallowed. Very toxic to aquatic organisms. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. May cause long-term adverse effects in the aquatic environment. Harmful: may cause lung damage if swallowed. May be fatal if swallowed and enters airways. Causes skin irritation. Causes serious eye damage. May cause damage to organs through prolonged or repeated exposure if swallowed. Very toxic to aquatic life. Very toxic to aquatic life with long lasting effects. Toxic to aquatic life with long lasting effects.

Update: Safety datasheet sections which have been updated: 2 2. HAZARDS IDENTIFICATION 3 3. COMPOSITION/INFORMATION ON INGREDIENTS 4 4. FIRST AID MEASURES 5 5. FIREFIGHTING MEASURES 6 6. ACCIDENTAL RELEASE MEASURES 7 7. HANDLING AND STORAGE 8 8. EXPOSURE CONTROLS/PERSONAL PROTECTION 9 9. PHYSICAL AND CHEMICAL PROPERTIES 10 10. STABILITY AND REACTIVITY 11 11. TOXICOLOGICAL INFORMATION 12 12. ECOLOGICAL INFORMATION 13 13. DISPOSAL CONSIDERATIONS 15 15. REGULATORY INFORMATION

Type: Revisions Revisions Revisions Revisions Revisions Revisions Revisions Revisions Revisions Revisions Revisions Revisions Revisions

Thesaurus: NOAEL : No Observed Adverse Effect Level (NOAEL) LOAEL : Lowest Observed Adverse Effect Level (LOAEL) bw : Body weight food : oral feed dw : Dry weight vPvB : very Persistent and very Bioaccumulative PBT : Persistent, Bioaccumulative and Toxic

This safety data sheet complies with international standard ISO 11014-1. In case of formulations or mixtures, it is necessary to ascertain that a new danger will not appear. The information contained is based on our knowledge of the product, at the date of publishing and it is given quite sincerely. Users are advised of possible additional hazards when the product is used in applications for which it was not intended. This sheet shall only be used and reproduced for prevention and security purposes. The references to legislative, regulatory and codes of practice documents cannot be considered as exhaustive. It is the responsibility of the person receiving the product to refer to the totality of the official documents concerning the use, the possession and the handling of the product. It is also the responsibility of the handlers of the product to pass on to any subsequent persons who will come into contact with the product (usage, storage, cleaning of containers, other processes) the totality of the information contained within this safety data sheet and necessary for safety at work, the protection of health and the protection of environment. NB: In this document the numerical separator of the thousands is the "." (point), the decimal separator is "," (comma).

CECA SA Quick-FDS [17208-54883-03729-011442] - 2015-02-10 - 15:14:43

89 Boulevard National - 92250 LA GARENNE-COLOMBES - FRANCE