MK Lindemann Consultant, Greenvile, SC, USA .fr

G. M. Kline, Analytical Chemistry of Polymers, Part III,. Interscience, New York ... W. Schnabel, in: "Polymer Degradation - Principles and. Practical Applications" ...
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Physical Constants of Poly(vinyl acetate) M. K. Ln idemann Consua tln,t Greenve li, SC, USA

Property Absorption of Water (%)

Adhesive Strength Lap shear (Mpa) Peel strength (N/cm) Chain Dimensions and Entanglement Spacings Cohesive Energy (J/mol) Cohesive Energy Density (J/cm3) Compressibility (cm3/g/atm) Isothermal (bar"1) ( x 10~5) At80°C At 100°C At 120°C

Value Approx. 3-6 4 6

At 200C for 24 to 144 h At 23°C At 700C

3.9 1.9

Aluminum Aluminum

See Refs. 26000-36000 3.69 x 102 1.8 x 10 ~5

Density (Mg/m3) = (g/cm3) At 200C At25°C At 500C At 1200C At 200°C At the melting point At 7=35-100°C A t T = - 3 0 to +20 0 C As a function of pressure

In the glassy state

6.2 6.6 7.1

Decomposition Temperature (0C) Degradation, Thermal

Remarks

Refs. 26 65,66

130 144-146 52 58 1 113

150 Tl/2 = 269°C; £act = 7 * kJ/mol; monomer yield: none

15 Temperature at which the polymer loses 50% of its weight, if heated in vacuum for 30 min

1.191 1.19 1.17 1.11 1.05 1.28 1.2124-8.62 x 10~4 7 + 0.223 x 10~6 T2 1.196-3.37 x 10" 4 T See Refs.

52

16,24,26

58 113 113 113,114,115 At 500C and 2 x 103 kHz At 1500C and 2 x 103 kHz

Of oligo PVAC As a function of MW

3.5 8.3 See Ref. See Ref.

Dielectric Dissipation Factor (tan 6)

1.5 x 102

At 50°C and 2 x 103 kHz

26 x 102

At 1200C and 2 x 103 kHz

Dielectric Loss Versus Frequency

See Ref.

At various temperatures

95

Dielectric Strength (V/cm) ( x 10 ~3)

394 307

At 300C At 600C

16

Dielectric Constant

34 59 96 34

Property

Value

Remarks

Refs.

Dielectric Relaxation Parameters

See Refs.

Dipole Moment (ESU (per monomer unit))

2.3 x 10 ~18 1.77 x 10"18

At 200C At 15O0C

4.8 D

For oligo PVAC, n = 5

59

Dynamic Mechanical Loss Peak ( C)

70

At 100 Hz

33

Elongation At Break (%)

10-20

At 200C, %RH

27

Gas Diffusivity Gas Permeability

See Ref. See Refs.

N 2 for PVAC below 7g(cm2/s/bar) N 2 for PVAC above Tg O2,73°dry film

6 x 10" 10 5 x 10- 10 2.7 x 10~9

For N 2 , O 2 , CO 2 , H 2 Diffusion and sorption of CO 2 (below and above 7 g )

Gas Solubility (cm3(STP)/cm3 bar)

N2 O2 H2

Gel Permeation Chromatography

See Refs.

(debye units) 0

Gel Properties Swelling pressure, elastic modulus and shear modulus parameters of PVAC networks in toluene and acetone Glass Transition Temperature (0C)

Pressure dependence (K/bar) As a function of MW Activation energy for the glass transition (J/mol)

121-129 22,23

52 53,94 52 100

0.02 0.04 0.023

At 298 K

Universal calibration

See Ref.

52

90,91,92 166

28-31 25.8 31.4 23.6 34-39 100

Molar Volume At 250C (cm3/mol)

74.25

Nuclear Magnetic Resonance Spectra Shift with Eu and Pr reagents, improved resolution Solvent and temperature effects Conformational information

See Refs. See Ref. See Ref. See Ref.

Remarks

Refs.

(dn/dc)

52

39,102,131,132 133 69

At 200C, with polyethylene At 200C, with poly(dimethylsiloxane) At 200C, with polyisobutene At 200C, with polystyrene With polyethylene Linear PVAC with polyethylene Branched PVAC with polyethylene

70 120 9 11 9 11 101 101 101

6,29,30

40-51,77 136-139 73 74 134,135

ASTM-D256

27 52 27 99 36,81,82 78

Syndiotactic PVAC

79 80

Optical Configuration Parameters (Aa) (A3) Acetone Benzene Bromobenzene Bromoform Carbon tetrachloride Carbon tetrachloride Chlorobenzene Chloroform Chloroform Cyclohexane Dichloroethane Dichloroethane Tetrabromoethane

- 20 4.0-5.9 9.4 - 20 -16 - 26 14 -34.9 -24 -23 -36 -39 -25

Wavelength of 6328 A

106 107 108 106 107 109 107 109 107 107 107 107 107

References page V- 83

Property

Value

Tetrabromoethane Toluene Toluene Toluene o-Xylene Chloroform Chloroform 1,3,5-Triethylbenzene /.-Radiation Effect Yields of crosslinking Yields of scission Raman Spectra

Remarks

- 33 10 13.5 19 2.0 81 - 2.68 -1.90

Temp. 500C; v2 = 1.0° Temp. 500C ; v2 = 0.6"

0.3 0.15 0.07 0.06

Oxygen atmosphere Nitrogen atmosphere Oxygen atmosphere Nitrogen atmosphere

See Ref. 0

Softening Temperature ( C)

106 107 112 109 107 107 110,111 110,111 164 165 37

35-50

7

Solubility

See Ref.

Solubility Parameter (5(MPa) 1Z2) At25°C At 500C At 125°C Sd i 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 0 0 1 1 0 1 0 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 0 1 1 0.4-0.8 1

Interaction parameter, z 0.51 0.95-0.88 1.90-1.75 0.85-0.63 0.28-0.33 0.73-0.66 20.17-20.09 0.25 0.82 0.75 1.63 1.65-1.16 1.18 0.44 1.67 1.53 1.65-1.50 2.5-2.01 0.81 0.19 20.04-0.00 20.14 0.400 0.407 0.17-0.03 2.48-2.27 0.47 0.80 0.415 0.36 0.66-0.58 2.14-1.63 0.55 2.99 2.06-1.71 0.49 0.66 0.77-0.73 0.30 0.30 0.14-0.19 2.38-1.88 2.3-1.94 0.65 1.55 2.06 0.59-0.41 0.38 3.2 1.3-1.0 0.64-0.38 0.44-0.35 0.42 0.61 2.70 0.30-0.14 0.83-0.77 1.72-1.56 0.56-0.40 0.49 0.40 0.38 2.17-1.86 2.7-2.14 0.41-0.22 2.5

Refs. 148 160 160 148,149,158 148,149 148,149 148,149,158 148 148 154 148 148,149,150,158,160 148 149,159 148 148 160 148,149,159,160 159 148 148,150 148 151 151 148,150 159,160 157 148 162 148 148,159 148,150,158 159 159 148,158 159 154 150 148 159 150 148,149,159,160 148,158 159 149 148 148,159 149 148 154 148,159 150,159 148 154 159 148,150 160 160 148,150,158,159 148 148 151 158 148,159,160 156 161

References page V- 83

Property

Value

Specific Heat Conformational (dEcont/dT)

Remarks

See also Heat Capacity 1.3 1.8

Softening Point As a function of MW

Refs.

Syndiotactic Isotactic

85

See Refs.

116,117,118 4

Specific Volume (I/kg)

(1/mol) Stress Relaxation Curves Surface Resistance (ft/cm)

0.823 + 6.4 x 10~ x T 0.84 1.073 0.841 0.08774

T= 100-200 C At Tg Monomer Polymer One mole repeating unit

9,13 19,61 77

See Ref.

22-61.8°C

20,97

5 x 10~

Surface Tension (mN/m) At 200C At 1400C At 180°C At 150°C

0

103

n

15 9,10,11,12,86

36.5 28.6 25.9 27.9 - d 7 /d7 = 0.066 (mN/m) 7 ds = 27.4 ± 0.1 7 d s = 15.4 ±0.7 Tsoiid = 42.85 ± 0.8

58,87,101 58,119 85

Dispersive Polar Total

Tensile Strength (MPa) = (N/mm2)

29.4-49.0 See Table in Ref.

Thermal Conductivity (W/m/K) Pressure and temperature dependence

0.159 See Ref. 0.159

16 88 116

2.8 XlO" 4 2.8 XlO- 4 7.13 x 10 ~4 7.17 x l O ~ 4 7.2OxIO- 4 7.23 XlO" 4 6.7 XlO- 4 22 x 10 " 5 7 xlO-5

113

Thermal Expansion Coefficient (K" 1 ) AtO0C At 20 0C At 40 0C At 60 0C At 80 0C AtIOO 0 C Cubic Linear above Tg Below 7 g

At 20°C

16 96

15,25 17,27

Theta Temperatures

Polymer Poly (vinyl acetate) Linear

4

Mw(xl0 )

Dispersity

87-346

2.7-126.8

2.0

4.1-83 0.35-150 3.0-32

0.8-130 Branched

1.02-1.05

Solvent (MJMn) Methyl isopropyl ketoneM-heptane (73.2/26.8) rc-heptane/methyl isopropyl ketone (27.3/72.7) Ethyl n-butyl ketone Ethyl isoamyl ketone Methanol Ethyl /i-butyl ketone Carbon tetrachloride Ethanol 3-Heptanone Cetyl alcohol Ethanol 3-Heptanone

0 Temp. (0C)

K0 (x 104) [dl/g (g mol w t ) 1 / 2 ]

25

Refs. 151

30

9.2

152

29 66 6 29 46.4 19 29 123 12-15 26

9.29 8.20 10.1 9.55

153 154 155 163

5.37

156 163

Property

Value

Remarks

Ultraviolet Radiation ^(nm) Absorption, cut-off Quantum yields (mol/Einstein) (in air) at A = 254 Acetic acid formation Carbon dioxide formation Carbon monoxide formation Methane formation Chain scission Crosslinking

0.01 0.0065 0.0069 0.0038 0.05 (in air), 0.066 (in nitrogen) 0.0025 (in air), 0.047 (in nitrogen)

Ultraviolet Spectra

See Ref.

Young's Modulus (MPa) = (N/mm2)

600

Viscoelastic Response

See Refs.

X-Ray Diffraction

See Ref.

a

240

Refs. 142 143

30,38 At 25°C and 50% RH

8 167-171

Wide angle

98

Polymer volume fraction.

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