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TABLE 1. cont'd Monomer 1 Styrene, p-4-methoxyphenyl ketone Styrene, p-WV-dimethylaminoStyrene, p-WV-dimethylaminoStyrene, p-WV-dimethylaminoStyrene, p-AW-dimethylaminomethylStyrene, p-acetoxyStyrene,/7-acetoxyStyrene, p-acetoxyStyrene, p-aminoStyrene, p-aminoStyrene, p-aminoStyrene, p-bromoStyrene, p-bromoStyrene, p-bromoStyrene, p-bromoStyrene, p-bromoStyrene, p-bromoStyrene, p-bromoStyrene, /?-chloroStyrene, p-chloroStyrene, p-chloroStyrene,/7-chloroStyrene, p-chloroStyrene, p-chloroStyrene,/7-chloroStyrene,/7-chloroStyrene,/7-chloroStyrene,/?-chloroStyrene, /7-chloroStyrene, /7-chloroStyrene,/7-chloroStyrene, p-chloroStyrene,/7-chloroStyrene,/7-chloroStyrene,/?-chloroStyrene,/7-chloroStyrene,/7-chloroStyrene,/7-chloroStyrene,/7-chloroStyrene,/7-chloroStyrene, p-chloroStyrene, p-chloroStyrene, p-chloroStyrene, p-chloroStyrene, p-chloroStyrene, p-chloroStyrene, p-chloroStyrene, p-chloroStyrene, p-chloroStyrene, p-chloromethylStyrene, p-chloromethylStyrene, p-chloromethylStyrene, p-chloromethylStyrene, p-chloromethylStyrene, p-chloromethylStyrene, p-chloromethylStyrene, p-chloromethylStyrene, p-chloromethylStyrene, p-cyanoStyrene, p-cyanoStyrene, p-cyanoStyrene, p-cyanoStyrene, p-cyanoStyrene, p-decylStyrene, p-diethylaminoethyl-
Monomer 2 Styrene Acrylate, methyl Benzophenone, p-vinylMethacrylate, methyl Benzophenone, p-vinyl Acrylonitrile Styrene Styrene Styrene Styrene Styrene, m-aminoMethacrylate, methyl Styrene Styrene Styrene Styrene Styrene Styrene, p-methoxyAcrylate, a-trifluoromethyl-, methyl Acrylonitrile, a-trifluoromethylButadiene Butadiene, l-(2-hydroxyethylthio)Carbazole, Af-vinylCyclopentene, 4-,-1,3-dione Itaconate, dimethyl Methacrylate, butyl Methacrylate, butyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Norbornadiene Styrene Styrene Styrene Styrene Styrene Styrene Styrene Styrene, 2,4,6-trimethylStyrene, a-methylStyrene, m-nitroStyrene, p-l-(2-hydroxypropyl)Styrene, p-2-(2-hydroxypropyl)Styrene, p-cyanoStyrene, p-methoxyStyrene, p-methoxyStyrene, p-methylVinyl methyl sulfoxide Vinyl, p-, benzylmethylcarbinol Acrylonitrile Butadiene Methacrylate, butyl Methacrylate, ethyl Methacrylate, methyl Phosphazene, isopropenylpentafluoroStyrene Styrene Styrene Methacrylate, methyl Styrene Styrene Styrene, p-chloro Styrene, p-methoxyStyrene Styrene
r\ 1.85 0.38 0.07 0.101 0.26 0.4 1.305 1.218 0.22 1.07 0.49 1.1 1.05 1.1 0.99 1.05 1 1.15 0.24 0.92 1.6 0.24 7 0.294 0.69 1.036 1.025 0.77 0.89 0.47 69.93 1.08 1.029 1.062 1.03 0.76 1.76 1.02 17.83 1.56 0.3 0.91 1.24 0.26 0.47 0.86 1.15 6.46 1 0.56 0.42 1.46 1.29 0.91 1.64 1.12 1.12 1.66 1.41 1.22 1.16 1.28 0.89 0.26 0.59
±95% 0.93 0.16 0.05 0.016 0.017 0.03 0.05 0.069 0.004 0.07 0.05 0.11 0.08 0.02 0.06 5.7 0.081 0.1 0.124 0.12 24.19 0.07 0.056 0.014 0.12 5.24 0.42 0.14 0.08 0.16
0.15 0.58 0.17 0.2 0.46 0.11 0.13 0.03 1.32 0.19
r2 0.423 0.06 0.84 0.204 2.54 0.07 0.835 0.887 0.41 0.876 0.63 0.4 0.7 0.67 0.71 0.71 0.69 0.44 0 - 0.09 1.22 3.27 0.02 0.014 0.15 0.517 0.564 0.334 0.42 0.43 0 0.62 0.744 0.816 0.74 0.39 0.76 0.74 0.34 0.21 1.73 0.63 0.53 1.28 0.41 0.56 0.61 0.01 1 0.067 0.87 0.38 0.36 0.408 -0.048 0.622 0.62 0.6 0.22 0.24 0.28 0.26 0.14 0.88 1.12
±95%
Conv.
0.071 0.01 0.18 0.022 0.136 0.01 0.029 0.034
Y Y Y Y N
0.007
Y
0.03 0.09 0.14
N N Y
0.02 0.03 0.06 2.16
N N N Y
0.006
Y
0.1 0.131 0.016
N
0.12 0.1 0.08 0.029
Y N Y Y
0.043
Y
1.05 0.2 0.47
Y Y Y
0.13 0.08
N N
Y
Y
0.038 0.067 0.047 0.15 0.3
Y Y Y
0.07
N
0.08 0.05 0.22 0.19
N N
Refs. 806 866 866 256 86 47 806 806 775 989 774 256 125 128 256 447 554 128 825 825 255 810 551 264 398 872 966 150 256 476 188 128 139 139 140 150 523 554 58 218 222 380 547 128 128 256 256 737 48 1035 1075 1035 1035 756 765 756 806 806 256 128 256 128 128 806 806
TABLE 1. cont'd Monomer 1 Styrene,/7-dimethylaminoStyrene, /7-dimethylaminoStyrene,/7-dimethylaminomethylStyrene,/7-ethoxyStyrene, p-fluoroStyrene, /7-fluoromethylStyrene,/7-formylStyrene,/7-formylStyrene, /7-iodoStyrene,/7-iodoStyrene,/7-mercaptoStyrene, /7-methoxyStyrene, /7-methoxy Styrene,/7-methoxy Styrene,/7-methoxy Styrene,/?-methoxy Styrene, p-methoxy Styrene, /7-methoxy Styrene,/7-methoxy Styrene,/7-methoxy Styrene,/7-methoxy Styrene, /7-methoxy Styrene,/7-methoxy Styrene,/7-methyl Styrene,/7-methyl Styrene, /7-methyl Styrene,/7-methyl Styrene,/7-methyl Styrene,/?-methyl Styrene, p-methyl Styrene, p-nitro Styrene,/7-octylamine sulfonate Styrene,/7-octylamine sulfonate Styrene,/?-octylamine sulfonate Styrene,/7-octylamine sulfonate Styrene, p-sulfonic acid fluoride Styrene, p-tert-buty\Styrene, p-tert-buty\Styrene, p-trimethoxysilylStyrene,/7-trimethylsilylStyrene, pentachloroStyrene, pentachloroStyrene, pentachloroStyrene, tert-butoxyStyrenesulfonate,/7-, sodium Styrenesulfonate, p-, sodium Styrenesulfonate,/?-, sodium Styrenesulfonate,/?-, sodium Succinamate, potassium TV-vinylSuccinimide, TV-vinylSuccinimide, TV-vinylSuccinimide, TV-vinylSuccinimide, TV-vinylSuccinimide, TV-vinylSuccinimide, TV-vinylSuccinimide, TV-vinylSuccinimide, TV-vinylSuccinimide, N-vinylSuccinimide, TV-vinylSuccinimide, TV-vinylSuccinimide, TV-vinylSuccinimide, TV-vinylSuccinimide, N-vinylSuccinimide, N-vinylSuccinimide, TV-vinyl-
Monomer 2 Acrylate, methyl Benzophenone, p-vinylBenzophenone,/?-vinylStyrene Myrcene Styrene Styrene Styrene Styrene Styrene Styrene Acrylate, methyl Methacrylate, methyl Styrene Styrene Styrene Styrene Styrene; m-bromoStyrene, m-chloroStyrene, /7-bromoStyrene,/?-chloroStyrene, /7-chloroStyrene,/?-cyanoAcrylate, methyl Acrylonitrile Methacrylate, methyl TV,TV-Divinylaniline Styrene Styrene,/?-chloroVinyl methyl sulfoxide Styrene Acrylate, butyl Methacrylate, butyl Methacrylate, methyl Styrene Styrene Methacrylate, methyl Styrene Imidazole, TV-vinylStyrene Methacrylate, methyl Styrene Vinyl chloride Fumarate, dibutyl Acrolein Acrolein Acrolein Acrylate, oc-chloro-, sodium Methacrylate, methyl Acrylamide Acrylate, butyl Acrylate, methyl Acrylonitrile Carbazole, N-vinylMaleate, dimethyl Maleic anhydride Methacrylate, methyl Methacrylate, methyl Pyrrolidone, TV-vinylStyrene Styrene Styrene Styrene Vinyl acetate Vinyl acetate
rx 0.372 0.176 0.135 0.71 0.362 1.399 3 1.43 1.044 0.965 0.907 2 0.32 0.69 1.01 0.82 0.79 0.25 0.2 0.44 0.41 0.56 0.14 1.54 0.33 0.44 6.15 0.993 0.61 2.73 1.13 2.3 1.5 2.6 2.7 1.372 0.5 1.581 6.9 1.15 0.3 0.07 5.3 0.18 0.047 0.327 0.01 1.44 -0.02 0.17 0.15 0.9 0.516 0.11 1.25 0.148 0.048 -0.059 3.67 0.045 0.045 0.01 7 5.68 4.49
±95% 0.055 0.046 0.017 0.14 0.022 0.236
0.159 0.124 0.223
0.1 1.27
0.02 0.08 0.05
0.16 0.028
0.13
0.188 0.342 0.72 0.05 0.1
0.071 0.033 0.009 0.31 0.12
0.17 0.081 0.83 0.16 0.073 0.026 0.096 0.89 0.036 0.072 0.23 1.6 0.12 9.49
r2 0.192 0.842 2.54 0.98 0.87 0.474 0.2 0.16 0.485 0.629 0.607 0.07 0.29 0.85 1.14 1.16 1.05 1.4 1.9 1.15 0.47 0.86 0.89 0.17 0.05 0.4 0.06 0.891 1.15 0.01 0.193 0.3 0.7 0.6 0.7 0.171 0.44 0.774 0.002 1.26 3.65 1.33 0.43 0.01 0.26 0.395 0.113 0.27 1.1 1.86 1.54 0.357 0.116 0.04 -0.012 0.021 9.94 0.01 0.97 10.74 10.09 2.31 0.052 0.072 0.18
±95% 0.01 0.072 0.259 0.19 0.143 0.151
Conv.
Refs.
Y Y Y
911 911 911 806 1062 806 1025 956 806 839 806 558 35 128 160 256 535 168 168 128 128 256 128 558 378 256 45 261 256 737 256 817 817 817 817 806 634 806 1095 806 7 7 516 1077 57 57 57 834 771 600 789 80 80 284 284 284 104 693 96 104 163 693 80 104 167
Y
0.093 0.039 0.188
Y
0.19 0.6
N N
0.08 0.16
N N
0.03
N
0.03 0.086
Y Y
0.092
Y
0.045 0.126 0.47 0.85 0.19
N N
0.16 0.092 0.018 0.06 0.17
Y Y Y Y Y
0.063 0.024 0.09 0.021 0.027 0.27 0.031 0.42 0.49 0.46 0.98 0.32 0.009 0.54
Y Y Y Y Y Y Y N Y Y Y Y Y Y
References page II - 290
TABLE 1. cont'd Monomer 1 Succinimide, N-vinylSuccinimide, N-vinylSuccinimide, N-vinylSulfonate, 2-acrylamido2-methylpropane-, sodium Sulfonic acid, o-methacryloylaminobenzeneSulfonic acid, o-methacryloylaminobenzeneSulfonic acid, o-methacryloylaminobenzeneSulfonic acid,/?-methacryloylaminobenzeneSulfonic acid,/7-methacryloylamino benzeneSulfonic acid, /?-methacryloylamino benzeneTerpyridinyM'-vinyl^'tf'^''Tetrazole, 1-vinylTetrazole, 1-vinylTetrazole, 1-vinylTetrazole, 2-methyl-5-(4/-vinyl)phenylTetrazole, 2-methyl-5-(4/-vinyl)phenylTetrazole, 2-methyl-5-(4/-vinyl)phenylTetrazole, 2-methyl-5-vinylTetrazole, 2-methyl-5-vinylTetrazole, 2-methyl-5-vinylTetrazole, 2-phenyl-5-(4/-vinyl)phenylTetrazole, 2-phenyl-5-(4/-vinyl)phenylTetrazole, 2-phenyl-5-(4'-vinyl)phenylTetrazole, 2-phenyl-5-(4/-vinyl)phenylTetrazole, 2-phenyl-5-(4 '-vinyl)phenylTetrazole, 2-phenyl-5-(4/-vinyl)phenylTetrazole, 5-vinylTetrazole, 5-vinylThioindigoid Thiophene, 3-vinyl Thiophene, 3-vinyl Thioxanthone, 2-(acryloyloxy)Titanium, dicylopentadienyl-, dimethacrylate Titanium, dicylopentadienyl-, dimethacrylate Toluenesulfonamide, A^V-methyl-vinylToluenesulfonamide, AW-methyl-vinylToluenesulfonamide, WV-methyl-vinylToluenesulfonamide, AW-methyl-vinylTriallyl citrate Triallyl citrate Triallyl citrate Triallyl citrate Triallyl citrate Triallyl cyanurate Triallyl cyanurate Triallyl cyanurate Triallyl isocyanurate Triallyl isocyanurate Triallyl isocyanurate Triazine, 4,6-diamino-2-vinylTriazine, l,3,5-2-amino-4-(A^-methylp-aminoanilino)-6-isopropenylTriazine, l,3,5-2-amino-4-(N-methyl/?-aminoanilino)-6-isopropenylTriazine, 1,3,5-2-amino4-(p-nitroanilino)-6-isopropenyl-
Monomer 2
r\
±95%
r2
±95%
Conv.
Refs.
Vinyl acetate Vinyl thiolacetate Vinylidene chloride Acrylamide, AW-dimethyl-
1.99 0.17 0.311 0.162
0.43 0.15 0.058 0.949
0.229 2.47 1.441 1.108
0.06 0.37 0.061 0.59
Y N Y Y
80 97 104 857
Methacrylic acid
0.217
0.122
0.203
0.067
Y
1006
Methacrylic acid
0.523
0.195
0.188
0.076
Y
1006
Pyridine, 2-methyl-5-vinyl-
1.83
0.218
-0.002
0.031
Y
1006
Methacrylic acid
1.08
0.338
0.156
0.081
Y
1006
Methacrylic acid
1.65
0.27
0.155
0.052
Y
1006
Pyridine, 2-methyl-5-vinyl-
2.72
0.525
- 0.054
0.048
Y
1006
1.26 0.314 0.262 0.184 1.1 1.3 1.9 0.486 0.62 28.51 0.4 1 1.8 1.4 2.2 1.9 0.31 0.31 0.5 0.499 0.25 0.5 0.89
0.33 0.066 0.026 0.031
0.53 0.54 7.13 3.85 0.42 0.65 0.13 1.026 1.124 0.04 0.7 0.95 0.25 0.32 0.48 0.11 0.78 0.78 11.5 0.386 0.563 1.36 1.09
0.384 0.032 0.093 0.045
N Y Y Y
0.029 0.081 0.16
Y Y Y
953 925 925 925 583 583 583 670 670 670 583 583 583 583 583 583 870 902 1007 1000 1000 986 895
Styrene Acrylonitrile Methacrylate, methyl Styrene Acrylonitrile Styrene Vinylidene chloride Methacrylate, methyl Styrene Vinyl acetate Methacrylate, methyl Styrene Vinylidene chloride Acrylonitrile Styrene Vinylidene chloride Styrene Styrene Methacrylate, butyl Acrylate, butyl Methacrylate, methyl Methacrylate, methyl Copper diacrylate Nickel diacrylate Acrylonitrile Methacrylate methyl Styrene Vinyl butyl ether Acrylonitrile Allylbenzene Styrene Vinyl acetate Vinyl chloride Methacrylate, methyl Styrene Vinyl acetate Methacrylate, methyl Styrene Vinyl acetate Styrene Styrene
0.075 0.21 31.34
0.02
0.65
0.3
0.95
895
0.04 -1.83 -0.58 -0.31 -0.08 2.01 0.076 2.97 1.03 -0.005 0.22 1.29 - 0.49 -0.05 1.95 0.538 0.44
1.04 0.26 0.44 0.29 0.1 0.5 0.041 0.38 0.17 0.05 0.12 0.42 0.94 0.11 0.42 0.141 0.12
0.42 1.87 5.6 3.37 1.76 0.339 20.02 0.222 0.605 16.12 32.45 0.197 16.88 28.6 0.278 1.104 0.306
0.12 0.19 1.13 1.65 0.082 0.039 0.81 0.025 0.033 0.56 1.27 0.053 6.64 1.39 0.043 0.157 0.054
Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y
80 80 80 80 367 367 367 367 367 201 201 201 201 201 201 806 364
Styrene
1.676
0.065
0.169
0.013
Y
364
Styrene
0.91
0.18
0.257
0.062
Y
364
TABLE 1. cont'd Monomer 1 Triazine, 2-allyloxy-4,6-dichloroTriazine, 4,6-diamino-2-vinylTriazole, 1,2,3-, l-/?-bromophenyl-4-vinylTriazole, 1,2,3-, l-p-bromophenyl-4-vinylTriazole, 1,2,3-, l-p-bromophenyl-4-vinylTriazole, 1,2,3-, 4(5)-vinylTriazole, 1,2,3-, 4(5)-vinylTriazole, 1 -N- vinyl-1,2,4Tricyclo[4,2,2,0{2,5}]dec-7-ene3,4,9,10-tetracarboxylicacid Tropone, 2-methacryloyloxyUrea, l,3-divinyl-l,3-diphenylUrea, JV-acryloyl-N'-benzoylUrea, N-vinyl-iV'-ethylUrea, N-vinyl-N'-ethylUrea, N-vinyl-W-ethylUrea, N-vinyl-N'-ethylUrea, JV-vinyl-iV'-ethylValerolactone, a-methyleneValerolactone, a-methyleneVinyl 1-cyano- acetate Vinyl 12-ketostearate Vinyl 12-ketostearate Vinyl 12-ketostearate Vinyl 12-ketostearate Vinyl 2-, 1,1-dichlorocyclopropane Vinyl 2-bromo-ethyl ether Vinyl 2-bromo-ethyl ether Vinyl 2-chlorocyclohexyl ketone Vinyl 2-chloroethyl ether Vinyl 2-chloroethyl ether Vinyl 2-chloroethyl ether Vinyl 2-chloroethyl ether Vinyl 2-chloroethyl ether Vinyl 2-chloroethyl ether Vinyl 2-chloroethyl ether Vinyl 2-chloroethyl ether Vinyl 2-ethylhexanoate Vinyl 3,3-bis(ethoxycarbonyl)propyl ether Vinyl 4-dithiobenzoate methyl Vinyl 4-dithiobenzoate methyl Vinyl 4-chlorocyclohexyl ketone Vinyl 4-chlorocyclohexyl ketone Vinyl 4-chlorocyclohexyl ketone Vinyl 4-chlorocyclohexyl ketone Vinyl 4-chlorocyclohexyl ketone Vinyl N,N-methylacetamide Vinyl oc-chloro-, triethoxysilane Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate
Monomer 2
r\
Pyrrolidone, N-vinylVinyl methyl ketone Methacrylate, methyl Styrene Vinyl acetate Methacrylate, methyl Styrene Imidazole, 1-Af-vinyl Acrylonitrile
0.5 1.35 0.266 0.73 42.47 0.27 0.52
Acrylate, ethyl Styrene Styrene Methacrylate, methyl Styrene Vinyl acetate Vinyl acetate Vinyl acetate Styrene Styrene Styrene Acrylonitrile Vinyl acetate Vinyl chloride Vinylidene chloride Styrene Acrylate, methyl Styrene Maleic anhydride Acrylate, ethyl Acrylate, ethyl Acrylate, methyl Acrylonitrile Methacrylate, methyl Styrene Vinyl acetate Vinyl chloride Acrylonitrile Acrylonitrile
3.13 -1.76 0.053 -0.008 -0.33 0.621 3.61 1.45 1.42 1.44 0.147 -0.18 -0.28 -0.01 0.26 0 -0.79
Methacrylate, methyl Styrene Maleic anhydride Methacrylate, methyl Styrene Vinyl acetate Vinyl cyclohexyl ketone Vinyl acetate Acrylonitrile 2-Oxazoline, 2-isopropenyl2-Oxazolinium BF4, 3-methyl2-isopropenylAcetamide, N-vinylAcetamide, N-vinylAcetate, 2-chloro-, vinyl Acetate, allyl Acetate, chloro-, allyl Acetate, dichloro-, allyl Acetate, trichloro-, allyl Acrolein Acrolein, methyl Acrylamide, N-octadecylAcrylamido, 1-, -1-deoxy-D-glucitol Acrylamido, 2-, -2-methylpropanesulfonate
±95%
0.68 0.058 0.4 9.84 0.13 0.26
0.25
1.7 0.15 0 0 0 0 0.07 0.16 -0.07 -0.047 0.06
r2 0.98 0.17 0.832 1.32 -0.011 0.839 1.48
±95%
Conv.
0.11 0.022 0.15 0.008 0.055 0.12
Y Y Y Y Y Y N
0.027 0.98
Y Y
0.23 2.07 0.029
Y Y Y
2.75 0.528 1.36 0.029 0.33 0.081
0.033 0.36 2.61 0.034 0.32
0.11 0.05
0.387 3.62 0.404 1.85 10.78 0.463 0.16 0.38 0.097 0.096 0.181 3.3 0.18 0.03 4.4 17.98 16.83 0.83 5 4.65 3.27 1.09 18.8 160 2.36 2.46 9.24 1.02
0.409 0.5 4.8 0.59 2.34
Y Y Y Y Y Y
0.52 1.96
Y Y Y Y
0.3 2.08 0.12 0.51 0.58 0.15 0.5 0.93
0.29 0.81
0.151 0.111 0.08 0.77 0.53 0.1 1.6 0.49
0.092 0.009
0.25 0.114
0.04 0.021
7.1 0.413
2 0.005
Y
0.6 0 0.8 1.8 0.77 0.57 0.41 -0.02 0.15 0.004 0.03 0.05
0.12 0.011 0.17
5.5 21 1.18 0.43 0.69 0.54 0.28 3.04 0.98 8.25 0.98 11.6
Y
0.43
N
1.46 0.87
Y N
Refs. 826 243 670 670 670 670 670 972 963 1104 800 1090 101 101 101 683 683 919 855 806 146 146 146 146 806 194 194 836 439 726 726 597 597 597 597 304 47 1015 697 697 836 668 668 668 668 631 237 894 908 984 984 892 1045 1045 1045 1045 207 589 119 258 700
References page II - 290
TABLE 1. cont'd Monomer 1 Vinyl acetate Vinyl Vinyl Vinyl Vinyl Vinyl Vinyl Vinyl Vinyl Vinyl Vinyl Vinyl Vinyl Vinyl Vinyl Vinyl Vinyl Vinyl Vinyl Vinyl Vinyl Vinyl Vinyl Vinyl Vinyl Vinyl Vinyl Vinyl Vinyl Vinyl Vinyl Vinyl Vinyl Vinyl Vinyl
acetate acetate acetate acetate acetate acetate acetate acetate acetate acetate acetate acetate acetate acetate acetate acetate acetate acetate acetate acetate acetate acetate acetate acetate acetate acetate acetate acetate acetate acetate acetate acetate acetate acetate
Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl Vinyl Vinyl Vinyl Vinyl Vinyl Vinyl Vinyl Vinyl Vinyl Vinyl Vinyl Vinyl Vinyl Vinyl Vinyl Vinyl Vinyl Vinyl Vinyl Vinyl
acetate acetate acetate acetate acetate acetate acetate acetate acetate acetate acetate acetate acetate acetate acetate acetate acetate acetate acetate acetate acetate
Monomer 2 Acrylamidomethylamino, p-, azobenzene Acrylate, 2-cyano-, methyl Acrylate, 2-ethylhexyl Acrylate, a-acetoxy-, ethyl Acrylate, a-chloro-, ethyl Acrylate, butyl Acrylate, glycidyl Acrylate, methyl Acrylate, methyl Acrylate, methyl Acrylate, methyl Acrylate, methyl Acrylate, sodium Acrylate, trifluoro-, methyl Actylate, trifluoro-, methyl Acrylic acid Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Allyl acetate Allyl acetate Allyl acetate Allyl acrylate Allyl butyrate Allyl chloride Allyl chloride Allyl chloride Allyl isobutyrate Allyl propionate Allyl trimethylacetate Allyl valerate Allystearamide, NAzobenzene, 4-(acrylamidomethylamino)Benzothiazole, vinylmercaptoBicyclo[2,2,l]hept-2-ene5,6-dicarboximide, N-benzyl Bicyclo[2,2,l]hept-2-ene5,6-dicarboximide, N-benzyl Bicyclo[2,2,l]hept-2-ene5,6-dicarboximide, Af-benzyl Butadiene, 2-chloroButene-1 Butene-2, cisButene-2, transCaprolactam, Af-vinylCaprolactam, N-vinylCaprolactam, Af-vinylCarbamate, N,N-diethyl-, vinyl Carbamate, N-vinyl-, ethyl Carbamate, N-vinyl-, ethyl Carbamate, N-vinyl-, tert-buty\ Carbazole, N-vinylCarbazole, N-vinylCarbazole, N-vinylCarbon monoxide Crotonic acid Crotonic acid Crotonic acid Diallyl P-cyanoethylisocyanurate Diallyl melamine Diallyl phthalate
rx
±95%
r2
±95%
Conv.
Refs.
0.126
12.98
858
0.005 0.04 0.08 0.03 0.018 0.003 0.04 0.03 0.405 0.03 0.03
0.05 7.5 5.621 30 3.48 7.6 7.28 6.38 2.58 6.7 6.3
452 570 244 638 301 553 1067 158 25 489 568 37 595 598 37 158 235 6 75 75 140 502 998 578 998 204 3 438 998 998 998 998 119 880
0.021 0.072 0.01 0.043
0.094
Y
3.39
Y
0.37 0.3
Y Y
Y 0.24 0.24 0.021 0.04 0.06 -0.06 -0.03 0.6 1 1 0.11 0.97 1.355 0.66 0.34 1.04 1.29 1.15 1.07 0.923 0.126 0.013 1.26
0.059 0.067 0.22 0.08 0.09
0.089 0.15
0.092
0.037
0 0 8.66 4.05
Y Y N Y Y Y
5.51 5.29 9.2 0.45 0.7 0.7 17.35 0.64 -2.4 0.61 0.75 0.51 0.42 0.34 0.58 0.68 12.98
0.91 1.13 6.39
0.26
Y
2.53 0.35
0.47
Y
1.46
3.21
Y Y
0.15
0.15
1.99 - 0.02 1.55 %21 12 0.63 0.35 0.35 1.7 0.39 0.418 0.07 0.126 0.15 0.13 0.24 0.317 0.3 0.31 0.06 0.68 0.336
6.63 0.82
994
0.014 0.09 0.24 1.05 1.69
0.04 0.063 1.12 0.023
0.081 0.07 0.026 0.049
33.52 0.11 0.03 -0.03 0.31 2.5 2.5 0.13 2.09 0.4 0.46 2.67 3.02 3.9 0.33 0.04 0.01 0.001 4.6 0.318 2.19
763 994
994 8.98 0.42 0.25 0.44
N Y Y Y
0.19
Y
0.26 0.03 0.13
Y N Y
0.14
Y
0.1
N
0.073 0.34
Y Y
247 211 211 211 557 859 883 197 629 81 827 246 246 551 474 47 526 94 778 201 297
TABLE 1. cont'd Monomer 1 Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate
Monomer 2 Diallyl phthalate Diallyl phthalate Diallyl, 1,3-, 5-(2-hydroxy3-phenoxypropyl) Diallyl, 1,3-, 5-(2-hydroxy3-phenoxypropyl) Diallylcyanamide Diallyldimethylammonium chloride Ethylene Ethylene Ethylene Ethylene Ethylene Ethylene Ethylene Ethylene Ethylene Ethylene, chlorotrifluoroEthylene, chlorotrifluoroEthylene, dichloro-, cisEthylene, dichloro-, cisEthylene, dichloro-, cisEthylene, dichloro-, cisEthylene, tetrachloroEthylene, tetrachloroEthylene, trichloroEthylene, trichloroFumarate, diethyl Fumarate, diethyl Fumarate, diisopropyl Fumaryl chloride Hexatriene, tetrachloroImidazole, 1-vinylIndene Isobutylene Isobutylene, 3-chloroIsopropenyl acetate Itaconate, dimenthyl Itaconic anhydride Itaconic anhydride Maleate, di-terf-butyl Maleate, diethyl Maleate, dimethyl Maleic anhydride Maleimide, A^-(2-hydroxyethyl)Maleimide, N-(2-hydroxyethyl)Maleimide, A^-(2-hydroxyphenyl)Maleimide, N-hydroxymethylMaleimide, W-phenylMethacrylamide, 1-deoxy-D-glucitol Methacrylate, 2,2,6,6-tetramethyl4-piperidinyl Methacrylate, butyl Methacrylate, di-, di-n-butylstannyl Methacrylate, ethyl Methacrylate, ferrocenylmethyl Methacrylate, isobutyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate acid Methacrylonitrile tyAr-Divinylaniline
rx 0.414 0.72 0.15
±95% 0.029
r2
±95%
Conv.
Refs.
1.66 2 5.5
0.16
Y
297 509 671
0.16
3.65
676
0.01 0.35 0.72
1.62 1.95 0.16
581 1029 309 41 413 42 559 68 68 766 6 1097 236 137 137 9 9 3 59 158 9 137 718 1038 91 4 364 360 211 475 100 975 365 365 1049 137 1049 260 323 323 323 323 328 258 664
1.14 1.03 1.52 3.74 1.23 1.4 0.33 0.68 0.47 1.02 6.4 0.898 4.13 4.45 0.607 0.7 0.011 0.09 0.012
1.2 0.77 0.64 0.21 0.58 0.11 0.27 0.06 1.94 1.87 0.076 0.1 0.004
0.28 0.88 0.74 0.67 0.13 0.79 -0.13 0.04 - .0.02 0.055 0.01 0.058 0.1 -0.07 -0.06 -0.006 0.443 0.33 0.9
N N
0.52
N
0.03 0.01
N N
0.36 0.02
Y
0.34 0.019 0.007
Y Y Y Y Y Y Y Y Y Y
6.99 2.8 0.19
Y Y Y Y Y
0.024 0.03 0.14 0.015
-0.11 0.39 1.66 0.13 1.171
1.17 0.2 0.18
-0.019 - 0.04 0.005 0.171 -0.006 0.019 -0.014 0.01 -0.011 0.017 -0.003 0.16 0.2
0.045 0.024 0.024 0.025 0.084 0.008 0.037 0.041 0.027 0.037 0.006
1.57 2.87 0.199 0.04 0.257 -0.058 0.61 0.88 1.75 1.45 1.284 0.56 13.7
0.36 0.32 0.02 0.012 0.086 0.074 0.12 0.17 0.17 0.21 0.046
Y Y Y Y Y Y Y Y Y Y Y Y Y
-0.003 0.013 -0.77 0.2 -0.06 -0.2 -0.81 0.03 0.04 0.07 0.01 0.01 0.058
0.15 0.018 5.29
30.18 0.013 131.8 1.52 29.7 2.71 137.5 26 28.6 22.21 0.2 12 3.99
14.47 0.036 29.8
Y Y N
24.16 0.25 5.9
Y Y N
0.12
Y
0.038
0.22 0.01 1.17
0.009
1.9 8.64 0.17 0 1.082
0.03
0.074
165 949 210 293 165 158 210 272 383 471 377 75 45
References page II - 290
TABLE 1. cont'd Monomer 1 Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate
Monomer 2
rx
Norbornadiene 0.818 Oxazolidone, N-vinyl0.602 Oxazolidone, Af-vinyl0.55 Oxazoline, 2-, 2-isopropenyl0.25 Oxazoline, 2-, 4-acryloxymethyl0.03 dimethyl-2,4-dimethyl Oxazoline, 2-, 4-methacryloxy0.05 2,4-dimethyl Oxazolinium, 2- tetrafluoroborate, 0.43 3-methyl Phosphate, diethyl isopropenyl 1.56 Phosphine oxide, diphenylvinyl0.38 Phosphonate, oc-carbomethoxyvinyl-, 0.09 diethyl Phosphonate, isopropenyl-, dimethyl 0.14 Phosphonate, vinyl-, bis(2-chloroethyl) 0.09 Phosphonate, vinyl-, bis(2-chloroethyl) 0.09 Phosphonate, vinyl-, bis(2-chloroethyl) 0.33 Phosphonate, vinyl-, diethyl 0.04 Phosphonate, vinyl-, dimethyl 0.04 Phosphonate, vinyl-, dimethyl 0.04 Propene, 1-chloro-, cis7.08 Propene, 1-chloro-, trans3.13 Propene, 2-chloro0.186 Propene, 3,3,3-trichloro0.19 Pyridine, 2-methyl-5-vinyl0.11 Pyridine, 2-vinyl-0.11 Pyridine, 2-vinyl0 Pyrrolidone, N-vinyl0.26 Pyrrolidone, Af-vinyl0.19 Pyrrolidone, N-vinyl0.195 5-Ethyl AT-vinyl-iV-methylthiolcarbamate 0.67 5-Vinyl AW-diethylthiolcarbamate 0.133 Styrene -0.04 Styrene 0.02 Styrene 0.01 Styrene 0.05 Styrene 0.16 Styrene 0.08 Styrene, 3-fn-rc-butylstannyl5.33 Succinimide, N-vinyl0.072 Succinimide, N-vinyl0.18 Succinimide, N-vinyl0.229 Tetrazole, 2-methyl-5-vinyl0.04 Triallyl citrate 0.222 Triallyl cyanurate 0.197 Triallyl isocyanurate 0.278 Triazole, 1,2,3-, l-/?-bromophenyl-0.011 4-vinylUrea, W-vinyl-AA'-ethyl0.463 Urea, N-vinyl-7V'-ethyl0.16 Urea, N-vinyl-Ar'-ethyl0.38 Vinyl 12-ketostearate 0.18 Vinyl 2-chloroethyl ether 2.36 Vinyl 4-chlorocyclohexyl ketone 0.1 Vinyl benzenesulfonate 0.628 Vinyl benzoate 0.455 Vinyl benzoate 0.35 Vinyl benzoate 0.78 Vinyl benzoate 0.7 Vinyl benzoate 0.66 Vinyl benzoate 0.24 Vinyl bromide 0.41 Vinyl bromide 0.6 Vinyl bromide 0.38
±95% 0.019 0.038 0.18
r2 1.354 1.55 2.04 7.1 1.41
±95%
Conv.
0.07 0.28 0.13
Y Y Y
6.2 0.057
0.35 0.15 0.091 0.17 0.25 1.77 0.057 0.1 0.025 0.072 0.12
0.009 0.54 0.06 0.16 0.025 0.053 0.043 0.008 0.029
0.036 0.069 0.52 0.2 0.13 0.09
0.366
Refs. 188 102 36 862 596 596
0.151
Y
877
0.44 1.7 0.6
650 843 684
0.99 0.85 0.85 0.47 0.74 0.74 0.74 -0.012 0.011 1.65 0.19 9 13.65 30 1.06 1.75 3.4 1.22 1.89 42.48 18.8 56 48 60 57.8 0.38 5.68 4.49 1.99 28.51 2.97 1.29 1.95 42.47
684 592 594 595 592 592 594 181 181 181 402 812 6 6 103 121 36 197 197 158 241 481 481 481 812 985 104 167 80 670 367 201 201 670
0.621 3.61 1.45 -0.28 0.16 0.15 -1.34 1.07 0.99 1.64 1.13 1.74 1.98 5.26 1.92 3
0.061 0.074 0.36
Y Y Y
3.64
Y
0.25 2.79 0.21 1.17 0.77 26.85 2.87
Y N Y Y Y Y Y
0.12 9.49 0.43 31.34 0.38 0.42 0.42 9.84
Y Y Y Y Y Y Y Y
0.081
Y Y
1.7 0.27
Y Y
1.93
Y
0.98 1.23 0.35
N Y N
101 683 683 146 597 668 942 253 253 26 272 430 696 158 268 268
TABLEI. cont'd Monomer 1 Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetoxymethyl ketone Vinyl benzenesulfonate Vinyl benzoate
Monomer 2 Vinyl butyl ether Vinyl butyl ether Vinyl butyl ether Vinyl butylsulfonate Vinyl butyrate Vinyl butyrate Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloroacetate Vinyl chloroacetate Vinyl chloroacetate Vinyl chloroformate Vinyl chloroformate Vinyl chloromethyl ketone Vinyl cinnamate Vinyl cyclohexyl ketone Vinyl cymantrene Vinyl dodecyl ether Vinyl ethyl ether Vinyl ethyl ketone Vinyl ethyl oxalate Vinyl fluoride Vinyl formate Vinyl formate Vinyl isopropyl ketone Vinyl isopropyl ketone Vinyl laurate Vinyl methanesulfonate Vinyl methyl ketone Vinyl methyl sulfone Vinyl octadecyl ether Vinyl octyl ether Vinyl phenyl carbonate Vinyl phenyl carbonate Vinyl phenyl ketone Vinyl phenyl sulfone Vinyl propionate Vinyl propionate Vinyl stearate Vinyl stearate Vinyl tert-butyl sulfide Vinyl tert-butyl sulfide Vinyl thiolacetate Vinyl, N-, N-methylacetamide Vinylene carbonate Vinylene carbonate Vinylene carbonate Vinylene carbonate Vinylene carbonate Vinylene carbonate Vinylidene chloride Vinylidene chloride Vinylidene chloride Vinylidene chloride Vinylidene chloride Vinylidene cyanide Vinylidene fluoride Styrene Vinyl acetate Acrylonitrile
rx
±95%
3.72 0.71 2.5 0.025 1 1.35 0.43 0.981 0.24 0.263 0.25 0.65 0.26 0.83 0.803 0.8 0.67 0.66 0.044 0.04 0.08 0.072 3.67 3.42 -0.13 1.35 3.5 0.94 1.41 0.3 -0.154 1.4 0.639
0.09
0 4.5 3.47 0.85 0.85 -0.06 0.171 0.98 0.9 0.953 0.9 13 13 0.05 0.49 3.2 3 7.16 7.3 3.83 3.92 0.03 0.05 0.05 -0.002 0.12 0.003 6 0.368 -1.34 0.019
0.02
0.006 0.14 0.036 0.15 0.028 0.15 0.14 0.12 0.089 0.16 0.12 0.054 0.003 0.18 0.84 0.14 0.073 0.014
0.23 0.23 0.057 0.064 0.015
0.62 0.64 0.18 0.32 0.1 0.026 0.002 0.018 1.7 0.051
r2
±95%
Conv.
0.01 0.2 0.16 0.13 0.97 1.25 1.63 1.032 1.84 2.13 1.64 1.35 2.3 1.39 0.88 1.18 0.579 0.586 49.52 1.2 13.76 7.21 0 0.26 10.18 9.89 0.25 0.98 0.68 7.87 6.47 0.7 0.206
0.02
N
0.33
Y
0.32 0.097 0.68 0.2 0.12
Y Y Y Y Y
0.64 0.3 0.19
N N Y Y Y Y
0.355 0 0 0.384 0.384 5.81 -0.35 0.98 1 0.96 0.73 0.07 0.07 5.5 0.93 0.3 0.27 0.05 0.13 0.044 0.08 4.66 6.7 5 3.49 4.7 0.1 0.08 0.103 0.628 5.03
0.076 0.052 15.79 1.01
Y
6.62 8.44
Y Y Y
0.06
N
2.18
Y
0.427 0.21
Y Y Y
0.083 0.083 0.96 0.37
Y Y Y Y
0.17
Y
0.3
Y
0.16
Y
0.039 0.11 0.26
Y Y Y
0.17
Y
0.11
Y
0.011 0.036 1.08
Y Y
Refs. 345 448 553 185 272 515 109 148 158 283 3 450 86 71 779 861 675 706 356 200 846 354 372 158 794 124 755 272 401 601 794 503 942 91 195 372 372 675 705 794 193 272 425 1 537 598 601 566 631 103 103 120 120 144 90 3 432 436 59 812 82 627 806 942 47
References page II - 290
TABLE 1. cont'd Monomer 1 Vinyl benzoate Vinyl benzoate Vinyl benzoate Vinyl benzoate Vinyl benzoate Vinyl benzoate Vinyl benzoate Vinyl benzoate Vinyl benzoate Vinyl benzoate Vinyl benzoate Vinyl benzoate Vinyl benzoate Vinyl benzoate Vinyl benzoate Vinyl benzoate Vinyl benzoate Vinyl benzoate Vinyl benzoate Vinyl benzyl sulfide Vinyl benzyl sulfide Vinyl bromide Vinyl bromide Vinyl bromide Vinyl bromide Vinyl bromide Vinyl bromide Vinyl bromide Vinyl bromide Vinyl bromide Vinyl bromide Vinyl bromide Vinyl bromide Vinyl bromide Vinyl bromide Vinyl butyl ether Vinyl butyl ether Vinyl butyl ether Vinyl butyl ether Vinyl butyl ether Vinyl butyl ether Vinyl butyl ether Vinyl butyl ether Vinyl butyl ether Vinyl butyl ether Vinyl butyl ether Vinyl butyl ether Vinyl butyl ether Vinyl butyl ether Vinyl butyl ether Vinyl butyl ether Vinyl butyl ether Vinyl butyl ether Vinyl butyl sulfide Vinyl butyl sulfide Vinyl butylsulfonate Vinyl butylsulfonate Vinyl butylsulfonate Vinyl butylsulfonate Vinyl butylsulfonate Vinyl butyrate Vinyl butyrate Vinyl butyrate Vinyl butyrate Vinyl butyrate
Monomer 2 Allyl chloride Methacrylate, methyl Pyrrolidone, N-vinylStyrene Styrene Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl chloride Vinyl chloride Vinyl chloride Vinyl p-bromobenzoate Vinyl p-chlorobenzoate Vinyl p-cyanobenzoate Vinylidene chloride Vinylidene cyanide Methacrylic anhydride Styrene Acrylate, butyl Acrylate, butyl Acrylonitrile Acrylonitrile Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Styrene Styrene Styrene Vinyl acetate Vinyl acetate Vinyl acetate Acrylate, 2-chloroethyl Acrylate, methyl Acrylate, methyl Acrylonitrile Acrylonitrile Benzenesulfamide, /?-methacrylamideCaprolactam, TV-vinylMethacrylate, 2-bromoethyl Methacrylate, methyl Pyrrolidone, N-vinyl Styrene Toluenesulfonamide, AW-methyl-vinylVinyl acetate Vinyl acetate Vinyl acetate Vinyl chloride Vinyl chloroacetate Vinylidene chloride Acrylonitrile Styrene Acrylate, methyl Styrene Vinyl acetate Vinyl chloride Vinyl chloride Allyl chloride Butadiene, 2-chloroCarbazole, N-vinylEthylene Methacrylate, methyl
T1 0.46 0.07 0.408 -0.02 0.06 1.07 0.99 1.64 1.13 1.74 1.98 0.343 0.5 0.28 0.716 0.832 0.659 0.065 0 - 0.048 0.04 0.18 0.19 0.06 0.06 0.12 0.33 0.052 0.05 0.012 0.06 0.09 5.26 1.92 3 0 0.01 0 -0.03 0 0.03 0 -0.027 -0.08 3.37 0.01 0.2 0.16 0.023 0.12 0.004 0.041 -0.06 0 0 0.13 0.267 0.083 0.31 0.07 1.5 0.03
±95%
0.03 1.62 0.15 0.27 1.93 0.98 0.036 0.031 0.028 0.033 0.093 0.017 0.033 0.17 0.16 0.04 0.06 0.026 0.074 0.049 0.2 1.23 0.35 0.01 0.01 0.73 0.063 0.78 1.65 0.02 0.001 4.39 0.001 0.028 0.18 0.14 0.16 0.33 0.046 0.096 0.12
r2 0.88 20.3 2.507 34.8 31.56 0.455 0.35 0.78 0.7 0.66 0.24 1.66 1.7 0.72 1.17 0.81 0.878 5.58 0.061 0.97 2.32 4.07 3.7 2.25 2.79 14.11 17.1 25.1 19.84 16.88 18 15 0.41 0.6 0.38 2.01 3.65 3.6
±95%
Conv.
0.039 29.3 4.33 0.069
Y Y N Y
0.52
Y
0.2 0.16
N Y
0.13 0.072 0.094 1.76 0.047 0.27 0.25 0.44
Y Y Y Y Y Y Y N
0.2 0.67
N N
0.88 2.58 0.94
Y Y Y
8.26 0.13 0.09
N Y N
0.07
N N N
0.98 3.4 3.1 13.7
0.13 0.1 5.3
1.49 21.25 -0.31 3.72 0.71 2.5 2.084 1.49 1.75 0.086 2.69 4.14 1.74 0.025 0.325 8.47 1.15
0.95 16.53 0.29 0.09
N Y Y Y N
0.016 34.5 0.11 0.01 0.25 0.58 0.27 0.006 0.013 0.86
Y Y Y Y Y Y Y Y Y Y
0.34
N Y
1.33 0.7 25
Y
Refs. 438 272 253 26 696 253 253 26 272 430 696 283 450 519 110 110 110 47 82 106 303 268 268 268 286 268 268 34 34 34 34 368 158 268 268 790 345 574 345 347 1005 215 657 127 215 241 80 345 448 553 279 212 279 303 303 185 185 185 185 185 438 247 246 605 272
TABLE 1.
cont'd
Monomer 1 Vinyl butyrate Vinyl butyrate Vinyl butyrate Vinyl butyrate Vinyl butyrate Vinyl caproate Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride
Monomer 2 Vinyl acetate Vinyl acetate Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Aconitate, trimethyl Acrolein Acrylamide Acrylamide, Af-methylolAcrylate, 2-ethylhexyl Acrylate, butyl Acrylate, methyl Acrylate, methyl Acrylate, methyl Acrylate, methyl Acrylate, octyl Acrylate, trifluoro-, methyl Acrylate, trifluoro-, methyl Acrylic acid Acrylic acid Acrylic acid Acrylic acid Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acryloyl chloride Allyl acetate Allyl acetate Allyltriethoxysilane Butadiene Butadiene Butene-1 Butene-1, 2-ethylButene-1, 2-methylButene-1,3, 3-dimethylButene-1,3, 3-dimethylButene-2 Butene-2, 2-methylButene-2, cisCarbazole, N-vinylCarbon monoxide Crotonaldehyde Diallyl phthalate Diallylcyanamide Diallylcyanamide Ethylene Ethylene Ethylene Ethylene Ethylene Ethylene Ethylene Ethylene Ethylene Ethylene Ethylene, chlorotrifluoroFumarate, diethyl Fumarate, diisopropyl Hexene-1 Imidazole, l-vinyl-2-methylIsobutylene
rx 0.97 1.25 0.302 0.55 0.65 0.348 0.04 0.03
0.16 0.07 0.093 0.002 0 0.06 0.12 1.5 1.5 0.107 0.03 0.024 0.11 -0.01 0.07 0.02 0.044 0.052 0.04 0.02 1.2 1.16 1.68 0.04 -0.11 3.34 1.56 1.01 5.64 6.18 3.3 8.52 8.8 0.17 13.52 1.55 0.833 0.44 0.44 3.82 1.99 1.74 4.38 2 3.21 1.85 0.96 1.63 1.55 2.53 0.13 0.29 1.54 0.188 2.04
±95%
0.013
0.05 0.11
0.002 0.01
0.011 0.09 0.069 0.037 0.03 0.08 0.002 0.01 0.029
0.38 0.31 0.58 0.26 0.31 0.2 13.57 2.18 10.54
0.25 0.26 0.012
0.59 0.42 0.58 0.44
0.1 0.22 0.22 0.18 0.1 0.98 0.077 1.82
r2 1 1.35 2.092 1.75 1.35 2.26 0.19 5.22
4.15 4.4 4.4 7.66 5 4 4.8 0 0 6.69 9.28 7.04 6.8 3.26 2.55 2.62 3.62 3.65 4 3.03 0 -0.94 8.8 5.27 0.12 -1.05 -1.18 -0.44 -0.07 -1.79 0.3 0 4.77 0.121 -0.56 0.7 0.68 0.68 0.02 0.19 0.24 0.34 0.2 0.21 0.21 0.14 0.23 0.16 0.01 0.48 0.49 -1.72 2.15 0.06
±95%
Conv.
0.074
Y
0.22 0.13
Y Y N Y Y
0.22 0.5
Y Y
0.88 0.51 0.33
Y N Y
0.34 0.12 0.25 0.21 0.22
Y N N Y Y
0.22
Y
0.48
Y
3.35 0.12 0.89 1.2 0.28 2.5 5.22 5.31
Y Y N N N Y N N
0.011 0.25 0.046
Y N Y
0.06 0.17 0.13 0.13
N N N N
0.01 0.12 0.01 0.01
N N N N
0.1
Y
9.23 0.26 0.8
N Y Y
Refs. 272 515 283 400 494 283 147 271 156 157 510 518 151 46 470 518 518 595 598 135 229 288 379 140 202 22 238 46 529 288 470 475 237 517 717 230 329 329 329 6 329 329 230 427 184 271 296 602 603 161 180 270 42 472 536 63 63 64 68 454 137 1038 329 154 140
References page II - 290
TABLE 1. cont'd Monomer 1 Vinyl Vinyl Vinyl Vinyl Vinyl Vinyl Vinyl Vinyl Vinyl Vinyl Vinyl Vinyl Vinyl Vinyl Vinyl Vinyl Vinyl Vinyl Vinyl Vinyl Vinyl Vinyl Vinyl
chloride chloride chloride chloride chloride chloride chloride chloride chloride chloride chloride chloride chloride chloride chloride chloride chloride chloride chloride chloride chloride chloride chloride
Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride
Monomer 2
rx
Isobutylene 2.12 Isobutylene 1.2 Isobutylene 1.54 Isobutylene, 3-chloro0.31 Isopropenyl acetate 2.26 Isopropenylisocyanate 0.39 Itaconate, diethyl 0.06 Itaconate, dimethyl 0.05 Maleate, diethyl 0.768 Maleate, diethyl 0.8 Maleate, diethyl 0.9 Maleate, dioctyl 0.05 Maleic anhydride 0.098 Maleic anhydride 0.04 Maleic anhydride 0.1 Maleimide, N-(4-carboxyethylphenyl)0.04 Maleimide, N-(4-chlorophenyl)0.026 Maleimide, AH4-methylphenyl)0.022 Maleimide, N-butyl0.24 Maleimide, N-phenyl0.023 Maleimide, Af-propyl0.06 Methacrylate, 3,5-dimethyladamantyl 0.21 Methacrylate, p-(2-benzothiazolylthio)- 0.64 ethyl Methacrylate, butyl 0.05 Methacrylate, methyl 0.07 Methacrylate, octyl 0.04 Methacrylic acid 0.064 Methacrylic acid -0.022 Methacrylic acid 0.07 Methacryloyl chloride 0.3 Methacryloyloxy-, 0-, benzoic acid 0.004 Norbornadiene 0.67 Octene-1 3.26 Oxazolidone, Af-vinyl0.313 Pentene-1 4 Pentene-1 2.08 Pentene-1, 2-methyl1.59 Phosphate, vinyl diethyl 3.4 Phosphate, vinyl diphenyl 3.009 Propene, 1-chloro-, ds11.52 Propene, 1-chloro-, trans4.45 Propene, 2-chloro0.095 Propene, 2-chloro0.75 Propenyl, 2-, acetate 2.2 Propenyl, 2-chloro-, acetate 0.7 Propenyltriethoxysilane Propylene 2.35 Propylene -0.05 Propylene 5.16 Propylene 2.45 Propylene 2.9 Pyridine, 4-vinylPyrrolidone, N-vinyl0.53 Pyrrolidone, N-vinyl0.55 Pyrrolidone, Af-vinyl0.74 Styrene -0.06 Styrene 0.058 Styrene 0.16 Styrene 0.005 Styrene 0.04 Styrene 0.01 Styrene, pentachloro0.43 Triallyl citrate 0.605 Vinyl 12-ketostearate 0.03
±95% 0.2 2.05 0.13
0.078 0.11 0.14 0.042 0.03 0.044 0.048 1.13 0.026 0.05 0.04
0.047 0.008 0.02 0.052 0.02 0.45 0.095 1.78 0.68 0.21 0.077 2.14 0.81 0.085
0.14 0.1 0.06
r2 0.268 -0.54 0.08 0 0.23 3 5.65 5 -0.003 0 0.046 0.608 -0.22 0.4 0.67 3.29 3.65 4.49 -12.7 4.01 2.38 1.85 0.26 13.5 8.99 14 23.52 23.26 9.05 2 11.26 0.41 -0.57 0.822 0.001 0.81 -1.16 0.15 0.327 0.1 0.33 4.75 0.58 0.25 0 0.196 3.1 -0.02 0.09
±95%
Conv.
Refs.
0.043 5.8
Y N
0.16
Y
0.044
Y
0.07 0.099 0.38
Y Y Y
155 329 560 475 100 777 480 479 137 449 6 3 260 521 521 306 306 306 305 306 305 335 741
0.18 0.39 0.34 106.2 0.18 0.16 8.87
N Y Y Y Y N N
2.97
Y
0.98 0.96
Y Y
3.5 0.01 0.85 0.048 5.2 2.31 0.047 0.023 0.63 0.4 5.12
Y N N Y Y N N Y Y Y Y Y
0.023 0.21 0.04
Y Y N N Y
0.08 0.003 0.08 0.031 0.87 0.033
0.38 0.34 0.73 27.54 17.24 23.92 25 12.4 14.7 5.3 1.03 - 0.01
7.35 1.12 3.6 5 29.2 0.17
Y Y N Y Y Y Y
519 3 511 135 229 46 432 938 267 329 36 3 329 329 779 779 181 181 181 517 189 445 237 155 329 355 560 588 154 40 582 582 109 238 242 46 516 59 516 367 146
TABLE 1. cont'd Monomer 1 Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloroacetate Vinyl chloroacetate
Monomer 2 Vinyl 2-chloroethyl ether Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl benzoate Vinyl benzoate Vinyl benzoate Vinyl butyl ether Vinyl butylsulfonate Vinyl butylsulfonate Vinyl butyrate Vinyl butyrate Vinyl butyrate Vinyl caproate Vinyl chloroacetate Vinyl dichloroacetate Vinyl dodecyl ether Vinyl fluoride Vinyl fluoride Vinyl hendecanoate Vinyl isobutyl ether Vinyl laurate Vinyl m-cresyl ether Vinyl methyl ketone Vinyl o-cresyl ether Vinyl octadecyl ether Vinyl octyl ether Vinyl p-chlorophenyl ether Vinyl /?-cresyl ether Vinyl p-terf-butylphenyl ether Vinyl p-vinyloxybenzoate Vinyl pelargonate Vinyl phenyl ether Vinyl phenyl ether Vinyl phenyl ether Vinyl propionate Vinyl propionate Vinyl stearate Vinyl tert-buty\ sulfide Vinyl terf-butyl sulfide Vinyl valerate Vinylene carbonate Vinylene carbonate Vinylene carbonate Vinylethyldiethoxysilane Vinylidene chloride Vinylidene chloride Vinylidene chloride Vinylidene chloride Vinylidene chloride Vinylidene chloride Vinylidene chloride Vinylidene chloride Vinylidene cyanide Vinylidene cyanide Vinylisocyanate Vinylphenylisocyanate, p Vinyltriethoxysilane Vinyltrimethoxysilane Acrylonitrile Acrylonitrile
rx 2.46 1.63 1.032 1.84 2.13 1.64 1.35 2.3 1.66 1.7 0.72 2.084 0.325 8.47 2.092 1.75 1.35 2.26 1.64 1.3 1.93 11 11.6 1.081 2.19 7.4 1.23 0.1 1.33 2.1 1.9 1 1.17 1.08 0.58 1.16 1.28 1.06 1.21 1.6 1.35 0.71 3 3 2.006 4.82 15.38 17.81 0.94 0.071 0.14 0.25 0.3 0.2 0.2 0.16 0.205 0.01 0.016 0.46 0.01 0.82 0.93 -0.007 0.09
±95% 0.52 0.32 0.097 0.68 0.2 0.12 0.64 0.16 0.016 0.013 0.86 0.074 0.22 0.34 0.55
0.016 1.43 0.04 0.02 0.04 0.02 0.06 0.06 0.14 0.03 0.097 0.071 0.49 1.44 7.84 1.53 0.025 0.32
0.003 0.002 0.16 0.016
r2 -0.07 0.43 0.981 0.24 0.263 0.25 0.65 0.26 0.343 0.5 0.28 0.023 0.267 0.083 0.302 0.55 0.65 0.348 0.421 0.91 0.15 0.05 0.11 0.38 0.04 0.2 0.13 8.3 0.14 -0.1 0.1 0.63 0.13 0.14 0.78 0.28 0.01 0.16 0.17 0.6 0.65 0.24 0.15 0.15 0.277 0.03 0.069 0 -0.44 2.06 3.39 8.92 3.2 4.5 1.8 4.5 3.068 0.72 0.6 3.7 11.9 -0.04 0.09 4.18 0.34
±95%
Conv.
0.11 0.14 0.036 0.15 0.028 0.15
Y Y Y Y Y Y
0.14 0.036
N Y
0.001 0.046 0.096 0.013
Y Y Y Y
0.05 0.055 0.49
Y Y Y
0.022 0.37
Y Y
0.02
Y
0.01
Y
0.05 0.01 0.02 0.07
Y Y Y N
0.59
Y
0.03
N
0.64
Y
0.014 0.12 0.068 0.22 2.97 0.32 1.16
Y Y Y Y Y Y N Y
0.076
Y
0.068
Y
0.44
Y Y Y
0.33
Refs. 304 109 148 158 283 3 450 86 283 450 519 279 185 185 283 400 494 283 283 283 370 590 755 145 47 450 279 375 279 370 370 279 279 279 497 145 172 279 280 400 450 145 598 601 283 103 319 319 237 238 29 3 470 517 539 585 67 409 82 777 777 237 237 362 542
References page II-290
TABLE 1. cont'd Monomer 1 Vinyl Vinyl Vinyl Vinyl Vinyl Vinyl Vinyl Vinyl Vinyl Vinyl Vinyl Vinyl Vinyl Vinyl Vinyl Vinyl Vinyl Vinyl Vinyl Vinyl Vinyl Vinyl Vinyl Vinyl Vinyl Vinyl Vinyl Vinyl Vinyl Vinyl Vinyl Vinyl Vinyl Vinyl Vinyl Vinyl Vinyl Vinyl Vinyl Vinyl Vinyl Vinyl Vinyl Vinyl Vinyl Vinyl Vinyl Vinyl Vinyl Vinyl Vinyl Vinyl Vinyl Vinyl Vinyl Vinyl Vinyl Vinyl Vinyl Vinyl Vinyl Vinyl Vinyl Vinyl Vinyl
chloroacetate chloroacetate chloroacetate chloroacetate chloroacetate chloroacetate chloroacetate chloroacetate chloroacetate chloroacetate chloroacetate chloroacetate chloroethyl ether chloroethyl ether chloroformate chloroformate chloromethyl ketone chloromethyl ketone chloromethyl ketone chloromethyl ketone chloromethyl ketone chloromethyl ketone cinnamate cinnamate cinnamate cyclohexyl ether cyclohexyl ketone cyclohexyl ketone cymantrene cymantrene cymantrene cymantrene cymantrene dichloroacetate dichloroacetate dichloroacetate dichloroacetate diethylphosphinate diethylphosphinate dodecyl ether dodecyl ether dodecyl ether dodecyl ether dodecyl ether dodecyl ether ether ether ether ether ethyl ether ethyl ether ethyl ether ethyl ether ethyl ether ethyl ether ethyl ether ethyl ether ethyl ether ethyl ether ethyl ketone ethyl ketone ethyl ketone ethyl ketone ethyl ketone ethyl ketone
Monomer 2 Phosphate, vinyl diethyl Phosphate, vinyl diphenyl Styrene Styrene Vinyl acetate Vinyl acetate Vinyl acetate Vinyl butyl ether Vinyl chloride Vinyl ethyl ether Vinyl phenyl ether Vinylidene cyanide Acrylonitrile Methacrylic anhydride Vinyl acetate Vinyl acetate Acrylonitrile Methacrylate, methyl Styrene Styrene, a-methylVinyl acetate Vinylidene chloride Methacrylonitrile Pyrrolidone, N-vinylVinyl acetate Pyrrolidone, A^-vinylVinyl 4-chlorocyclohexyl ketone Vinyl acetate Acrylate, methyl Acrylonitrile Pyrrolidone, N-vinylStyrene Vinyl acetate Acrylonitrile Acrylonitrile Styrene Vinyl chloride Ethylene Ethylene Acrylonitrile Styrene Styrene Vinyl acetate Vinyl chloride Vinylidene chloride Acrylonitrile Methacrylate, methyl Pyridine, 4-vinylStyrene Acrylate, methyl Acrylonitrile Ethylene Fumarate, diethyl Methacrylate methyl Styrene Styrene Vinyl acetate Vinyl chloroacetate Vinylidene chloride Methacrylate, methyl Styrene Styrene Styrene Styrene Vinyl acetate
rt 2.01 1.42 -0.04 0.03 1.39 0.88 1.18 1.49 0.421 1.92 0.84 0 -0.02 0.579 0.586 0.88 0.593 0.507 0.386 49.52 6.8 0.15 1.2 1.2 -0.11 1.6 13.76 0.211 - 0.065 0.093 0.096 7.21 0.044 0.18 0.28 0.91 -11.99 -62.84 0 0 0 0 0.15 0 0.02 -0.15 0.03 1.2 0 0.06 0 -0.124 0.01 0 -0.122 0.26 0.43 0 0.65 -0.033 0.43 0.332 0.122 10.18
±95% 0.2 0.15 0.24 0.3 0.19 34.5 0.055 17.19 1.67 0.006 0.02 0.076 0.052 0.12 0.092 0.039 0.034 15.79 0.3
0.59
0.067 0.093 0.053 0.014 1.01 0.015
0.49 80.64 34.66
0.16 5.3 0.12 0.059
0.066 3.9 0.42 0.023 0.06 0.043 0.017 6.62
r2
±95%
Conv.
0.374 0.53 14.57 45 0.83 0.803 0.8 0.12 1.64 0.43 0.55 0.137 1.04
0.046 0.12 62.41
Y Y Y
0.12 0.089
N Y
4.39 0.34 3.9 0.61 0.037 0.05
0.67 0.66 0.064 0.121 0.127 0.009 0.044 0.018 4.6 0.01 0.04 1.91 0.5 0.08 0.46 0.446 0.037 2.324 0.072 7.45 0.25 20 1.3 0.15 0.05 0.82 27 56 3.67 1.93 1.3 0.94 4.9 32 152 3.3 0.69 2.7 1.63 37 90 111 3.42 1.92 3.2 0.42 13.83 0.2 0.29 0.665 -0.13
0.16 0.12 0.019 0.021 0.047 0.01 0.054 0.009
Y Y Y Y Y N Y Y Y Y Y Y Y Y Y
9.39
Y
0.14 0.048 0.03 0.06 0.003 0.32
Y Y Y Y Y Y
0.55 0.16 0.01
Y Y Y
0.99
Y
185
Y
0.12
N
0.16
Y
15.5 17.19 0.17 1.44 0.08 0.16 0.021 0.18
Y Y Y Y Y N Y Y Y
Refs. 779 779 212 542 71 779 861 212 283 212 212 82 116 106 675 706 356 356 353 356 356 356 200 200 200 214 668 846 354 354 308 354 354 362 542 542 283 311 311 373 374 374 372 370 371 386 45 395 45 470 194 584 194 106 140 194 158 212 470 794 112 344 353 550 794
TABLE 1. cont'd Monomer 1 Vinyl ethyl oxalate Vinyl ethyl oxalate Vinyl ethyl oxalate Vinyl ethyl oxalate Vinyl ethyl sulfide Vinyl ethyl sulfide Vinyl ethyl sulfide Vinyl ethyl sulfide Vinyl ethyl sulfide Vinyl ethyl sulfide Vinyl ethyl sulfoxide Vinyl ethyl sulfoxide Vinyl ethyl sulfoxide Vinyl ethyl sulfoxide Vinyl ethylene glycol glycidyl ether Vinyl ethylene glycol glycidyl ether Vinyl fluoride Vinyl fluoride Vinyl fluoride Vinyl fluoride Vinyl fluoride Vinyl fluoride Vinyl fluoride Vinyl fluoride Vinyl fluoride Vinyl fluoride Vinyl fluoride Vinyl fluoride Vinyl fluoride Vinyl formate Vinyl formate Vinyl formate Vinyl formate Vinyl formate Vinyl formate Vinyl formate Vinyl hendecanoate Vinyl hendecanoate Vinyl hendecanoate Vinyl hendecanoate Vinyl hendecanoate Vinyl hendecanoate Vinyl iodide Vinyl isobutyl ether Vinyl isobutyl ether Vinyl isobutyl ether Vinyl isobutyl ether Vinyl isobutyl ether Vinyl isobutyl ether Vinyl isobutyl ether Vinyl isobutyl ether Vinyl isobutyl ether Vinyl isobutyl ether Vinyl isobutyl ether Vinyl isobutyl ether Vinyl isobutyl ether Vinyl isobutyl ether Vinyl isobutyl sulfide Vinyl isobutyl sulfide Vinyl isobutyl sulfide Vinyl isobutyl sulfide Vinyl isobutyl sulfide Vinyl isobutyl sulfide Vinyl isobutyl sulfide Vinyl isobutyl sulfide
Monomer 2
r\
Acrylonitrile Methacrylate, methyl Styrene Vinyl acetate Acrylonitrile Acrylonitrile Methacrylate, methyl Methacrylate, methyl Styrene Styrene Acrylonitrile Methacrylate, methyl Styrene Styrene Pyrrolidone, AT-vinylPyrrolidone, N-vinylAcrylate, butyl Acrylate, butyl Acrylate, methyl Acrylate, methyl Acrylonitrile Acrylonitrile Ethylene Ethylene Ethylene, chlorotrifluoroVinyl acetate Vinyl chloride Vinyl chloride Vinylidene chloride Acrylonitrile Allyl chloride Butadiene, 2-chloroButadiene, 2-chloroCarbazole, iV-vinylVinyl acetate Vinyl acetate Acrylate, methyl Acrylonitrile Butadiene Styrene Vinyl chloride Vinylidene chloride Styrene Acrylate, 2-chloroethyl Acrylate, methyl Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Ethylene, trichloroFumarate, diethyl Maleate, diethyl Styrene Styrene Styrene Vinyl chloride Vinylene carbonate Acrylate, ethyl Acrylate, ethyl Acrylate, methyl Acrylate, methyl Acrylonitrile Acrylonitrile Acrylonitrile Methacrylate, methyl
0 -0.05 -0.12 9.89 0.06 0.05 0.036 0.3 0.113 0.25 -0.08 -0.037 0.101 0.1 0.06 0.06 0.01 0.01 0.01 0.01 0.005 1 0.01 0.3 0.8 0.25 0.05 0.11 0.16 -0.004 0.57 -0.04 -0.05 0.192 0.98 0.68 0.033 0.09 -0.22 -0.17 0.38 0.04 0.126 0 0 0.7 0.99 -0.04 -0.04 0.05 0 0 0.65 0.29 0.01 0.04 0.18 0.05 0.05 0.05 0.06 0.03 0.022 0.03 0.05
±95% 0.28 0.44 0.19 8.44 0.03 0.03 0.017 0.032 0.14 0.06 0.044
0.15
0.12 0.01 0.001 0.06 0.008 0.91 1.26 0.18 0.022 0.16 0.035 0.002 0.09 0.06 0.01 0.02 0.009 0.39 0.33 0.37 0.04 0.05 0.02 0.02 0.01 0.038 0.01 0.03
r2
±95%
Conv.
1.34 4.74 5.62 1.35 0.09 0.06 1.03 2.7 4.76 6 1.63 11.17 9.64 6 1.4 1.4 19 19 43 43 44 24 2.52 1.7 1.2 3.5 11 11.6 6 2.54 0.78 15 11.91 4.142 0.94 1.41 3.615 1.88 22.56 24.89 1.081 2.72 7.401 2.24 3.63 - 0.24 - 0.05 0.98 1.26 0.014 0.52 0.17 11.58 11.96 50 2.19 0.16 0.36 0.32 0.3 0.29 0.08 0.062 0.08 0.89
0.45 2.95 1.06 0.84 0.01 0.01 0.11
Y Y Y Y N N Y
0.2
Y
0.16 0.48 0.54
Y Y Y
0.32
N
1.79
Y
3.89 0.011 0.14
N Y N
0.012 0.44 24.54 1.22 0.016 0.37 0.315
Y Y Y Y Y Y
0.04 0.26 0.07 0.15 0.19 0.003
N N N N N Y
1.91 2.32
N N
1.43
Y
0.02 0.02 0.01 0.01 0.005 0.004 0.004 0.01
N N N N N Y N N
Refs. 124 124 124 124 285 336 303 507 303 507 286 286 286 286 369 818 604 606 604 606 528 590 42 590 406 755 590 755 607 47 438 127 247 246 272 401 145 145 145 145 145 145 806 790 347 322 322 347 347 332 640 640 349 349 490 47 322 285 336 285 336 285 303 336 285
References page II-290
TABLE 1. cont'd Monomer 1 Vinyl isobutyl sulfide Vinyl isobutyl sulfide Vinyl isobutyl sulfide Vinyl isopropyl ether Vinyl isopropyl ether Vinyl isopropyl ketone Vinyl isopropyl ketone Vinyl isopropyl ketone Vinyl isopropyl ketone Vinyl isopropyl ketone Vinyl isopropyl ketone Vinyl isopropyl ketone Vinyl isopropyl sulfide Vinyl isopropyl sulfide Vinyl isothiocyanate Vinyl isothiocyanate Vinyl isothiocyanate Vinyl isothiocyanate Vinyl 1-methyl ether Vinyl laurate Vinyl laurate Vinyl laurate Vinyl m-cresyl ether Vinyl m-cresyl ether Vinyl m-cresyl ether Vinyl methanesulfonate Vinyl methyl ketone Vinyl methyl ketone Vinyl methyl ketone Vinyl methyl ketone Vinyl methyl ketone Vinyl methyl ketone Vinyl methyl ketone Vinyl methyl ketone Vinyl methyl ketone Vinyl methyl ketone Vinyl methyl ketone Vinyl methyl ketone Vinyl methyl ketone Vinyl methyl ketone Vinyl methyl ketone Vinyl methyl ketone Vinyl methyl ketone Vinyl methyl ketone Vinyl methyl ketone Vinyl methyl ketone Vinyl methyl ketone Vinyl methyl ketone Vinyl methyl sulfide Vinyl methyl sulfide Vinyl methyl sulfide Vinyl methyl sulfide Vinyl methyl sulfide Vinyl methyl sulfide Vinyl methyl sulfone Vinyl methyl sulfone Vinyl methyl sulfoxide Vinyl methyl sulfoxide Vinyl methyl sulfoxide Vinyl mono-diethyleneglycol ether Vinyl mono-ethyleneglycol ether Vinyl o-cresyl ether Vinyl o-cresyl ether Vinyl o-cresyl ether
Monomer 2 Methacrylate, methyl Methacrylate, methyl Styrene Caprolactam, N-vinylPyrrolidone, TV-vinylMethacrylate, methyl Methacrylate, methyl Styrene Styrene Styrene Vinyl acetate Vinyl acetate Methacrylate, methyl Styrene Acrylonitrile Methacrylate, methyl Styrene Styrene Indene Acrylonitrile Vinyl acetate Vinyl chloride Methacrylate, methyl Vinyl chloride Vinylidene chloride Vinyl acetate Acrylamide Acrylamide Acrylamide, AyV-dimethyl Acrylate, butyl Acrylonitrile Acrylonitrile Indene Indene Methacrylamide Methacrylamide Methacrylate, 2,2,6,6-tetramethyl4-piperidinyl Methyleneglutaronitrile, 2Styrene Styrene Styrene Styrene, 2,5-dichloroTriazine, 4,6-diamino-2-vinylVinyl acetate Vinyl chloride Vinyl phenyl ether Vinyl phenyl ketone Vinylidene chloride Acrylate, methyl Methacrylate, methyl Styrene Styrene Styrene Vinylene carbonate Styrene Vinyl acetate Styrene Styrene, /?-chloroStyrene, /7-methylMethacrylic acid Methacrylate, glycidyl Methacrylate, methyl Vinyl chloride Vinylidene chloride
rx 0.021 0.03 -0.11 0.01 0.03 1.44 0.6 0.26 0.272 0.3 7.87 6.47 0.046 0.16 1.4 0.6 0.37 0.5 0.67 0.04 0.7 0.2 0.2 0.13 0.04 0.206 0.47 0.75 0.1 1.81 1.75 1.39 2.63 2.9 0.25 0.28 0.41 5.05 0.349 0.348 0.27 0.5 0.17 8.3 4.4 0.74 1.8 0.084 0.03 0.15 0.066 0.046 7.72 -0.22 0.55 0.01 0.01 0.01 2.2 0 0.1 0.14 0.04
±95% 0.034 0.02 0.2 0.96 2.09 0.47 0.07 0.046 2.18 0.025 0.068
2.82
0.02 0.004 0.427 0.44 0.23 0.43 0.24 0.11
0.12 0.24
0.068 0.009 0.11
0.086 0.056 0.084 1.68 0.17 0.21
0.01 0.01
r2 0.985 0.88 2.38 0.22 0.87 0.81 0.54 0.46 0.36 0.4 0.3 -0.154 0.822 4.61 0.36 0.85 0.65 0.8 12.64 4 1.4 7.4 3.3 1.23 1.95 0.639 3.99 1.02 0.82 0.8 0.59 0.63 0.2 0.25 3 1.72 0.53 1.24 0.288 0.237 0.35 2 1.35 0.1 0.01 0.671 0.55 0.209 1 4.5 4.46 5 -0.08 1.146 0 3.57 6.46 2.73 0 4.41 1.8 1.33 2.1
±95%
Conv.
0.077 0.02 0.41 1.95 9.3
Y N Y Y Y
0.22 0.05 0.1
Y N Y
0.073 0.064 0.18
Y Y Y
12.59
Y
0.04 0.07 0.014 0.7 0.13 0.36 0.06 0.13
Y Y Y Y Y Y N Y
0.18 0.26
Y Y
0.092 0.023
Y Y
0.68
Y Y
0.034
Y
0.11 0.24 0.17 0.087 0.02
Y Y Y Y Y
0.02 0.1
Y Y
Refs. 303 336 303 215 215 601 794 344 353 599 601 794 303 303 542 422 422 542 750 381 503 450 605 279 279 942 609 609 609 53 140 504 606 606 609 609 664 512 140 353 550 375 243 91 375 423 946 375 195 106 193 195 303 120 195 195 737 737 737 831 780 605 279 279
TABLE 1. cont'd Monomer 1 Vinyl octadecyl ether Vinyl octadecyl ether Vinyl octadecyl ether Vinyl octadecyl ether Vinyl octyl ether Vinyl octyl ether Vinyl octyl ether Vinyl octyl ether Vinyl p-benzylethylcarbinol Vinyl p-benzylethylcarbinol Vinyl p-benzylethylcarbinol Vinyl p-benzylmethylcarbinol Vinyl p-benzylmethylcarbinol Vinyl p-benzylmethylcarbinol Vinyl p-benzylmethylcarbinol Vinyl p-bromobenzoate Vinyl p-bromobenzoate Vinyl p-bromobenzoate Vinyl p-bromobenzoate Vinyl p-chlorobenzoate Vinyl p-chlorobenzoate Vinyl p-chlorobenzoate Vinyl p-chlorobenzoate Vinyl p-chlorophenyl ether Vinyl p-chlorophenyl ether Vinyl p-cresyl ether Vinyl p-cresyl ether Vinyl p-cresyl ether Vinyl p-cyanobenzoate Vinyl p-cyanobenzoate Vinyl p-cyanobenzoate Vinyl p-cyanobenzoate Vinyl/?-cyanobenzoate Vinyl p-methoxybenzoate Vinyl p-methoxybenzoate Vinyl p-methoxybenzoate Vinyl p-methylbenzoate Vinyl p-methylbenzoate Vinyl p-methylbenzoate Vinyl p-tert-butylphenyl ether Vinyl p-terf-butylphenyl ether Vinyl p-vinyloxybenzoate Vinyl pelargonate Vinyl pelargonate Vinyl pelargonate Vinyl pelargonate Vinyl phenyl carbonate Vinyl phenyl carbonate Vinyl phenyl ether Vinyl phenyl ether Vinyl phenyl ether Vinyl phenyl ether Vinyl phenyl ether Vinyl phenyl ether Vinyl phenyl ether Vinyl phenyl ether Vinyl phenyl ether Vinyl phenyl ether Vinyl phenyl ether Vinyl phenyl ether Vinyl phenyl ether Vinyl phenyl ketone Vinyl phenyl ketone Vinyl phenyl ketone Vinyl phenyl ketone
Monomer 2
rx
Acrylonitrile Vinyl acetate Vinyl chloride Vinylidene chloride Acrylonitrile Styrene Vinyl acetate Vinyl chloride Acrylate, butyl Acrylate, methyl Acrylonitrile Acrylonitrile Methacrylate, methyl Styrene Styrene, p-chloroVinyl benzoate Vinyl p-cyanobenzoate Vinyl p-methoxybenzoate Vinyl p-methylbenzoate Vinyl benzoate Vinyl p-cyanobenzoate Vinyl p-methoxybenzoate Vinyl p-methylbenzoate Vinyl chloride Vinylidene chloride Methacrylate, methyl Vinyl chloride Vinylidene chloride Vinyl benzoate Vinyl p-bromobenzoate Vinyl/7-chlorobenzoate Vinyl p-methoxybenzoate Vinyl/7-methylbenzoate Vinyl/7-bromobenzoate Vinyl p-chlorobenzoate Vinyl p-cyanobenzoate Vinyl p-bromobenzoate Vinyl p-chlorobenzoate Vinyl p-cyanobenzoate Vinyl chloride Vinylidene chloride Vinyl chloride Butadiene Styrene Vinyl chloride Vinylidene chloride Vinyl acetate Vinyl acetate Acrylonitrile Caprolactam, N-vinylMethacrylate, methyl Methacrylate, methyl Pyrrolidone, N-vinylStyrene Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloroacetate Vinyl methyl ketone Vinylidene chloride Vinylidene chloride Methacrylate, glycidyl Methacrylate, methyl Styrene Styrene
0 0 -0.1 0 0 0 0 0.1 0.4 0.48 0.31 0.54 0.98 0.94 1 1.17 0.83 1.08 1.05 0.81 0.813 1 0.853 0.63 0.14 0 0.13 0.03 0.878 0.901 1.031 0.63 0.81 0.72 0.699 0.685 0.594 0.682 0.624 0.14 0.05 0.78 0.02 0.01 0.28 0 0.384 0.384 0.23 0.26 0.01 0 0.253 0.01 0.01 0.16 0.17 0.55 0.01 0.433 0.04 0.697 0.59 0.3 0.465
±95%
0.2 0.28 0.15 0.13 0.021 0.29 0.17 0.072 0.014 0.14 0.054 0.05 0.01 0.01 0.004 0.094 0.034 0.028 0.22 0.1 0.1 0.057 0.075 0.045 0.021 0.04 0.02 0.004 0.07
0.083 0.083 0.37 0.32 0.007 0.59 0.03 0.61 0.051 0.03 1.9 0.02 0.03
r2 0.85 4.5 2.1 1.5 0.81 65 3.47 1.9 0.17 0.18 0.04 0.11 0.24 0.98 1 0.716 0.901 0.72 0.594 0.832 1.031 0.699 0.682 1 2.44 2.6 1.17 1.97 0.659 0.83 0.813 0.685 0.624 1.08 1 0.63 1.05 0.853 0.81 1.08 2.04 0.58 26.3 49.5 1.16 4.08 0.85 0.85 2.5 1.3 11.34 2.8 4.48 1.7 1.28 1.06 1.21 0.84 4.4 2.45 2.11 0.719 0.71 0.24 0.21
±95%
0.17 0.26 0.32
Conv.
0.031 0.034 0.1 0.045 0.028 0.028 0.057 0.021 0.04 0.04
N Y Y Y Y Y Y Y Y Y Y Y Y Y
0.02 0.06 0.033 0.021 0.014 0.075 0.04 0.29 0.14 0.22 0.17 0.054 0.1 0.06 0.06 0.06
Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y N
0.23 0.23
Y Y
2.43 5.76
Y Y
0.1
Y
0.14
Y
0.03 1.67
N Y
0.34 0.11
Y N
0.6 0.04 0.042
Y N Y
Refs. 373 372 370 371 373 374 372 370 591 591 591 48 48 48 48 110 110 110 110 110 110 110 110 279 279 605 279 279 110 110 110 110 110 110 110 110 110 110 110 279 279 497 145 145 145 145 675 705 556 214 172 605 214 423 172 279 280 212 423 240 280 946 794 344 353
References page II - 290
Next Page
TABLE 1. cont'd Monomer 1 Vinyl phenyl ketone Vinyl phenyl ketone Vinyl phenyl sulfide Vinyl phenyl sulfide Vinyl phenyl sulfide Vinyl phenyl sulfide Vinyl phenyl sulfide Vinyl phenyl sulfide Vinyl phenyl sulfide Vinyl phenyl sulfide Vinyl phenyl sulfone Vinyl phenyl sulfone Vinyl propionate Vinyl propionate Vinyl propionate Vinyl propionate Vinyl propionate Vinyl propionate Vinyl propionate Vinyl propionate Vinyl propionate Vinyl stearate Vinyl stearate Vinyl stearate Vinyl stearate Vinyl stearate Vinyl stearate Vinyl stearate Vinyl stearate Vinyl sulfone Vinyl sulfone Vinyl tert-butyl ketone Vinyl tert-butyl ketone Vinyl tert-butyl sulfide Vinyl tert-buty\ sulfide Vinyl tert-butyl sulfide Vinyl tert-butyl sulfide Vinyl tert-butyl sulfide Vinyl tert-butyl sulfide Vinyl tert-butyl sulfide Vinyl thiolacetate Vinyl thiolacetate Vinyl thiolacetate Vinyl thiolacetate Vinyl thiolacetate Vinyl thiolacetate Vinyl trichloroacetate Vinyl trimethylammonioethyl ether iodide Vinyl valerate Vinyl, 2-, 2-methyl-4,4,6,6-tetraphenylcyclotrisiloxane Vinyl-tris(trimethoxysiloxy)silane Vinyl-tris(trimethoxysiloxy)silane Vinyl-tris(trimethoxysiloxy)silane Vinyl-tris(trimethoxysiloxy)silane Vinyl-tris(trimethoxysiloxy)silane Vinylacetophenone Vinylacetophenone Vinylanthracene, 9Vinylanthracene, 9Vinylanthracene, 9Vinylanthracene, 9Vinylanthracene, 9Vinylanthracene, 9Vinylbenzoate, /?-, sodium
Monomer 2 Vinyl acetate Vinyl methyl ketone Acrylate, methyl Acrylonitrile Acrylonitrile Benzothiazole, vinylmercaptoMethacrylate, methyl Methacrylate, methyl Styrene Styrene Styrene Vinyl acetate Allyl chloride Butadiene, 2-chloroCarbazole, JV-vinylEthylene Methacrylate, methyl Vinyl acetate Vinyl acetate Vinyl chloride Vinyl chloride Acrylate, methyl Acrylonitrile Butadiene Styrene Vinyl acetate Vinyl acetate Vinyl chloride Vinylidene chloride Methacrylate, methyl Styrene Methacrylate, methyl Styrene Styrene Acrylonitrile Styrene Vinyl acetate Vinyl acetate Vinyl chloride Vinyl chloride Acrylate, methyl Carbazole, Af-vinylStyrene Succinimide, N-vinylVinyl acetate Vinylene carbonate Acrylonitrile Af-Vinylpyrrolidone Vinyl chloride Styrene Acrylonitrile Acrylonitrile Methacrylate, methyl Styrene Styrene Methacrylate, methyl Styrene Acrylate, butyl Acrylate, ethyl Acrylate, methyl Methacrylate, methyl Styrene Styrene Acrylonitrile
T1
±95%
r2
5.81 0.671 -0.02 0.03 0.03 0.24 0.06 0.08 0.019 0.26 -0.31 -0.35 0.62
0.96
-0.06 0.74 0.57 0.11 0.1.1 0.95 0.79 0.85 3.63 3.96 1.562 0.171 0.68
0.081 1.5 0.03 0.98 1 0.6 0.65 0.03 0.078 0.02 -0.39 0.96 0.73 0.24 0.08 0.1 -0.027 0.65 3.2 0.248 0 0.158 0.07 0.07 0.15 0.15 0.23 0.45 0.25 2.47 5.5 13.57 0.047 0 0.277 0.8 0.07 0.08 0.02 0 0.01 1.65 1.12 0.126 0.295 0.08 0.117 0.25 0.3 0.23
0.22 0.02 0.01 0.12 0.09 0.054 0.18 0.16 0.37 0.073
0.007 0.27 0.71 0.17 0.64 0.17 0.16 0.047 0.15 0.46 0.05 0.013 0.073
0.15 0.37 1.04 0.039 0.02 0.014
3.81 0.42 0.054 0.056 0.092 0.043 0.34
1.69 0.67 24 0.98 0.9 1.6 1.35 5.8 4.639 42.5 15.96 0.953 0.9 0.71 3.92 4.5 0.731 1.21 0.3 0.36 0.09 4.36 13 13 3 3 0.8 0.44 4 0.17 0.05 0.041 7.34 11.6 2.006 0.11 3.9 3.85 34 26 24 0.33 0.246 3.717 3.498 2.998 4.068 2.12 2.12 0.174
±95%
Conv.
Refs.
0.057
Y
0.1 0.01 0.01 0.61 0.06
Y N N Y N
0.12 0.27 0.091 0.064
Y N Y Y
0.21
N Y
0.015 4.73 13.32 0.015
Y Y Y Y
0.097 0.14 0.49 0.058 0.11 0.31 0.11 0.024 0.76
Y Y Y Y Y N Y Y Y
0.28
N
0.15
N
0.01 0.9 0.03 0.071
Y Y
794 946 193 285 336 763 239 239 193 239 193 193 438 247 246 605 272 272 425 400 450 537 145 145 145 1 537 145 145 45 45 794 344 353 303 303 598 601 598 601 566 97 566 97 566 186 362 1037 283 626
Y
0.36 0.072 0.046 0.041 0.067 0.04
Y Y Y Y Y Y
0.04
Y
209 573 482 209 482 266 266 123 123 123 123 123 48 175
