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TABLE 1. cont'd Monomer 1 Fumarate, Fumarate, Fumarate, Fumarate, Fumarate, Fumarate, Fumarate,
di-(2-chloroethyl) di-(2-cyanoethyl) di-(2-(methoxyethyl) di-(2-phenylethyl) di-^c-butyl di-terf-amyl di-tert-butyl
Fumarate, Fumarate, Fumarate, Fumarate, Fumarate, Fumarate, Fumarate, Fumarate, Fumarate, Fumarate, Fumarate, Fumarate, Fumarate, Fumarate, Fumarate, Fumarate, Fumarate, Fumarate, Fumarate, Fumarate, Fumarate, Fumarate, Fumarate, Fumarate, Fumarate, Fumarate, Fumarate, Fumarate, Fumarate, Fumarate, Fumarate, Fumarate, Fumarate, Fumarate, Fumarate, Fumarate, Fumarate, Fumarate, Fumarate, Fumarate,
di-terf-butyl di-tert-buty\ di-terf-butyl dibenzyl dibutyl dibutyl dibutyl dibutyl dicyclohexyl dicyclopentyl diethyl diethyl diethyl diethyl diethyl diethyl diethyl diethyl diethyl diethyl diethyl diethyl diethyl diethyl diethyl diethyl diethyl diethyl diethyl diethyl diethyl diethyl diisobutyl diisopropyl diisopropyl diisopropyl diisopropyl diisopropyl diisopropyl diisopropyl
Fumarate, Fumarate, Fumarate, Fumarate, Fumarate, Fumarate, Fumarate, Fumarate, Fumarate, Fumarate, Fumarate, Fumarate, Fumarate, Fumarate, Fumarate, Fumarate,
diisopropyl diisopropyl diisopropyl diisopropyl diisopropyl diisopropyl diisopropyl dimethyl dimethyl dimethyl dioctyl dioctyl dipropyl dipropyl isopropyl butyl isopropyl butyl
Monomer 2 Styrene Styrene Styrene Styrene Styrene Styrene Fumarate, bis(3-[tris(trimethylsiloxy) silyl)propyl Fumarate, dimethyl Maleate, dimethyl Styrene Styrene Diallyl phthalate Imidazole, 1-vinylStyrene Styrene, terf-butoxy Styrene Styrene Acrylonitrile Acrylonitrile Butadiene Butadiene, 2-chloroDiallyl phthalate Ethylene Methacrylate, methyl Methacrylate, methyl A^-Vinylimidazole Styrene Styrene Styrene Styrene Styrene Styrene Styrene Vinyl acetate Vinyl acetate Vinyl chloride Vinyl ethyl ether Vinyl isobutyl ether Vinylidene chloride Styrene Acenaphthalene Acetate, isopropenyl Acrylate, methyl Acrylate, phenyl Acrylonitrile Carbazole, iV-vinylFumarate, bis(3-[tris(trimethylsiloxy) silyl)propyl Isobutylene Methacrylate, methyl Methacrylonitrile Styrene Vinyl acetate Vinyl chloride Vinylidene chloride Fumarate, di-tert-buty\ JV-Vinylimidazole Styrene Diallyl phthalate Pyrrolidone, N-vinylImidazole, 1-vinylStyrene Styrene Styrene
r\
±95%
0 0.09 0.03 O 0.04 0.08 0.67 1.57 18.2 0.04 O 1.01 0.182 0.04 0.01 0.06 0.06 0 0.1 0.25 0.02 1.25 1.91 0.04 0.05 0.191 0.02 0.081 0.11 0.07 0 0.1 0.02 0.443 0.33 0.48 1.63 0.52 0.012 0.05 0.06 0.67 0.091 0.07 0.2 0 0.87 0.42 0.17 0 0.055 0.9 0.49 0.095 0.156 0.252 0.03 0.96 0.04 0.163 0.02 0.01 0.01
r2
±95%
Conv.
0.18 0.07 0.35 0.27 0.55 0.69 0.21 0.365 6.7
0.054
3.4 0.004 0.022 0.005 0.022 0.01 0.007 0.1 0.16 0.038
0.227 0.015 0.04 0.69
0.156 0.011 0.57 0.32 0.02 0.03 0.35 0.18 0.49 0.3 8 10 2.13 6.51 0.01 0.11 40.3 2.1 0.113 0.29 6.3 0.394 0.3 0.31 0.36 0.29 0.011 0.09 0.13 -0.124 0 12.19 0.37 2.57 0.011 1.9 3.4 16 0 0.07 0 23 85 0.4 0.012 0.29 48 1.57 0.133 0.39 0.02 0.02 0.009 0.32 0.42 0.3
Refs. 1038 1038 1038 1038 1038 1038 1040
0.227 0.037
Y Y
0.01
Y
Y 1.14 0.6
N N
0.019
Y
0.26 0.06
Y Y
0.02
N
0.004
Y
0.1 0.059
Y Y
1.58
Y
0.365 0.021
Y Y
0.01 0.012
N Y
1049 1049 1038 1038 665 614 1038 1077 1038 1038 470 640 466 61 665 41 28 394 879 1038 139 139 139 249 562 640 137 718 137 194 640 59 1038 1039 1038 1038 1038 1038 1038 1040 1038 1038 1038 1038 1038 1038 1038 1049 879 1038 665 121 614 1038 1056 1056
TABLE 1. cont'd Monomer 1 Fumarate, isopropyl isobutyl Fumarate, isopropyl methyl Fumarate, isopropyl sec-butyl Fumarate, methyl butyl Fumarate, methyl ethyl Fumarate, methyl isobutyl Fumarate, methyl isopropyl Fumarate, methyl propyl Fumarate, methyl 5ec-butyl Fumarate, methyl terf-amyl Fumarate, methyl tert-bvXy\ Fumarate, mono-2-butyl Fumarate, tert-buiyl 2-ethylhexyl Fumarate, terr-butyl 4-methyl-2-pentyl Fumarate, tert-b\xiy\ ethyl Fumarate, terf-Butyl isoamyl Fumarate, tert-buiy\ methyl Fumarate, tert-bxxtyX sec-butyl Fumaricacid Fumaronitrile Fumaronitrile Fumaronitrile Fumaronitrile Fumaronitrile Fumaronitrile Fumaronitrile Fumaryl chloride Fumaryl chloride Furan, 2,3-dihydroFuran, 2-vinyl-5-methyl Furan, 2-vinyl-5-methyl Furan, 2-vinyl-5-methyl Hex-3-yne-5-ene, 2-methyl-terf-butyl peroxide Hexatriene, tetrachloroHexatriene, tetrachloroHexatriene, tetrachloroHexatriene, tetrachloroHexatriene, tetrachloroHexatriene, tetrachloroHexatriene, tetrachloroHexene, 1-, 3,4-dioic anhydride Hexene, 2-, 3,4-dioic anhydride Hexene, 3-, 3,4-dioic anhydride Hexene, 5-, 2,4-dione Hexene, 5-, 2,4-dione Hexene, 5-, 2,4-dione Hexene, 5-, 2,4-dione Hexene, 5-, 2,4-dione Hexene, 5-, 2,4-dione Hexene, 5-, 2,4-dione Hexene, 5-, 2,4-dione Hexene, 5-, 2,4-dione Hexene, 5-, 2,4-dione Hexene, 5-, 2,4-dione Hexene, 5-, 2,4-dione Hexene-1 Hexene-1 Hexene-1 Hexene-1, 2,5-dicarboxylate, dimethyl Imidazole, 1-vinyl Imidazole, 1-vinylImidazole, 1-vinylImidazole, 1-vinyl-
Monomer 2 Styrene Styrene Styrene Styrene Styrene Styrene Styrene Styrene Styrene Styrene Styrene Styrene Styrene Styrene Styrene Styrene Styrene Styrene N-vinylimidazole Benzothiazole, vinylmercaptoMethacrylate, methyl Styrene Styrene Styrene Styrene Styrene, a-methylStyrene Vinyl acetate Styrene Acrylate, butyl Methacrylate, isobutyl Methacrylate, methyl Maleic anhydride Acrylate, methyl Acrylonitrile Butadiene, 2-chloroIsoprene Methacrylate, methyl Styrene Vinyl acetate Styrene Styrene Styrene Styrene Styrene Styrene Styrene Styrene Styrene Styrene Styrene Styrene Styrene Styrene Styrene Acrylate, methyl Acrylonitrile Vinyl chloride Styrene Triazole, 1-N-vinyl-1,2,4Acrylic acid Fumarate, dibutyl Fumarate, dipropyl
rx 0.01 0.16 0.02 0.02 0.02 0.03 0.16 0.05 0.02 0.06 0.03 - 0.04 0.01 0.01 0.04 0.06 0.03 0.07 0.313
±95%
0.03
0.012
r2 0.46 0.3 0.54 0.36 0.32 0.32 0.3 0.28 0.45 0.53 0.45 0.33 0.54 0.57 0.25 0.45 0.45 0.55 0.121
±95%
Conv.
0.03
N
0.01
Y Y Y Y Y
-0.064 -0.016 0.006 0
0.096 0.021 0.031
6.74 0.202 0.294 0.3
0.79 0.058 0.044
-0.01
0.078
0.094
0.02
0.051 0.169 0.292
20 0.118 0.105 0.183 0.01
0.019 0.044 0.146
Y Y Y
0.087 0.05
Y Y
0.057 0.042
Y Y Y Y Y Y
0 0.392 0.716 0.867 0.36 3.19 4.01 0.2 1.58 1.76 0.85 -0.052 -0.08 -0.54 1.22 1.38 1.52 1.73 1.91 1.91 2.07 2.46 2.69 2.93 3.19 4.11 -0.67 -1.08 -1.72 0.196 0.32 0.03 0.009
1.36 1.25
0.28 0.22 1 1.17 5.83
0.262 0.234 3.6 0.58 0.504 0.123
9.23 0.043
8.57 3.63 17.17 0.031 0.049 0.066 0.07 0.171 0.179 0.173 0.121 0.24 0.014 0.044 0.028 -0.13 2.07 1.54 0.678
0.01 0.012
0.002 0.182 0.163
0.03
8.4 5.6 436
0.6 0.98 0.031
0.054 0.069
Y Y Y Y
Y Y N Y N Y Y
Refs. 1056 1056 1056 1056 1056 1056 1056 1056 1056 1056 1056 249 1056 1056 1056 1056 1056 1056 879 763 191 137 199 478 77 77 91 91 806 1105 1105 1105 637 5 4 459 459 5 4 4 933 933 933 931 931 931 931 931 931 931 931 931 931 931 931 60 60 329 828 972 955 614 614
References page II - 290
TABLE 1. cont'd Monomer 1 Imidazole, 1-vinylImidazole, 1-vinylImidazole, 1-vinylImidazole, 1-vinylImidazole, 1-vinylImidazole, 1-vinylImidazole, 1-vinylImidazole, 1-vinylImidazole, l-vinyl-2-methylImidazole, l-vinyl-2-methylImidazole, l-vinyl-2-methylImidazole, l-vinyl-2-methylImidazole, l-vinyl-2-methylImidazole, l-vinyl-2-methylImidazole, N-vinylImidazole, N-vinylImidazole, TV-vinylImidazolid-2-one, 1,3-divinylImidazolid-2-one, l-ethyl-3-vinylIndene Indene Indene Indene Indene Indene Indene Indene Indene Indene Indene Isobutene Isobutylene Isobutylene Isobutylene Isobutylene Isobutylene Isobutylene Isobutylene Isobutylene Isobutylene Isobutylene Isobutylene Isobutylene, 3-chloroIsobutylene, 3-chloroIsobutylene, 3-chloroIsobutylene, 3-chloroIsooctene Isoprene Isoprene Isoprene Isoprene Isoprene Isoprene Isoprene Isoprene Isoprene Isoprene Isoprene Isoprene Isoprene Isoprene Isoprene Isoprene Isoprene
Monomer 2 Maleate, dibutyl Maleate, dipropyl Maleate, monomethyl Maleic acid Methacrylate, methyl Pyrrolidone, N-vinylStyrene Vinyl acetate Acrylate, methyl Methacrylate, methyl Methacrylate, methyl Styrene Styrene Vinyl chloride Silane, methacryloxypropyldimethoxy methylSilane, methacryloxypropyltrimethoxyStyrene, /?-trimethyoxysilylAcrylate, ethyl Acrylate, ethyl Acrylate, methyl Acrylate, methyl Acrylonitrile Acrylonitrile Styrene, /?-chloroVinyl acetate Vinyl 1-menthyl ether Vinyl methyl ketone Vinyl methyl ketone Vinylidene chloride Vinylidene chloride Maleimide, Af-cyclohexylAcrylonitrile Acrylonitrile Acrylonitrile Ethylene, chlorotrifluoroFumarate, diisopropyl Maleic anhydride Vinyl acetate Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Allyl acetate Vinyl acetate Vinyl chloride Vinylidene chloride Maleimide, JV-cyclohexylAcetylene, phenylAcrylate, methyl Acrylonitrile Butadiene Butadiene Butadiene, 2,3-dimethylButadiene, 2-chloroButadiene, 2-fluoroButadiene, hexafluoroFerrocene, ethyl-oc-cyclo-pentadienylide Hexatriene, tetrachloroMethacrylate, methyl Methacrylate, methyl Methacrylate, methyl Pyridine, 2-vinylPyridine, 2-vinylPyridine, 4-vinyl-
T1 0.486 0.314 0.4 0.3 0.014 0.96 0.071 1.9 0.05 0.047 0.003 0.09 0.07 2.15 0.079 0.158 0.002 -0.08 0.01 0.1 0.12 0.09 0.07 -0.069 8.64 12.64 0.2 0.25 0.293 0.34 0.41 0 0.02 0 0.06 0 0.012 0.17 0.06 0.268 -0.54 0.08 4.5 0 0 0 0.72 3.01 0.75 0.45 1.06 0.608 1.18 0.06 0.25 1.19 0.01 0.58 0.65 0.64 0.64 0.59 0.58 0.32
±95% 0.057 0.028 0.03 0.19 0.029 6.99 0.088 0.064 0.26 0.04 0.03 0.01 0.25 0.24 0.066 2.8 12.59 0.095 0.85 0.002 0.38 0.03 0.19 0.8 0.043 5.8
0.062 0.12
0.23
r2
±95%
Conv.
Refs. 614 614 724 635 364 364 364 364 465 364 479 364 479 154 1095
0.093 0.053 0.6 0.6 4.36 0.16 9.94 -0.11 1.28 4 3.48 8.87 8.97 0.188 1.39
0.08 0.035
Y Y
1.86 0.074 0.24 1.17
Y Y Y Y
0.54
Y
0.62
Y
0.077
Y
2.27 6.9 0.41 0.47 0.63 0.62 0.281 0.29 2.86 0.39 0.67 2.63 2.9 0.49 -0.02 0 1.295 0.98 1.02 0.01 0.42 0.065 1.66 2.04 2.12 1.2 1.54 0.15 0.13 0.31 1.1 0 0.1 0.12 0.03 0.94 0.14 0.84 2.82 2.63 0.78 1.91 1.58 0.26 0.25 0.25 0.47 0.46 2.49
1.12
Y
0.13 0.06
N N
0.05 0.12 0.83 0.2 2.82
Y Y Y Y Y
0.15 1.15
Y Y
0.008 0.25
Y Y
0.02
N
0.18 1.82 0.2 2.05
Y Y Y N
0.37
Y
0.96
Y
0.21
Y
1088 1095 800 800 606 606 360 360 6 360 750 606 606 6 6 995 21 211 484 318 1038 988 211 140 155 329 560 412 475 475 470 995 648 424 417 173 83 173 418 174 453 699 459 302 698 704 456 458 424
TABLE 1.
cont'd
Monomer 1 Isoprene Isoprene Isoprene Isoprene Isoprene Isoprene Isoprene, 3-acetoxyIsoprene, 3-acetoxyIsoprene, 3-acetoxyIsopropenyl acetate Isopropenyl acetate Isopropenyl acetate Isopropenyl acetate Isopropenyl methyl ketone Isopropenyl methyl ketone Isopropenyl methyl ketone Isopropenyl methyl ketone Isopropenyl methyl ketone Isopropenyl methyl ketone Isopropenyl, 3-(l-cyclohexenyl), acetate Isopropenyl, 3-(l-cyclohexenyl), acetate Isopropenyl, 3-(l-cyclohexenyl), acetate Isopropenyl-, p-, phenol glycidyl ether Isopropenylacetophenone, pIsopropenylisocyanate Isopropenylisocyanate Isopropenylisocyanate Isopropenylisocyanate Isopropenylisocyanate Isopropenylisocyanate Isopropenylisocyanate Isopropenylisocyanate Isopropenylisocyanate Isopropenyltoluene Isopropenyltoluene Isopropylidene, 2,3:4,5-di-0-, -1 - vinylbenzyl- (3-D-fructose Itaconamate, N-(4-carboethoxyphenyl)-, butyl Itaconamate, Af-(4-carboethoxyphenyl)-, ethyl Itaconamate, N-(4-carboethoxyphenyl)-, ethyl Itaconamate, N-(4-carboethoxyphenyl)-, methyl Itaconamate, Af-(4-carboethoxyphenyl)-, propyl Itaconamate, A^-(4-carboethoxyphenyl)-, propyl Itaconamate, A^-(4-chlorophenyl)-, ethyl Itaconamate, N-(4-chlorophenyl)-, ethyl Itaconamate, A^-(4-chlorophenyl)-, methyl Itaconamate, Af-(4-chlorophenyl)-, propyl Itaconamate, A^-(4-chlorophenyl)-, propyl Itaconamate, Af-(4-methoxyphenyl)-, butyl Itaconamate, N-(4-methoxyphenyl)-, ethyl Itaconamate, A^-(4-methoxyphenyl)-, ethyl Itaconamate, N-(4-methoxyphenyl)-, methyl Itaconamate, Af-(4-methoxyphenyl)-, propyl Itaconamate, AH4-methoxyphenyl)-, propyl Itaconamate, Af-(4-methylphenyl)-, propyl Itaconamate, Af-(4-methylphenyl)-, propyl
Monomer 2 Quinoline, 2-vinylStyrene Styrene Styrene Styrene Styrene Acrylate, methyl Methacrylate, methyl Styrene Maleic anhydride Methacrylate, methyl Vinyl acetate Vinyl chloride Acrylonitrile Acrylonitirle Butadiene, 2-chloroStyrene Styrene Vinylidene chloride Acrylate, methyl Methacrylate, methyl Styrene Maleic anhydride Styrene Acrylate, ethyl Acrylate, methyl Acrylate, methyl Acrylonitrile Methacrylate, methyl Styrene Styrene Vinyl chloride Vinylidene chloride Methacrylate, methyl Methacrylate, methyl Styrene
r\ 1.88 1.922 1.957 1.98 2.02 1.3 5.71 2.81 4.47 0.034 -0.09 1.082 0.23 1.2 0.7 0.14 0.29 0.66 4.06 0.57 0.4 0.56 0.003 0.84 0.15 0.11 0.079 0.1 0.14 0.07 0.122 3 0.31 0.04 0.04 3.26
±95%
0.016 0.011
0.022 0.12 0.074 0.16 0.01 0.66
0.59 0.047
0.047
1.12
r2 0.53 0.513 0.476 0.44 0.42 0.48 0.27 0.16 0.34 0.002 17.36 1.171 2.26 0.3 0.36 4.035 0.44 0.32 0.134 0.37 0.81 1.59 0.002 0.3 0.79 0.6 0.799 0.24 3.1 8.12 6.84 0.39 0.85 0.68 0.68 0.14
±95%
Conv.
0.02 0.018
Y Y
0.011 1.95 0.038 0.13
Y Y Y Y
0.087
Y
0.099
Y
0.18
Y
0.049
Y
0.18
Y
0.055
Y
Refs. 456 366 366 544 544 83 770 770 770 260 100 100 100 490 542 259 542 542 47 770 770 770 937 266 434 434 99 434 434 434 99 777 434 688 722 772
Styrene
0.61
0.2
678
Methacrylate, methyl
0.48
1.21
678
Styrene
0.2
0.23
678
Styrene
0.58
0.15
678
Methacrylate, methyl
0.53
1
678
Styrene
0.4
0.26
678
Methacrylate, methyl Styrene Styrene Methacrylate, methyl Styrene Styrene Methacrylate, methyl Styrene Styrene
0.36 0.16 0.18 0.31 0.31 0.69 0.43 0.34 0.41
1.24 0.35 0.38 1.26 0.39 0.12 1.31 0.33 0.26
678 678 678 678 678 678 678 678 678
Methacrylate, methyl
0.4
1.03
678
Styrene
0.4
0.38
678
Methacrylate, methyl Styrene
0.28 0.19
1.11 0.54
678 678
References page II - 290
TABLE 1. cont'd Monomer 1 Itaconamate, N-(4-methylphenyl)-, butyl Itaconamate, Af-(4-methylphenyl)-, ethyl Itaconamate, A^-(4-methylphenyl)-, ethyl Itaconamate, Ar-(4-methylphenyl)-, methyl Itaconamate, N-phenyl-, butyl Itaconamate, N-phenyl-, ethyl Itaconamate, N-phenyl-, ethyl Itaconamate, N-phenyl-, methyl Itaconamate, N-phenyl-, methyl Itaconamate, Af-phenyl-, propyl Itaconamate, Af-phenyl-, propyl Itaconate, bis(2-ethylhexyl) Itaconate, bis(tri-w-butyltin) Itaconate, bis(tri-rc-butyltin) Itaconate, bis(tri-n-butyltin) Itaconate, bis(tri-rc-butyltin) Itaconate, di-2[-2(2-methoxyethoxy)ethoxy]ethyl Itaconate, di-^-butyl Itaconate, diamyl Itaconate, dibutyl Itaconate, dibutyl Itaconate, dibutyl Itaconate, dibutyl Itaconate, diethyl Itaconate, diethyl Itaconate, diethyl Itaconate, dimenthyl Itaconate, dimenthyl Itaconate, dimenthyl Itaconate, dimenthyl Itaconate, dimethyl Itaconate, dimethyl Itaconate, dimethyl Itaconate, dimethyl Itaconate, dimethyl Itaconate, dimethyl Itaconate, dimethyl Itaconate, dimethyl Itaconate, dimethyl Itaconate, dimethyl Itaconate, dioctyl Itaconate, dipropy Itaconate, ethyl hexafluoroisopropyl Itaconate, glycidyl methyl Itaconate, mono-methyl Itaconate, mono-methyl Itaconate, mono-methyl Itaconate, mono-methyl Itaconate, mono-methyl Itaconate, mono-methyl Itaconate, mono-methyl Itaconate, mono-methyl Itaconate, monomethyl Itaconic acid Itaconic acid Itaconic acid Itaconic acid Itaconic acid Itaconic acid mono(/?-sulfamidoanilide) Itaconic anhydride Itaconic anhydride Itaconic anhydride Itaconic anhydride Itaconic anhydride
Monomer 2 Styrene Methacrylate, methyl Styrene Styrene Styrene Methacrylate, methyl Styrene Styrene Styrene Methacrylate, methyl Styrene Maleimide, N-cyclohexylAcrylate, 2-chloroethyl Acrylate, butyl Methacrylate,allyl N-Vinylpyrrolidone Styrene Maleimide, N-cyclohexyl Styrene Itaconate, dimethyl Methacrylate, methyl Methacrylate, methyl Styrene Pyridine, 2-methyl-5-vinylStyrene Vinyl chloride Maleimide, 7V-cyclohexylMethacrylate, methyl Styrene Vinyl acetate Acrylate, butyl Itaconate, dibutyl Methacrylate, methyl Methacrylonitrile Pyridine, 2-methyl-5-vinylStyrene Styrene Styrene Styrene, /?-chloroVinyl chloride Styrene Styrene Styrene Styrene Methacrylate, 2-naphthyl Methacrylate, 2-naphthyl Methacrylate, 2-naphthyl Methacrylate, 2-naphthyl Styrene Styrene Styrene Styrene Methacrylate, methyl Acrylonitrile Methacrylate, methyl Methacrylate, methyl Styrene Styrene Methacrylate, propargyl Acrylate, 2-chloroethyl Acrylate, 2-chloroethyl Acrylonitrile Methacrylate, methyl Styrene
rx 0.31 0.63 0.26 0.16 0.49 0.47 0.21 0.52 0.18 0.15 0.18 0.38 0.391 0.422 0.038 0.065 0.2 0.34 0.5 1.1 0.717 0.4 0.34 0.17 0.34 5.65 0.318 -0.156 0.483
±95%
0.04 0.015 0.04 0.09 0.11 0.05 0.12 0.213 0.02 0.364
r2 0.19 1.43 0.38 0.3 0.12 1.32 0.45 0.31 0.39 1.13 0.5 0.34 0.683 0.91 1.08 0.21 0.53 0.21 0.36 1.1 1.33 0.8 0.42 0.51 0.23 0.06 0.601 3.34 0.502
0.94 1.1 0.3 0.28 0.22
0.4 1.1 1.2 1.26 0.88
0.14 0.06 0.15 5 0.14 0.28 0.039 0.041 0.31 0.36 0.135 0.04 0.111 0.33 0.33 0.218 0.139 0.86 0 0 0 0.12 0.58 2.46 2.61 4.83 1.17 0.405
0.48 0.5 0.69 0.05 0.33 0.16 0.435 0.376 0.52 0.59 0.223 0.189 0.029 0.34 0.52 0.404 1.1 0.59 1.23 1.14 0.34 0.26 1.65 -0.016 0.251 0.034 0.155 0.004
±95%
0.013 0.022 0.04 0.05
Conv.
Y
N
0.09 0.06
N
0.11
N
0.193 0.557 0.188
Y Y Y Y
N
0.12 0.06 0.035 0.079 0.42 0.21 0.028 0.11 0.052 0.15 0.11 0.086 0.103 0.74
0.67 0.05 0.38 0.32 0.33 0.33 0.09
0.16 0.07 0.025 0.036 0.16 0.14 0.02 0.055 0.039 0.077 0.085 0.06 0.071 0.34
0.08 0.02 0.022 0.021 0.014 0.024 0.01
N N N Y Y Y Y Y Y Y Y Y Y
Y Y Y Y Y Y
Refs. 678 678 678 678 678 678 678 1059 678 678 678 1060 940 940 940 941 1098 1014 39 398 1073 398 39 545 39 480 975 975 975 975 398 398 398 398 545 39 398 586 398 479 39 39 1103 806 613 613 613 613 656 656 656 656 1010 164 260 408 420 76 957 365 365 365 1010 365
TABLE 1. cont'd Monomer 1 Itaconic anhydride Itaconic anhydride Itaconic anhydride Itaconic anhydride Itaconimide, AH2-chloroethyl)Itaconimide, AK2-chloroethyl)Itaconimide, AH4-acetoxyphenyl)Itaconimide, Af-(4-chlorophenyl)Itaconimide, N-(4-ethoxycarbonylphenyl)Itaconimide, N-(p-chlorophenyl)Itaconimide, N-(p-lo\y\)Itaconimide, Af-benzylItaconimide, Af-benzylItaconimide, Af-butylItaconimide, iV-ethylItaconimide, JV-ethylItaconimide, N-isobutylItaconimide, AMsopropylItaconimide, N-methylItaconimide, N-methylItaconimide, N-naphthylItaconimide, W-phenylItaconimide, Af-phenylItaconimide, N-phenylItaconimide, N-propylItaconimide, N-XxAyV Malemic acid, A^-3-dimethylamino6-methylphenylMalemic acid, A^-3-dimethylamino6-methylphenylMaleate, chloro-, diethyl Maleate, dibutyl Maleate, allyl methyl Maleate, butyl stannylallyl Maleate, di-tert-butyl Maleate, dibutyl tin Maleate, dibutyl tin Maleate, diethyl Maleate, diethyl Maleate, diethyl Maleate, diethyl Maleate, diethyl Maleate, diethyl Maleate, diethyl Maleate, diethyl Maleate, diethyl Maleate, diethyl Maleate, diethyl Maleate, diethyl Maleate, diethyl Maleate, diethyl Maleate, diethyl Maleate, diethyl Maleate, diethyl Maleate, diethyl Maleate, diethyl Maleate, diethyl Maleate, dimethyl Maleate, dimethyl Maleate, dimethyl Maleate, dimethyl Maleate, dimethyl Maleate, dimethyl Maleate, dimethyl Maleate, dioctyl
Monomer 2 Styrene Styrene Vinyl acetate Vinyl acetate Methacrylate, Styrene Styrene Styrene Styrene Styrene Styrene Methacrylate, Styrene Styrene Methacrylate, Styrene Styrene Styrene Methacrylate, Styrene Styrene Styrene Styrene Styrene Styrene Styrene Butadiene
rx 0.456 0.785 1.57 2.87 0.54 0.162 0.21 0.2 0.112 0.14 0.24 1.06 0.2 -0.019 0.42 0.172 -0.03 0.045 1.12 0.12 0.35 0.109 0.08 0.998 0.04 0.219 - 0.08
Styrene Styrene Imidazole, 1-vinylStyrene Styrene Vinyl acetate Methacrylate, methyl Styrene Acrylonitrile Acrylonitrile Butadiene Carbazole, N-vinylEthylene Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl iV-Vinylimidazole Styrene Styrene Styrene Styrene Styrene Vinyl acetate Vinyl chloride Vinyl chloride Vinyl chloride Vinyl isobutyl ether Vinylidene chloride Carbzole, Af-vinylFumarate, di-tert-butyl N-Vinylimidazole Styrene Styrene Succinimide, Af-vinylVinyl acetate Vinyl chloride
methyl
methyl methyl
methyl
±95%
±95%
Conv.
Refs.
0.015 0.005 0.045 0.024 0.11 0.045 0.12 0.084 0.032
Y Y Y Y Y Y Y Y Y
0.18 0.048 0.03 0.066 0.029 0.11 0.043 0.22 0.069
Y Y Y Y Y Y Y Y Y
0.043
Y
0.123 0.18 0.079 0.03
0.086 0.003 -0.019 - 0.04 0 0.069 0.35 0.159 0.232 0.15 0.16 0.46 0.056 0.22 0.486 0.232 0.44 0.308 0.38 0.153 0.08 0.116 0.05 0.05 0.28 0.134 0.37
0.248 0.12 0.031 0.04
N Y Y N
62 62 365 365 642 642 729 729 729 740 740 642 642 642 642 642 642 642 642 642 740 729 740 978 642 729 679
-0.19
0.03
0.55
0.03
N
679
-0.043 0.093 0.02 0.06 0.199 -0.095 0.194 0 0 0.11 0 10 -0.1 0 -0.02 0.106
0.021 0.08 0.01 0.03 0.02 0.199 0.121
2.07 0.486 8.29 0.1 0.005 72.7 2.08 12 20 8.08 0.21 0.25 341 20 285.8 0.057
0.14 0.057 0.14 0.02 0.024 5.93 0.118
Y Y N N Y Y Y
0.05
N
14 614 713 811 1049 987 987 470 640 466 361 41 28 470 873 879 14 139 640 874 888 137 137 449 6 640 3 361 1049 879 137 317 284 1049 3
-0.013 0.07 0.01 0.001 0.04 -0.003 0 0.046 0.17 12.5 0 0.011 0.046 0.15 0.105 -0.012 0.257 0.608
0.09 0.05 0.3 0.32 0.39 0.092 0.21 0.18 0.054
r2
0.75 0.11 0.04 0.13 0.06 0.11 0.064 0.73 0.12 0.082
0.01 0.05 0.015 0.147 0.022 0.01 0.012 0.044 0.07 0.01 0.037 0.438 0.12 0.058 0.021 0.086 0.099
6.59 8 6.07 6.592 0.171 0.768 0.8 0.9 0 0.51 18.2 0.046 10.65 0.083 1.25 -0.006 0.05
46
N
35.9 0.028 0.46
Y Y Y Y
0.07
N
0.025 0.078
Y Y
0.11
Y
0.11 6.7 0.046 2.81 0.015 0.16 0.084 0.14
N Y Y Y Y Y Y Y
References page II - 290
TABLE 1. cont'd Monomer 1 Maleate, dipropyl Maleate, monoallyl Maleate, monoallyl Maleate, monomethyl Maleate, tributylstannyl allyl Maleic Anhydride Maleic acid Maleic acid Maleic anhydride Maleic anhydride Maleic anhydride Maleic anhydride Maleic anhydride Maleic anhydride Maleic anhydride Maleic anhydride Maleic anhydride Maleic anhydride Maleic anhydride Maleic anhydride Maleic anhydride Maleic anhydride Maleic anhydride Maleic anhydride Maleic anhydride Maleic anhydride Maleic anhydride Maleic anhydride Maleic anhydride Maleic Maleic Maleic Maleic Maleic Maleic Maleic Maleic Maleic Maleic Maleic Maleic Maleic Maleic Maleic Maleic Maleic Maleic Maleic Maleic Maleic Maleic Maleic Maleic Maleic Maleic Maleic Maleic Maleic Maleic Maleic Maleic Maleic Maleic Maleic Maleic
anhydride anhydride anhydride anhydride anhydride anhydride anhydride anhydride anhydride anhydride anhydride anhydride anhydride anhydride anhydride anhydride anhydride anhydride anhydride anhydride anhydride anhydride anhydride anhydride anhydride anhydride anhydride anhydride anhydride anhydride anhydride anhydride anhydride anhydride anhydride anhydride
Monomer 2 Imidazole, 1-vinylMaleic anhydride Styrene Imidazole, 1-vinylMaleic anhydride Isopropenyl-, /?-, phenol glycidyl ether Imidazole, 1-vinylN-Vinylimidazole Acenaphthalene Acenaphthalene Acetylene, phenylAcrolein diethylacetal Acrylamide Acrylate, 2-chloroethyl Acrylate, ferrocenylmethyl Acrylate, methyl Acrylate, methyl Acrylonitrile Allyl acetate Allylbenzene Benzocyclobutane, oc-methyleneBenzothiazole, vinylmercaptoButadiene monoxide Butadiene, 2-chloroCarbamate, AUV-diethyl-, vinyl Dicyclopentadiene Divinylbenzene, p Ethylene Hex-3-yne-5-ene, 2-methyl-terf-butylperoxide Isobutylene Isopropenyl acetate Maleate, monoallyl Maleate, tributylstannyl allyl Maleimide, N-phenylMaleimide, N-phenylMethacrylate, ferrocenylmethyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, di-, di-rc-butylstannyl Methacrylate, benzyl Methacrylate, benzyl Phthalimide, N-vinylPropene, 1-chloro-, cisPropene, 1-chloro-, transStyrene Styrene Styrene Styrene Styrene Styrene Styrene Styrene Styrene Styrene Styrene Styrene Styrene Styrene Styrene, a-methyl-
rx
±95%
0.053 0.027 0.07 0.6 0.095 0.002 0.6 0.094 0.02 -0.04 0.06 0.07 0 0.027
0.035 0.014 0.02
0.012 0 0 0.028
0.013
0.104 0.027 0.05
0.004
0.019
0.025
r2 0.314 0.051 0.14 0.4 0.032 0.003 0.3 0.018 0.46 0.46 0.08 0.18 0.56 7.15 2.788 2.5 6 -0.001
±95%
Conv.
Refs.
0.028 0.054 0.01
Y N N
0.017
N
0.007
Y
0.13
N
0.31 2.96 0.051
Y Y Y Y
614 906 811 724 906 937 635 879 1039 326 797 767 655 117 325 260 470 470 27 351 1083 763 1064 1068 92 914 943 620 637
0.007
Y Y
0.002 Y
0.64 0.329 0.025 0.071 0.09 0 0.01 0.065 0.002 0.051 0.032 -0.095 0.02 0.24 -0.163 -0.019 0.08 0.02 0.01 0.01 0.01 0.02 0.024 0.372 0.008 0.347 0.28 0.001 0 0.003 0.02 0 0 0.02 0.01 0.001 0.005 0.01 0.02 0.05
0.06 0.107 0.034 0.045 0.01
0.011 0.054 0.017 0.106 0.65 0.28 0.027 0.026 1.77 0.004
0.008 0.093 0.012 0.082 0.012 0.008 0.13 0.03 0.01
0.05 0.026 0.024 0.037 0.01 0.04 0.36 0.012 0.034 0.027 0.095 1.08 1.92 0.33 4.18 6.36 0.46 5.2 3.1 3.85 3.4 3.85 0.012 - 0.075 0.344 -0.022 0.05 0.097 0.04 0.02 0 0.02 0.02 0.04 0.04 0.04 0.05 0.02 0.04 0.04
0.18 0.03 0.066 0.112 0.01
N Y Y
0.022 0.014 0.104 0.13 11.83 0.65 0.31 0.64 0.69 0.47
Y N N Y Y Y Y Y N N
0.016
Y Y Y Y Y Y N Y N N
0.088 0.061 0.08 0.015 0.002 0.12 0.003 0.01
N 0.08
0.04
988 260 906 906 990 341 325 169 260 320 33 524 524 524 524 954 720 720 284 181 181 105 12 17 241 384 397 483 506 522 522 522 522 522 923 492
TABLE 1. cont'd Monomer 1 Maleic anhydride Maleic anhydride Maleic anhydride Maleic anhydride Maleic anhydride Maleic anhydride Maleic anhydride Maleic anhydride Maleic anhydride, a-chloroMaleimide Maleimide Maleimide Maleimide Maleimide Maleimide Maleimide, N-hydroxymethyl Maleimide, 2,3-dimethylAf-(2-methacryloxyethyl)Maleimide, 2,3-dimethylAf-(2-methacryloxyethyl)Maleimide, 2,3-dimethylAf-(2-methacryloxyethyl)Maleimide, A^-(2,4-dimethylphenyl)Maleimide, N-(2,4-dimethylphenyl)Maleimide, N-(2,6-diethylphenyl)Maleimide, A^-(2,6-diethylphenyl)Maleimide, A^-(2,6-diisopropylphenyl)Maleimide, Af(2,6-dimethylphenyl)Maleimide, J/V-(2,6-dimethylphenyl)Maleimide, A^-(2-bromophenyl)Maleimide, AH2-chlorophenyl)Maleimide, N-(2-chlorophenyl)Maleimide, iV-(2-chlorophenyl)Maleimide, iV-(2-chlorophenyl)Maleimide, N-(2-chlorophenyl)Maleimide, A^-(2-chlorophenyl)Maleimide, N-(2-hydroxyethyl)Maleimide, 7V-(2-hydroxyethyl)Maleimide, iV-(2-hydroxyethyl)Maleimide, A^-(2-hydroxyethyl)Maleimide, A^-(2-hydroxyethyl)Maleimide, A^-(2-hydroxyethyl)Maleimide, TV-(2-methylphenyl)Maleimide, iV-(3,5-dimethylphenyl)Maleimide, AK3-dimethylaminophenyl)Maleimide, N-(3-methylphenyl)Maleimide, A^-(3-trifluoromethylphenyl)Maleimide, A^-(4-bromophenyl)Maleimide, A^-(4-bromophenyl)Maleimide, A^-(4-carboxyethylphenyl)Maleimide, JV-(4-carboxyethylphenyl)a-chloroMaleimide, A^-(4-carboxyethylphenyl)a-chloroMaleimide, A^-(4-chlorophenyl)Maleimide, A^-(4-chlorophenyl)Maleimide, 7V-(4-chlorophenyl)Maleimide, A^-(4-chlorophenyl)Maleimide, N-(4-chlorophenyI)-a-chloroMaleimide, A^-(4-chlorophenyl)-a-chloroMaleimide, iV-(4-hydroxyphenyl)Maleimide, A^-(4-hydroxyphenyl)Maleimide, AT-(4-hydroxyphenyl)Maleimide, Af-(4-hydroxyphenyl)-
Monomer 2
rx
Succinimide, N-vinyl0.021 Vinyl 2-chlorocyclohexyl ketone 0.83 Vinyl 4-chlorocyclohexyl ketone 0.08 Vinyl acetate -0.058 Vinyl chloride -0.22 Vinyl chloride 0.4 Vinyl chloride 0.67 Vinylidene cyanide Styrene 0 Butadiene, 2,3-bis(diethyl-phosphono)0.43 Methacrylate, methyl 0.166 Methacrylate, methyl 0.17 Piperidinol, 4-, TV-methyl0.49 4-(vinylethynyl)Styrene 0.088 Vinylidene chloride 0.464 Methacrylate, methyl 0.263 Acrylate, ethyl 1.55
±95% 0.027
0.074 0.38
r2 0.148 1.7 0.12 0.019 0.098 0.04 0.1
±95%
Conv.
0.073
Y
0.008 0.042
Y Y
Y
Refs. 284 836 836 260 260 521 521 82 845 759 251 992 948
0.061
0.01
0.07 0.14 2.576 2.5 2.05
0.036 0.083 0.026 3.06
0.057 0.666 1.745 0.28
0.012 0.056 0.03 1.15
Y Y Y Y
251 251 323 619
0.047
Y
0.03
Methacrylate, methyl
1.1
3.58
0.51
1.66
Y
619
Methacrylic acid
1.33
0.1
0.746
0.059
Y
619
Acrylate, butyl Acrylate, heptyl Methacrylate, methyl Styrene Methacrylate, methyl Methacrylate, methyl Styrene Acrylonitrile Acrylonitrile Methacrylate, methyl Styrene Styrene Styrene Styrene Butadiene, 2,3-bis(diethyl-phosphono)Methacrylate, methyl Pyrrolidone, TV-vinylStyrene Vinyl acetate Vinyl acetate Methacrylate, methyl Methacrylate, methyl Styrene Methacrylate, methyl Methacrylate, methyl Acrylate, methyl Styrene Vinyl chloride Methacrylate, methyl
0.2 0.2 0.05 0.02 0.02 0.07 0.08 0.338 1.078 0.1 0.013 0.028 0.01 0.006 0.49 0.201 0.038 0.011 0.61 0.88 0.09 0.28 0.19 0.22 0.1 0.39 0.018 3.29 -0.004
0.17 0.007 0.18 0.168
0.62 0.14 4.78 0.19 10.9 3.62 0.14 2.029 0.956 2.1 0.011 0.038 0.013 0.038 0.12 1.396 0.002 0.046 -0.014 0.01 2.22 1.63 0.03 1.18 1.57 0.429 0.02 0.04 0.472
0.045 0.048 0.002 0.003 0.005 0.003 0.083 0.01 0.027 0.12 0.17
0.214 0.095
Y Y
0.004 0.006 0.012 0.28
Y Y Y Y
0.089 0.002 0.017 0.037 0.041
Y Y Y Y Y
0.099 0.006 0.03 0.114
Y N Y
788 788 992 992 992 992 992 863 863 992 853 853 910 910 759 323 323 323 323 323 992 992 747 992 992 628 1030 306 973
Styrene
0.022
0.041
0.059
0.021
Y
973
Acrylate, methyl Acrylonitrile Butadiene, 2,3-bis(diethyl-phosphono)Vinyl chloride Methacrylate, methyl Styrene Methacrylate, methyl Styrene Vinyl acetate Butadiene, 2,3-bis(diethyl-phosphono)-
0.155 0.743 0.41 3.65 0.02 0.019 0.345 0.13 1.75 0.47
0.052 0.048
0.684 0.972 0.03 0.026 0.562 0.149 1.392 -0.059 -0.011 0.04
0.052 0.112
Y Y
0.044 0.025 0.048 0.001 0.041 0.027
Y Y Y Y Y Y
628 863 759 306 973 973 323 323 323 75
0.39 0.03 0.038 0.001 0.1 0.17
References page II - 290
TABLE 1. cont'd Monomer 1 Maleimide, A^-(4-methoxyphenyl)-a-chloroMaleimide, AH4-methoxyphenyl)-a-chloroMaleimide, TV-(4-methylphenyl)Maleimide, TV-(4-methylphenyl)Maleimide, AK4-methylphenyl)-a-chloroMaleimide, iV-(4-methylphneyl)-a-chloroMaleimide, TV-(4-tolyl)Maleimide, TV-(P-chloroethyl)-a-chloroMaleimide, AHP-chloroethyl)-oc-chloroMaleimide, TV-(p-chloroethyl)-a-chloroMaleimide, TV-(L-menthoxycarbonylmethyl)Maleimide, TV-(L-menthoxycarbonylmethyl)Maleimide, TV-2-bromophenylMaleimide, TV-2-chlorophenylMaleimide, TV-4-chlorophenylMaleimide, TV-[TV'-a-methylbenzyl) aminocarbonylpentyl]Maleimide, TV-[TV'-a-methylbenzyl) aminocarbonylpenty 1] Maleimide, TV-[TV'-a-methylbenzyl) aminocarbonylpenty I]Maleimide, TV-a-methylbenzylMaleimide, TV-a-methylbenzylMaleimide, TV-allylMaleimide, TV-benzylMaleimide, Maleimide, Maleimide, Maleimide, Maleimide, Maleimide, Maleimide, Maleimide, Maleimide, Maleimide, Maleimide, Maleimide, Maleimide, Maleimide, Maleimide, Maleimide, Maleimide, Maleimide, Maleimide, Maleimide, Maleimide, Maleimide, Maleimide, Maleimide, Maleimide, Maleimide, Maleimide, Maleimide, Maleimide, Maleimide, Maleimide, Maleimide, Maleimide, Maleimide, Maleimide, Maleimide,
TV-benzylTV-benzylTV-benzyl-a-chloroTV-butylTV-butylTV-butylTV-butylTV-chloromethylTV-cyclohexyliV-cyclohexylTV-cyclohexylTV-cyclohexylTV-cyclohexylTV-cyclohexylTV-cyclohexylTV-cyclohexylTV-cyclohexylTV-cyclohexylTV-cyclohexylTV-cyclohexylTV-cyclohexylTV-ethyl-a-chloroTV-ethyl-a-chloroTV-hexylTV-hexyliV-hydroxymethylTV-hydroxymethylTV-methyl-a-chloroTV-methyl-a-chloroTV-octadecylTV-octadecylTV-phenylTV-phenylTV-phenylTV-phenylTV-phenyl-
Maleimide, TV-phenyl-
Monomer 2
T1
±95%
Methacrylate, methyl Styrene Methacrylate, methyl Vinyl chloride Methacrylate, methyl Styrene Acrylate, methyl Methacrylate, methyl Methacrylate, methyl Styrene Maleimide, TV-benzyl Maleimide, TV-phenyl-
0.064 0.049 0.34 4.49 0.029 0.019 0.14 0.05 0.11 0 0.848 0.79
0.189 0.061
Acrylonitrile Acrylonitrile Acrylonitrile Methacrylate, methyl Styrene
r2
±95%
Conv.
Refs.
0.145 0.031
Y Y
0.34 0.158 0.078 0.16 0.04 0.05 0.06 0.221 0.261
0.556 0.112 0.83 0.022 0.564 0.107 0.64 0.94 0.59 0.29 0.474 0.798
0.048 0.117 0.048 0.16 0.06 0.06 0.05 0.087 0.141
Y Y Y Y
Y Y
973 973 992 306 973 973 644 974 974 974 1089 1089
0.348 1.08 0.743 0.582
0.044 0.048 0.048 0.359
2.02 0.955 0.972 1.37
0.205 0.095 0.112 0.291
Y Y Y Y
915 915 915 1099
0.258
0.25
0.198
0.143
Y
1099
Y
1099 1055 1055 1003 1089
Styrene Maleimide, TV-cyclohexyl1.07 Maleimide, TV-phenyl0.683 Styrene 0.035 Maleimide, TV-(L-menthoxycarbonyl0.474 methyl)Methacrylate, methyl 0.03 Styrene 0.013 Styrene 0 Methacrylate, methyl -0.1 Styrene Styrene 60 Vinyl chloride -12.7 Butadiene, 2,3-bis(diethyl-phosphono)0.3 Methacrylate, methyl 0.24 Acenaphthalene 0.11 Butene, cis-20 Isobutene 0 Itaconate, bis(2-ethylhexyl) 0.34 Itaconate, di-n-butyl 0.21 Itaconate, dimenthyl 0.601 Maleimide, TV-a-methylbenzyl0.392 Methacrylate, methyl 0.19 Methacrylate, methyl 0.106 Styrene 0.1 Styrene 0.162 Isooctene 0 Methacrylate, methyl 0.13 Styrene 0 Methacrylate, methyl 0.1 Styrene 0.09 Styrene 0.06 Vinyl acetate 1.45 Methacrylate, methyl 0.11 Styrene 0 Acrylonitrile 0.389 Acrylonitrile 0.39 Acrylate, methyl 0.103 Butadiene, 2,3-bis(diethyl-phosphono)0.42 Maleic anhydride 1.92 Maleic anhydride 1.08 Maleimide, TV-(L-menthoxycarbonyl0.798 methyl)Maleimide, TV-a-methylbenzyl0.788
0.177 0.177
0.214 0.5
Y Y
0.087
0.392 0.788 0.056 0.848
0.221
Y
0.23 0.031 0.06 0.16
1.28 0.058 0.42 1.41
0.23 0.021 0.06 0.19
Y Y
1.13
Y
0.04 0.213 0.177
Y Y
0.066
Y
0.017
Y
106.2
0.04 0.193 0.214 0.048 0.054 0.03 0.04 0.15 0.16 0.11 0.21 0.03 0.03 0.023 0.023 0.052 11.83 0.13 0.141 0.5
0.02 0.24 0.05 1.35 0.57 3 0.41 0.38 0.34 0.318 1.07 1.31 2.26 0.102 -0.01 0.72 0.53 0.9 1.9 -0.041 -0.035 0.017 0.63 0.63 2.482 2.46 0.554 0.05 0.02 -0.095 0.79
0.04 0.05 0.2 0.069 0.053 0.037 0.34 0.04 0.119 0.115 0.048
Y Y Y
0.65 0.106 0.261
Y Y Y
348 348 974 115 115 50 305 759 992 1039 995 995 1060 1014 975 1055 1100 348 1100 348 995 974 974 348 348 323 323 974 974 863 915 644 759 341 990 1089
0.683
0.177
Y
1055
Y Y
Y Y Y Y
TABLE 1. cont'd Monomer 1 Maleirnide, W-phenylMaleimide, N-phenylMaleimide, N-phenylMaleimide, N-phenylMaleimide, 7V-phenylMaleimide, N-phenylMaleimide, iV-phenylMaleimide, JV-phenylMaleimide, N-phenyl-a-chloroMaleimide, N-phenyl-a-chloroMaleimide, N-propylMaleimido-A^V-dimethylaniline, 4-(2-chlorophenyl)azo Mesaconate, dibenzyl Mesaconate, di-seobutyldithiol Mesaconate, diamyl Mesaconate, dibenzyldithiol Mesaconate, dibutyl Mesaconate, dibutyldithiol Mesaconate, dicyclohexyl Mesaconate, diethyl Mesaconate, diethyldithiol Mesaconate, dihexyl Mesaconate, diisoamyl Mesaconate, diisobutyl Mesaconate, diisobutyldithiol Mesaconate, diisopropyl Mesaconate, diisopropyldithiol Mesaconate, dimethyl Mesaconate, dimethyldithiol Mesaconate, dioctyl Mesaconate, diphenyl Mesaconate, diphenyldithiol Mesaconate, dipropyl Mesaconate, dipropyldithiol Mesaconic acid Methacryl-2'-ethyl-4,5J-trinitro9-fluorenone-2-carboxylate Methacrylamide Methacrylamide Methacrylamide Methacrylamide Methacrylamide Methacrylamide Methacrylamide Methacrylamide Methacrylamide Methacrylamide Methacrylamide, 1-deoxy-D-glucitol Methacrylamide, AK2-hydroxypropyl)Methacrylamide, A^-(4/-nitro-4-stilbenyl)Methacrylamide, iV-(4-stilbenyl)Methacrylamide, N-(p-chloroprienyl)Methacrylamide, N-(/?-methoxyphenyl)Methacrylamide, Af-(/?-methyrphenyl)Methacrylamide, 7V-(/?-nitrophenyl)Methacrylamide, A^-[4-(4-methoxyphenylacetyloxy)phenyl]Methacrylamide, iV-methoxymethylMethacrylamide, Af-/?-bromophenylMethacrylamide, N-p-tolylMethacrylamide, N-phenyl Methacrylamide, N-phenylMethacrylamide, N-phenyl-
Monomer 2 Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Styrene Styrene Styrene Vinyl acetate Vinyl chloride Methacrylate, methyl Styrene Vinyl chloride Styrene
rx 0.3 0.164 0.3 0.044 0.01 1.284 4.01 0.077 - 0.002 2.38 0.04
0.065 0.017 0.046 0.18 0.098 0.073 0.16
r2 0.98 1.014 0.91 0.016 0.07 -0.003 0.023 0.657 0.087 0.06 0.05
Conv.
0.06
Y
0.004
N Y
0.006 0.026 0.083 0.04 0.05
Y Y Y Y N
Refs. 323 328 992 1026 328 992 328 306 973 973 305 747
0.593 0.7 0.627 0.559 0.549 2.34 0.29
0.047 0.23 0.051 0.048 0.06 1.07
1.474 1.842 0.399 0.337 0.336 0.37 1.47
0.05 0.062 0.019 0.019 0.026 0.14
Y Y Y Y Y Y
342 342 352 352 352 352 1051
Methacrylate, Methacrylate, Methacrylate, Methacrylate, Acrylonitrile Methacrylate,
0.265 0.38 0.78 0.28 0.71 0.56
0.009 0.2 0.2 0.2 0.19 0.12
1.678 3.48 1.43 1.95 0.381 1.42
0.048 0.2 0.2 0.2 0.085 0.096
Y
227 968 968 968 352 352
methyl
1.27 0.425 0.49 0.33 1.28 0.2 0.48 1.24 3 1.72 0.56 1.01
0.014 0.24 0.085 0.25 0.014 0.2 0.38 0.18 0.26 0.09
0.73 0.45 1.27 0.28 1.28 0.41 1.25 1.24 0.4 1.51 1.34 1.29 0.41 1.31 0.44 0.98 0.35 1.23 0.45 0.16 1.22 0.39 1.6 0.63
±95%
Styrene Styrene Styrene Styrene Styrene Styrene Styrene Styrene Styrene Styrene Styrene Styrene Styrene Styrene Styrene Styrene Styrene Styrene Styrene Styrene Styrene Styrene Styrene Methacrylate, AT-(2-hydroxyethyl)carbazolyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylic acid Methacrylic acid Methacrylic acid Styrene Styrene Vinyl methyl ketone Vinyl methyl ketone Vinyl acetate Acrylamide, AH2-(4-hydroxyphenyl)ethyl)Methacrylate, 2-hydroxyethyl Methacrylate, 2-hydroxyethyl Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Methacrylate, 2-hydroxyethyl methyl methyl methyl methyl
0.08 0.02 0.02 0.06 0.05 0.05 0.1 0.06 0.03 0.1 0.07 0.1 0.03 0.04 0.05 0.04 0.07 0.01 0.07 0.15 0.05 0.06 0 0.382
±95%
1.57 1.39 1.65 2.73 1.55 2.006 1.4 1.42 0.25 0.28 0.16 0.95
0.041
Y
0.11 0.074
N Y
0.28
Y
0.09 0.13 0.17 0.12 0.24
Y N N Y Y
0.09
Y Y
658 624 658 624 658 624 658 658 624 658 658 658 624 658 624 658 624 658 658 624 658 624 1021 703 316 54 55 190 527 55 316 316 609 609 258 965
References page II - 290
TABLE 1. cont'd Monomer 1 Methacrylamide, N-phenylMethacrylamide, 1-deoxy-D-glucitol Methacrylamide, 1-deoxy-D-glucitol Methacrylamide, Af-/?-nitrophenylMethacrylate, 2-ethylhexyl Methacrylate, ferrocenylmethyl Methacrylate, ferrocenylmethyl Methacrylate, octyl Methacrylate, potassium 18-crown6-ether Methacrylate, tert-butyl Methacrylate, (-)-menthyl Methacrylate, (2,2-dimethyl1,3-dioxolane-4-yl)methyl Methacrylate, 1,1-diphenylethyl Methacrylate, 1-naphthyl Methacrylate, 1-naphthyl Methacrylate, 1-naphthyl Methacrylate, 1-naphthyl Methacrylate, 2,2,6,6-tetramethyl4-piperidinyl Methacrylate, 2,2,6,6-tetramethyl4-piperidinyl Methacrylate, 2,2,6,6-tetramethyl4-piperidinyl Methacrylate, 2,2,6,6-tetramethyl4-piperidinyl Methacrylate, 2,2-dimethylaminoethyl Methacrylate, 2,3-epithiopropyl Methacrylate, 2,3-epithiopropyl Methacrylate, 2,3-epithiopropyl Methacrylate, 2,3-epithiopropyl Methacrylate, 2,4,6-trinitrophenyl Methacrylate, 2,4-dinitrophenyl ethyl Methacrylate, 2,4-dinitrophenyl Methacrylate, 2,6-(diphenyl)phenyl Methacrylate, 2-(2-carboxybenzoyloxy)ethyl Methacrylate, 2-(2-carboxybenzoyloxy)ethyl Methacrylate, 2-(N,Ar-dimethylcarbamoyloxy)ethyl Methacrylate, 2-(AW-dimethylcarbamoyloxy)ethyl Methacrylate, 2-(N,N-dimethylcarbamoyloxy)ethyl Methacrylate, 2-(AW-dimethyl carbamoyloxy)ethyl Methacrylate, 2-(N,AT-dimethylcarbamoyloxy)ethyl Methacrylate, 2-acetoxyethyl Methacrylate, 2-acetoxyethyl Methacrylate, 2-acetoxyethyl Methacrylate, 2-acetylsalicylicoyloxy3-hydroxypropyl Methacrylate, 2-bromoethyl Methacrylate, 2-bromoethyl Methacrylate, 2-bromoethyl Methacrylate, 2-bromoethyl Methacrylate, 2-bromoethyl Methacrylate, 2-bromoethyl Methacrylate, 2-chloro-2,3,3,3-fluoropropyl
Monomer 2
rx
±95%
Styrene Methacrylate, methyl Styrene Methacrylate, methyl Methacrylate, 2-hydroxypropyl Maleic anhydride Pyrrolidone, Af-vinylMethacrylonitrile Acrylonitrile
0.88 0.04 0.005 0.29 0.083 0.33 2.57 0.61 0.175
0.17
Methacrylate, 2-chloroethyl Acenaphthalene Methacrylate, methyl
0.98 0.316 1.1
0.22 0.085
Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Acrylonitrile
methyl methyl methyl methyl methyl
Styrene Vinyl acetate
0.77 1.8 1.68 2.62 1.52 14
0.2 0.006 0.65 2.77 0.05 0.018
0.73 0.38 0.47
r2
±95%
Conv.
1.24 4.2 2.09 5.05 4.56 0.24 0.073 0.75 0.07
0.06
N
0.2 0.18 0.28 0.096 0.04 0.006
Y Y Y N Y
1.18 2.48 0.9
0.11 0.55
Y Y
0.14 0.078 0.084
Y Y Y
0.72 0.77 0.809 0.851 0.61 0.02
Refs. 352 258 258 968 708 325 325 44 808 179 645 807 761 752 752 752 761 664
0.3
0.63
664
13.7
0.2
664
0.41
664
Vinyl methyl ketone
0.53
Methacrylate, methyl Acrylate, methyl Methacrylate glycidyl Methacrylate, methyl Styrene Methacrylate, 2-naphthyl Acrylate, AK2-hydroxyethyl)-oxy) 3,6-dichloro Methyacrylate, A^-(2-hydroxyethyl)3,6-dichloro Methacrylate, methyl Methacrylate, butyl
1.01 2.81 0.78 0.97 0.28
0.54
0.42 0.34 0.81 0.83 0.41
0.02
N
1.207
0.032
0.115
0.029
Y Y
1.112
0.026
0.126
0.026
Y
0.071 0.85
0.004
1.42 0.75
0.06
Methacrylate, butyl
0.85
0.75
1041
Acrylate, butyl
1.89
0.47
600
Acrylate, methyl
1.32
0.22
600
Acrylonitrile
1.89
0.38
600
Butadiene
0.35
1.06
600
Methacrylate, methyl
0.42
0.59
600
Methacrylate, 2-hydroxyethyl Methacrylate, methyl Styrene Af-Vinylpyrrolidone
0.99 1.12 0.58 0.85
Acrylate, ethyl Acrylonitrile Methacrylate, methyl Pyrrolidone, N-vinylStyrene Vinyl butyl ether Acrylate, butyl
2.7 2.38 1.18 2.44 0.41 13.7 0.221
0.02 0.06 0.04
0.636
1.02 0.94 0.44 0.34 0.37 0.31 0.79 0.02 0.32 0 0.079
0.01 0.02 0.02
0.304
691 787 787 787 787 744 736
1079 1009
N N N
N
346 346 346 1080 657 657 657 657 657 657 927
TABLE 1. cont'd Monomer 1 Methacrylate, propyl Methacrylate, propyl Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate,
Monomer 2
r2
±95%
Conv.
Refs.
Methacrylate, methyl
0.583
1.17
0.984
0.395
N
927
2-chloro-2,3,3,3-fluoro-
Styrene
0.243
0.15
0.121
0.068
N
927
2-chloroethyl 2-chloroethyl 2-chloroethyl 2-chloroethyl 2-chloroethyl 2-chloroethyl 2-chloroethyl 2-chloroethyl 2-chloroethyl 2-chloroethyl 2-chloroethyl 2-chloroethyl 2-chloroethyl 2-ethylhexyl 2-hydroxyethyl
Acrylate, methyl Acrylonitrile Methacrylate, benzyl Methacrylate, butyl Methacrylate, isobutyl Methacrylate, methyl Methacrylate, methyl Methacrylate, phenyl Methacrylate, tert-buiy\ Styrene Styrene Styrene Methacrylate, tributyltin Methacrylate, 2-hydroxypropyl Acetamide, 7V-(4-methacryloyloxyphenyl)-2-(4-methoxy) Acetanilide, 4-(2-(methacryloyloxy) ethyloxy) Acetanilide, 4-(2-(methacryloyloxy) hexyloxy) Acetanilide, 4-(methacryloyloxy)Acrylamide Acrylamide Acrylamido, 2-,2-methylpropanesulfonic Acrylate, butyl Acrylate, ethyl Acrylate, furfuryl Acrylate, methyl Acrylonitrile Acryloxymethylpentamethyl disiloxane Methacrylate, 2-hydroxypropyl Methacrylamide, AK4'-nitro-4-stilbenyl)Methacrylamide, J/V-(4-stilbenyl)Methacrylamide, Af-[4-(4-methoxyphenylacetyloxy )phenyl] Methacrylate, 2-acetoxyethyl Methacrylate, dodecyl Methacrylate, dodecyl Methacrylate, dodecyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacryloxymethylpentamethyl disiloxane Pyridine, 2-vinylPyridine, 3-vinylPyridine, 4-vinylPyrrolidone, N-vinylStyrene Styrene Styrene Styrene Styrene Styrene Styrene Acrylamido, 2-, 2-methylpropanesulfonic Acrylate, butyl Acrylate, butyl Acrylate, ethyl Acrylate, ethyl
2.19 1.3 0.989 0.82 0.85 0.97 0.48 1.02 1.18 0.341 0.34 0.23 0.53 0.083 0.61
Methacrylate, 2-hydroxyethyl Methacrylate, 2-hydroxyethyl Methacrylate, 2-hydroxyethyl Methacrylate, 2-hydroxyethyl Methacrylate, 2-hydroxyethyl Methacrylate, 2-hydroxyethyl Methacrylate, 2-hydroxyethyl Methacrylate, 2-hydroxyethyl Methacrylate, 2-hydroxyethyl Methacrylate, 2-hydroxyethyl Methacrylate, 2-hydroxyethyl Methacrylate, 2-hydroxyethyl Methacrylate, 2-hydroxyethyl Methacrylate, 2-hydroxyethyl Methacrylate, 2-hydroxyethyl 2-hydroxyethyl 2-hydroxyethyl 2-hydroxyethyl 2-hydroxyethyl 2-hydroxyethyl 2-hydroxyethyl 2-hydroxyethyl 2-hydroxyethyl
Methacrylate, 2-hydroxyethyl Methacrylate, 2-hydroxyethyl Methacrylate, 2-hydroxyethyl Methacrylate, 2-hydroxyethyl Methacrylate, 2-hydroxyethyl Methacrylate, 2-hydroxyethyl Methacrylate, 2-hydroxyethyl Methacrylate, 2-hydroxyethyl Methacrylate, 2-hydroxyethyl Methacrylate, 2-hydroxyethyl Methacrylate, 2-hydroxyethyl Methacrylate, 2-hydroxypropyl Methacrylate, Methacrylate, Methacrylate, Methacrylate,
±95%
2-chloro-2,3,3,3-fluoro-
Methacrylate, 2-hydroxyethyl
Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate,
T1
2-hydroxypropyl 2-hydroxypropyl 2-hydroxypropyl 2-hydroxypropyl
0.098 0.041 0.14 0.18 0.21 0.11 0.075 0.08 0.16 0.006
0.29 0.14 1.068 1.086 1.014 1.156 0.55 0.785 0.98 0.35 0.345 0.42 0.2 4.56 1.49
0.042 0.02 0.064 0.082
Y Y Y Y
0.083 0.22 0.046 0.048
Y Y Y Y
0.444 0.18
N Y
726 382 179 179 179 179 382 179 179 179 179 382 945 692 1051
1.39
0.67
1096
1.19
0.87
1096
0.78 1.89 0.98 0.86 4.75 11.21 1.35 8.67 1 0.86 0.55 1.474 1.842 1.47
1.94 0.05 0.14 0.9 0.09 0.189 0.88 - 0.005 0.2 0.52 1.82 0.593 0.7 0.29
1096 689 928 618 358 358 1063 358 689 822 686 342 342 1051
1.02 11.2 1.6 0.8 0.63 0.81 1.5 0.97 0.56 0.69 0.62 4.841 0.54 0.856 0.65 1.65 0.53 0.59 1.65 0.89 5.35 3.3 13.32 9.08
4.2 0.43 0.08 8.28
0.05 0.062 0.01
0.076 1.02
0.04 0.01 0.04 0.133 0.03 0.018
0.32 6.82 1.05 3.95
0.11 0.008 0.19 0.036
Y
0.047 0.23
Y Y
0.02
N
0.01 0.09
Y Y
0.64 0.73 0.9 -0.019 0.44 0.332 0.57 0.5 0.59 0.53 0.5 1.03
0.16 0.04 0.09 0.046 0.02 0.006
N N N Y N Y
342 342 342 840 346 350 463 878 878 903 903 618
0.171 0.24 0.273 0.207
0.041 0.16 0.054 0.045
Y Y Y Y
333 662 333 662
0.99 0.7 0.5 0.8 0.824 0.192 0.75 0.33
Y Y
346 837 837 837 350 358 710 822
References page II - 290
TABLE 1. cont'd Monomer 1 Methacrylate, 2-hydroxypropyl Methacrylate, 2-hydroxypropyl Methacrylate, 2-hydroxypropyl Methacrylate, 2-hydroxypropyl Methacrylate, 2-hydroxypropyl Methacrylate, 2-hydroxypropyl Methacrylate, 2-hydroxypropyl Methacrylate, 2-hydroxypropyl Methacrylate, 2-hydroxypropyl Methacrylate, 2-hydroxypropyl Methacrylate, 2-hydroxypropyl Methacrylate, 2-hydroxypropyl Methacrylate, 2-naphthyl Methacrylate, 2-naphthyl Methacrylate, 2-naphthyl Methacrylate, 2-naphthyl Methacrylate, 2-naphthyl Methacrylate, 2-naphthyl Methacrylate, 2-naphthyl Methacrylate, 2-naphthyl Methacrylate, 2-naphthyl Methacrylate, 2-naphthyl Methacrylate, 2-naphthyl Methacrylate, 2-naphthyl Methacryiate, 2-naphthyl Methacrylate, 2-naphthyl Methacrylate, 2-naphthyl Methacrylate, 2-naphthyl Methacrylate, 2-naphthyl-, methyl Methacrylate, 2-naphthyl-, methyl Methacrylate, 2-naphthyl-, methyl Methacrylate, 2-naphthyl-, methyl Methacrylate, 2-sulfonic acid)ethyl Methacrylate, 2-sulfonic acid)ethyl Methacrylate, 2-sulfonic acid)ethyl Methacrylate, 2-sulfonic acid)ethyl Methacrylate, 2-methoxyethyl Methacrylate, 3,5-dimethyladamantyl Methacrylate, 3,5-dimethyladamantyl Methacrylate, 3,5-dimethyladamantyl Methacrylate, 3,5-dimethyladamantyl Methacrylate, 3-methoxy-2-hydroxypropyl Methacrylate, 5-oxo-pyrrolidinylmethyl Methacrylate, 5-oxo-pyrrolidinylmethyl Methacrylate, p-(2-benzothiazolylthio) ethyl Methacrylate, A^-(2-hydroxyethyl)3,6-dichlorocarbazolyl Methacrylate, N-(2-hydroxyethyl)carbazolyl Methacrylate, JV-(2-hydroxyethyl)carbazolyl Methacrylate, A^-(2-hydroxyethyl)carbazolyl Methacrylate, iV-ot-benzothiazolonylmethyl Methacrylate, iV-ethyl3-hydroxymethylcarbazolyl Methacrylate, N-ethyl-3hydroxymethylcarbazolyl Methacrylate, Af-methyl-N-phenyl2-aminoethyl Methacrylate, A^-methyl-A^-phenyl2-aminoethyl Methacrylate, N-methyl-N-phenyl2-aminoethyl
Monomer 2
T1
±95%
Acrylate, methyl Acryloyl chloride Methacrylate, 2-ethylhexyl Methacrylate, 2-ethylhexyl Methacrylate, 2-hydroxyethyl Methacrylate, butyl Methacrylate, butyl Methacrylate, ethyl Methacrylate, ethyl Methacrylate, methyl Methacrylate, tributyltin Methacrylic acid Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Itaconate, mono-methyl Itaconate, mono-methyl Itaconate, mono-methyl Itaconate, mono-methyl Methacrylate, 2,4,6-trinitrophenyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Styrene Styrene Styrene Styrene Styrene Acrylate, ethyl Methacrylate, ethyl Styrene Vinylidene chloride Styrene Acrylonitrile Methacrylate, methyl Styrene Vinyl chloride Acrylamide Methacrylate, methyl Styrene Vinyl chloride
7.335 1.79 4.56 4.56 1.82 2.35 2.35 1.878 1.844 1.055 1.81 0.31 1.17 1.02 0.76 0.64 0.52 0.59 0.223 0.189
0.083
0.85 2.57 2.53 1.91 4.41 3.83 0.534 0.113 0.321 0.576 0.216 3.2 2 0.6 3.6 0.48 1.3 0.45 0.63 1.85 3.98 0.694 0.411 0.26
0.34 0.48 0.27 0.6 0.76 0.57 0.099 0.126 0.098 0.477 0.422
Methacrylate, 2,4-dinitrophenyl
0.126
Acryl-2/-ethyl-4,5,7-trinitroflourenone
r2
±95%
Conv.
Refs.
0.013 0.29 0.083 0.083 0.55 0.158 0.158 0.245 0.267 0.402 0.728 0.99 0.15 0.094 0.06 -0.01 0.31 0.36 0.135 0.04
0.007
Y
0.006 0.006
Y Y
0.007 0.007 0.007 0.005 0.017 0.517
Y Y Y Y Y N
0.2 0.099 0.1 0.16 0.42 0.21 0.028 0.11
0.75 0.602 0.581 0.532 0.614 0.623 0.56 0.786 0.486 0.61 0.384 0.3 1 0.37 0.22 0.46 0.19 0.68 0.89 0.21 0.04 0.421 0.342 0.64
0.16 0.059 0.023 0.055 0.051 0.048 0.025 0.16 0.117 0.195 0.225
Y Y Y N Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y
0.01 0.04 0.14 0.04
N N N N
0.033 0.013
Y Y
0.026
1.112
0.026
Y
736
0.773
0.096
0.102
0.022
Y
703
Acrylate, 2,4-dinitrophenyl
0.243
0.034
0.186
0.009
Y
716
Methacryl-2/-ethyl-4,5,7-trinitro9-fluorenone Methacrylate, methyl Acryloyl-p-hydroxyethyl3,5-dinitrobenzoate Methacryloyl-P-hydroxyethyl3,5-dinitrobenzoate Acryloyloxy, 2-, benzoic acid
0.63
0.041
0.382
0.014
Y
703
0.6 1.425
0.02 0.09
0.5 0.103
0.01 0.015
Y
887 701
0.729
0.051
0.554
0.019
Y
701
0.22
0.03
1.82
0.2
N
651
Methacrylic acid
0.2
0.01
2.16
0.18
N
651
Methacryloyloxy, 2-,benzoate, methyl
0.55
0.04
1.11
0.18
N
651
0.18 0.18 0.13 0.13 0.056 0.039 0.04 0.275 0.2 0.19 0.18 0.24 0.16 0.14 0.02 0.055
0.23 0.16 0.21 8.87 0.087 0.033
333 649 692 708 686 692 708 692 708 333 945 886 611 611 611 611 613 613 613 613 744 540 760 760 760 760 760 540 924 924 924 924 564 564 564 564 918 335 335 335 335 689 633 633 741
TABLE 1. cont'd Monomer 1
Monomer 2
Methacrylate, N-methyl-Ar-phenyl2-aminoethyl Methacrylate, A^-methyl-A^-phenyl2-aminoethyl Methacrylate, a,a-dimethylbenzyl Methacrylate, oc-naphthoyloxy-, ethyl Methacrylate, acetonyl Methacrylate, allyl Methacrylate, amyl Methacrylate, benzyl Methacrylate, benzyl Methacrylate, benzyl Methacrylate, benzyl Methacrylate, benzyl Methacrylate, benzyl Methacrylate, benzyl Methacrylate, benzyl Methacrylate, benzyl Methacrylate, benzyl Methacrylate, benzyl Methacrylate, benzyl Methacrylate, benzyl Methacrylate, benzyl Methacrylate, benzyl Methacrylate, benzyl Methacrylate, benzylmethylaminoethyl Methacrylate, butyl Methacrylate, butyl Methacrylate, butyl Methacrylate, butyl Methacrylate, butyl Methacrylate, butyl Methacrylate, butyl Methacrylate, butyl Methacrylate, butyl Methacrylate, Methacrylate, Methacrylate, Methacrylate,
butyl butyl butyl butyl
Methacrylate, butyl Methacrylate, butyl Methacrylate, butyl Methacrylate, butyl Methacrylate, butyl Methacrylate, butyl Methacrylate, butyl Methacrylate, butyl Methacrylate, butyl Methacrylate, butyl Methacrylate, butyl Methacrylate, butyl Methacrylate, butyl Methacrylate, butyl Methacrylate, butyl Methacrylate, butyl Methacrylate, butyl Methacrylate, butyl Methacrylate, butyl Methacrylate, butyl Methacrylate, butyl Methacrylate, chloromethyl Methacrylate, chloromethyl
rx
±95%
r2
±95%
Conv.
Methacryloyloxy, 2-,benzoic acid
0.2
0.01
2.6
0.08
N
651
Styrene
0.58
0.02
0.44
0.04
N
651
Methacrylate, methyl Styrene Styrene Itaconate, bis(tri-w-butyltin) Styrene Acrylonitrile Allyl chloride Maleic anhydride Maleic anhydride Methacrylate, 2-chloroethyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, phenyl Styrene Styrene Styrene Styrene Styrene Styrene Vinylidene chloride Methacrylate, methyl Acetylene, phenylAcrylate, butyl Acrylate, ethyl Acrylic acid Acrylic acid, a-bromoAcrylonitrile Carbamate, Af-phenyl-, allyl Methacrylate, 2-(2-carboxybenzoyloxy)ethyl Methacrylate, 2-(2-carboxybenzoyloxy)ethyl Methacrylate, 2-chloroethyl Methacrylate, 2-hydroxypropyl Methacrylate, 2-hydroxypropyl Methacrylate, ethyleneglycolAf-phenylcarbamate Methacrylate, glycidyl Methacrylate, methyl Methacrylate, methyl Methacrylic acid Methacrylic acid Methacrylonitrile Styrene Styrene Styrene Styrene Styrene Styrene Styrene, o-chloroStyrene, p-chloroStyrene p-chloroStyrene chloromethylStyrene/?-octylamine sulfonate Thioindigoid Vinyl acetate Vinyl chloride Vinylidene chloride Methacrylate, methyl Styrene
0.92 0.242 0.505 1.08 0.46 0.96 58.7 - 0.075 1.068 1.112 1.05 1.38 0.67 0.658 0.467 0.51 0.42 0.3 0.5 3.3 0.296 1.7 2.2 2.43 3.53 0.85 0.98 0.418 0.75
0.018 0.115 0.2 0.1 0.088 0.042 0.093 0.06 0.084 0.048
0.38 0.123 0.39 0.42 0.2
0.75
0.372 0.989 0.808 0.93 0.78 1.42 0.463 0.435 0.45 0.48 0.8 0.45 0.34 0.523 0.21 0.3 0.22 0.24 0.13 0.291 0.329 0.85
0.043 0.041
Y
0.11 0.1
Y N
0.093 0.098 0.03
Y Y Y Y
0.09 0.041 0.026
N Y Y
0.32 0.134
Y
0.17 0.21
Y N
0.039
Y
0.85
1.086 0.158 0.158 0.395
0.02 0.007 0.007
0.85 2.11 1.2 1.26 1.15 0.75 0.31 2.52 0.47 0.64 0.64 0.59 0.32
0.03 0.08
0.564 0.38 0.7 11.5 30.18 13.5 2.07 1.02 0.298
0.81 0.216 0.285 0.038 0.52 0.2 0.02
0.12 0.12 0.07 0.2 1.1
0.1 0.131
14.47 0.18 0.16 0.03
0.82 2.35 2.35 0.299 0.94 0.52 1.27 0.8 0.73 0.56 0.56 -0.05 0.52 0.63 0.54 0.74 1.24 1.025 1.46 1.5 0.5 -0.003 0.05 0.35 0.477 0.208
Refs.
761 1102 958 940 179 23 438 720 720 179 111 32 540 32 111 179 487 540 602 806 432 1081 565 187 690 187 733 165 833 1009 1041
0.041 0.13 0.13
Y Y Y
179 692 708 833
0.06 0.07
N N
0.16 0.2 0.15 0.12 1.09
N N N Y N
0.1 0.124
N
0.15
Y
0.03 0.029 0.006
Y Y Y
224 30 844 187 224 44 179 43 463 530 530 835 558 872 966 1035 817 1007 165 519 3 712 712
References page II - 290
TABLE 1. cont'd Monomer 1 Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, titanate Methacrylate, titanate Methacrylate, Methacrylate, Methacrylate,
Monomer 2
T1
cyanomethyl cyanomethyl cyclohexyl cyclohexyl decyl di-, di-n-butylstannyl di-, di-rc-butylstannyl di-, zinc di-, dicyclopentadienyl-
Methacrylate, methyl Styrene Methacrylate, tributyltin Styrene Oxazolidone, TV-vinylMaleic anhydride Vinyl acetate Ethylene Acrylate, di-, copper
0.73 0.28 0.891 0.57 12.19 0.012 0.013 40 0.89
di-, dicyclopentadienyl-
Acrylate, di-, nickel
0.65
di-, ethylene glycol di-, triethyleneglycol di-, triethyleneglycol
Styrene Carbamate, N-phenyl-, allyl Methacrylate, ethylene-glycol Af-phenylcarbamate Methacrylate, methyl Methacrylic acid Methacrylate, methyl Acrylamide Methacrylate, 2-hydroxyethyl Methacrylate, 2-hydroxyethyl Methacrylate, dodecyl Methacrylate, methyl Styrene Allyl acetate Allyl alcohol Methacrylate, 2-(sulfonic acid)ethyl Methacrylate, 2-hydroxypropyl Methacrylate, 2-hydroxypropyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, tributyltin Methacrylic acid Methacrylonitrile Styrene Styrene Styrene Styrene Styrene, o-chloroStyrene, p-chloromethylVinyl acetate Vinylidene chloride Methacrylate, butyl
0.67 0.504 0.59
Methacrylate, diethylaminoethyl Methacrylate, diethylaminoethyl Methacrylate, dimethylaminoethyl Methacrylate, dimethylaminoethyl sulfate Methacrylate, diphenylmethyl Methacrylate, diphenylmethyl Methacrylate, diphenylmethyl Methacrylate, diphenylmethyl Methacrylate, diphenylmethyl Methacrylate, ethyl Methacrylate, ethyl Methacrylate, ethyl Methacrylate, ethyl Methacrylate, ethyl Methacrylate, ethyl Methacrylate, ethyl Methacrylate, ethyl Methacrylate, ethyl Methacrylate, ethyl Methacrylate, ethyl Methacrylate, ethyl Methacrylate, ethyl Methacrylate, ethyl Methacrylate, ethyl Methacrylate, ethyl Methacrylate, ethyl Methacrylate, ethyl Methacrylate, ethyl Methacrylate, ethyleneglycolAf-phenylcarbamate Methacrylate, ethyleneglycolAf-phenylcarbamate Methacrylate, ferrocenylmethyl Methacrylate, ferrocenylmethyl Methacrylate, ferrocenylmethyl Methacrylate, ferrocenylmethyl Methacrylate, ferrocenylmethyl Methacrylate, furfuryl Methacrylate, glycidyl Methacrylate, glycidyl Methacrylate, glycidyl Methacrylate, glycidyl Methacrylate, glycidyl Methacrylate, glycidyl Methacrylate, glycidyl Methacrylate, glycidyl Methacrylate, glycidyl Methacrylate, glycidyl Methacrylate, glycidyl
Methacrylate, di-, triethyleneglycol Acrylate, methyl Acrylonitrile Styrene Styrene Vinyl acetate N-Vinylpyrrolidone Acrylate, 2-ethylhexyl Acrylate, 4-acetylphenyl Acrylate, butyl Acrylate, isobutyl Acrylate, tert-butyl Acrylonitrile Acrylonitrile Methacrylate, 2,3-epithiopropyl Methacrylate, butyl Methacrylate, methyl Methacrylate, methyl
1.44 2.34 1.2 1.9 0.5 0.8 0.7 1.07 0.3 81.27 107.4 1 0.245 0.267 1.08 1 0.601 0.71 0.83 0.36 0.26 0.29 0.33 0.45 0.36 131.8 2.18 0.299
±95% 0.11 0.041 0.136 0.28 1.35 0.016 0.036
0.399 0.144 0.395 0.586 -0.052 0.024 0.013 0.19 1.09
±95% 0.019 0.011 0.428 0.088 0.049 0.008 0.018
Conv. Y Y N Y Y Y Y
0.95 0.08
0.085 1.59 0.154 0.2
0.1 1.93 5.3 0.007 0.005 0.09 0.123 0.05 0.12
29.8 0.1
0.24 0.042 0.82 -0.01 0.01 1.52 5.16 2.41 0.644 2.16 1.24 2.096 0.85 1.32 0.81 0.94 0.52 0.934
r2
0.39 0.034 0.24 0.843 0.63 0.699 0.52 1.6 0.8 11.2 0.81 0.528 -0.57 -0.02 2 1.878 1.844 1.08 1.16 0.299 0.57 0.46 0.55 0.67 0.65 0.55 1.34 1.29 -0.77 0.353 0.395
1.13 0.46 0.13 0.57 0.12 0.443 0.05 0.06 0.06 0.085
1.4 0.15 3.6 0.2 0.0036 0.09 0.292 0.083 0.282 0.463 0.95 0.14 0.78 0.85 0.71 0.726
625 625 945 179 36 954 949 935 876 876
0.15
N
262 833 833
0.128 1.47 0.051 0.05
Y Y Y
0.05 0.82 1.92
Y N N
0.056 0.039
Y Y N
0.19 0.607
N N
0.04 0.062
N Y
5.29 0.02
N Y
1081 16 1081 1052 837 837 837 761 179 210 210 564 692 708 32 844 87 945 820 44 179 530 530 570 558 1035 210 3 833
0.59 0.085 0.42 0.14
Refs.
833 0.35 0.04 3.63
Y Y Y
0.02 0.13 0.141 0.052 0.026 0.079 0.06
Y Y Y Y Y Y N
0.03 0.08 0.042
N Y Y
293 325 293 576 293 1050 674 1012 674 674 814 114 433 787 224 113 226
TABLE 1. cont'd Monomer 1 Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate,
Monomer 2 glycidyl glycidyl glycidyl glycidyl glycidyl glycidyl glycidyl glycidyl glycidyl glycidyl glycidyl glycidyl glycidyl glycidyl hexyl hydroxyethyl
Methacrylate, hydroxyethyl Methacrylate, iso-butyl Methacrylte, isobornyl Methacrylate, isobutyl Methacrylate, isobutyl Methacrylate, isobutyl Methacrylate, isobutyl Methacrylate, isobutyl Methacrylate, isobutyl Methacrylate, isobutyl Methacrylate, isobutyl Methacrylate, isobutyl Methacrylate, isobutyl Methacrylate, isobutyl Methacrylate, isobutyl Methacrylate, isobutyl Methacrylate, isobutyl Methacrylate, isobutyl Methacrylate, isobutyl Methacrylate, isobutyl Methacrylate, m-chlorophenyl Methacrylate, m-nitrophenyl Methacrylate, methoxymethyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl
rx
Methacrylate, methyl 1.05 Methacrylate, methyl 0.501 Methacrylic acid 1.2 Af-Vinylpyrrolidone 4.29 Styrene 0.16 Styrene 0.539 Styrene 0.46 Styrene 0.54 Styrene 0.55 Styrene 0.74 Styrene 0.73 Styrene 0.514 Vinyl phenyl ketone 0.719 Vinyl, mono-, ethylene glycol ether 4.41 Styrene 0.44 Methacrylate, tetra(2-hydroxypropyl) 0.606 ethylenediamine Methacrylate, tributyltin 2.33 Butadiene, 2-chloro0.9 Styrene 0.24 Acetylene, phenyl1.9 Acrylic acid 0.68 Acrylonitrile 1.05 Furan, 2-vinyl-5-methyl 0.105 Methacrylate, 2-chloroethyl 1.014 Methacrylate, methyl 1.88 Methacrylate, methyl 1.2 Methacrylate, methyl 0.488 Methacrylic acid 0.47 Methacrylonitrile 0.68 Methacrylonitrile 0.94 Styrene 0.271 Styrene 0.58 Styrene 0.42 Styrene 0.4 Styrene 0.74 Vinyl acetate 29.7 Styrene 0.209 Styrene 0.185 Styrene 0.586 2-Oxazoline, 2-isopropenyl0.69 3-Pyridazone, 2-vinyl 0.63 3-Pyridazone, 2-vinyl-6-methyl0.16 3-Pyridazone, 2-vinyl-6-methyl1.65 4,5-benz-33-Pyridazone, 2-vinyl-6-phenyl0.58 4H-1,3-Oxazinium F 3 CSO 3 , 3-methyl0.37 2-vinyl-5,6-dihydroAcenaphthalene 0.36 Acenaphthalene 0.38 Acenaphthalene 0.44 Acetamide, N-vinyl2.65 Acetamide, N-vinyl1.18 Acetamide, N-vinyl2.1 Acetylene, phenyl-0.06 Acetylene, phenyl1.5 Acetylene, phenyl1.111 Acrolein 1.136 Acrolein 1.33 Acrolein, methyl0.1 Acrylamide 2.34 Acrylamide 3 Acrylamide 2.53 Acrylamide 3 Acrylamide, 2-chloro-AyV-dimethyl2.71
±95%
0.027 0.1 0.498 0.03 0.04 0.08 0.1 0.284 0.098 0.13 0.416 0.185 0.088 0.3 0.22 0.044 0.064 0.07 0.029 0.05 0.12 0.036
24.16 0.013 0.054 0.069 0.02
r2 0.8 0.688 0.98 0.003 0.54 0.278 0.47 0.44 0.45 0.31 0.11 0.435 0.697 0 0.58 1.44 0.282 1.8 0.61 0.27 1.03 0.217 0.716 0.85 0.62 0.89 0.92 2.01 0.74 0.43 0.509 0.56 0.5 0.55 0.47 -0.06 0.375 0.44 0.395 0.99 1.56 0.3 0.27
±95%
Conv.
0.076 0.16 0.018 0.07 0.086 0.02
Y N
0.04 0.045 0.033
N N Y
0.07 1
Y Y
0.424 0.06 0.45
N N
0.037 0.169 0.14 0.08
Y Y Y N
0.15
Y
0.07 0.08 0.014
N N Y
0.22 0.05 0.16 0.014 0.07
Y Y Y Y
N Y N
0.49 0.31 0.04 0.04
0.16 0.095 0.05 0.4 0.17 0.09 0.45 0.398
1.05 0.99 2.25 0.19 0.71 0.01 1.69 0.2 0.07 0.76 0.59 0.4 2.29 0.53 0.82 0.9 -0.159
Refs. 463 639 224 1017 114 217 225 225 463 849 893 999 946 780 179 996 945 1057 806 565 847 165 1105 179 30 541 639 847 44 44 179 463 463 487 541 165 177 177 821 894 897 897 897 897 909
0.14 0.15
N N
26.56
Y
0.016 0.12 0.3
Y Y N
0.44 0.09
N N
1.07 0.502
N Y
326 326 575 984 984 984 357 443 732 291 292 589 314 314 314 691 917
References page II - 290
TABLE 1. cont'd Monomer 1
Monomer 2
Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate,
methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl
Methacrylate, Methacrylate, Methacrylate, Methacrylate,
methyl methyl methyl methyl
Methacrylate, methyl Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate,
methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl
Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate,
methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl
Acrylamide, N,N-dimethylAcrylamide, AA,A^-dimethylAcrylamide, WV-dimethylAcrylamide, WV-dimethylAcrylamide, N-methylAcrylamide, N-methylolAcrylamide, N-methylol Acrylamide, N-octadecylAcrylamide, N-tert-butylAcrylamide, a-fluoroAcrylamido, 1-,-1-deoxy-D-glucitol Acrylate, a-benzyl-, methyl Acrylate, a-chloro-methyl Acrylate, ferrocenylmethyl Acrylate, 2-(0-ethyl methylphosphonoxy)-, methyl Acrylate, 2-chloroethyl Acrylate, 2-nitrobutyl Acrylate, p-acetoxymethyl-, methyl Acrylate, a-(0-ethyl methylphosphenoxy) Acrylate, a-[2,2-bis(carbomethoxy)ethyl]-, methyl Acrylate, oc-acetoxy-, ethyl Acrylate, a-benzyl-, methyl Acrylate, a-chloro-, methyl Acrylate, oc-cyano-, methyl Acrylate, a-cyano-, methyl Acrylate, a-hydroxymethyl-, ethyl Acrylate, a-phenoxymethyl-, methyl Acrylate, a-phenyl-, methyl Acrylate, a-phenyl-, methyl Acrylate, oc-tetrafluoropropyloxymethyl-, methyl Acrylate, a-trifluoromethyl-, methyl Acrylate, a-trifluoromethyl-, methyl Acrylate, a-trifluoromethyl-, methyl Acrylate, benzyl Acrylate, butyl Acrylate, butyl Acrylate, butyl Acrylate, ethyl Acrylate, ethyl Acrylate, ethyl Acrylate, ferrocenylmethyl Acrylate, heptafluorobutyl Acrylate, heptyl Acrylate, isobutyl Acrylate, isobutyl Acrylate, m-nitrophenyl Acrylate, methyl Acrylate, o-chlorophenyl Acrylate, octadecyl Acrylate, p-bromophenyl Acrylate, p-chlorophenyl Acrylate,/?-chlorophenyl Acrylate, methylphenyl Acrylate, phenyl Acrylate, phenyl Acrylate, a-p-chlorobenzyl-, methyl Acrylate, a-p-methoxybenzyl-, methyl Acrylic acid Acrylic acid, a-bromoAcrylonitrile Acrylonitrile, a-trifluoromethyl-
rx 1.65 2.15 2.8 2.64 1.14 1.62 1.62 4.119 0.25 2.13 3.75 3.9 0.11 2.9 0.73 2.15 1.19 0.91 0.73
±95% 0.16 0.08 0.1 0.15 0.09 0.07 0.136 0.24 0.19 0.09 0.04 0.12
3.7
r2 0.41 0.57 0.59 0.21 0.05 0.7 0.7 0.42 2.83 0.148 0.05 0.09 1.92 0.08 0.44 0.37 0.27 0.24 0.44
±95%
Conv.
0.15 0.08 0.09 0.21 0.72
N N N N N
0.11
Y
0.081 0.09 0.01 0.08
Y N N N
0.25 0.04
N
0.04
1.65 2.36 0.31 0.21 0.068 1.26 1.13 0.21 0.3 1.43
0.12 0.23 0.24 0.02 0.014 0.17 0.038
1.8 3.2 2.3 2.23 0.92 2.86 1.88 1.83 2 2.04 2.8 1.387 2.51 1.04 4.1 0.928 2.15 1.25 2.477 0.926 1.01 1.09 1.45 1.56 1.54 1.87 1.71 0.418 0.37 1.322 1.11
0.23 0.5 0.2 0.14 0.2 0.32 0.4 0.28 0.19 0.072 0.13 0.08 0.5 0.248 0.04 0.024 0.056 0.132 0.275 0.14 0.222 0.109 0.02 0.05 0.12
Refs. 170 315 315 691 691 593 596 290 709 823 258 610 31 293 882 790 234 1091 851 1092
0.608 0.173 1.13 0.03 0.135 1.34 0.755 0 0 0.61
0.02 0.022 0.19 0.01 0.016 0.062 0.061
Y Y Y N Y N Y
244 610 6 141 182 1027 1048 141 49 1047
-0.17 0 0.1 0.19 0.13 0.11 0.43 0.47 0.28 0.22 0.024 0.177 0.46 0.29 0.135 1.04 0.4 0.4 0.464 0.191 0.235 0.3 0.223 0.45 0.416 0.255 0.13 1.73 0.11 0.138 -0.016
0.18 0.1 0.1 0.2 0.15 0.018 0.07
Y N N Y N Y N
0.05 0.064 0.084 0.02 0.04 0.02 0.135 0.12
N Y Y N Y Y N
0.07 0.014 0.023
Y Y Y
0.036
Y
0.041 0.034 0.008 0.096
Y Y Y N
0.037 0.048
Y Y
681 825 825 277 30 639 87 30 469 87 293 206 980 30 639 1074 324 621 290 1074 1074 621 1074 621 672 905 905 964 733 216 681
TABLE 1. cont'd Monomer 1 Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate,
Monomer 2 methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl
Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate,
methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl
Methacrylate, methyl Methacrylate, methyl Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate,
methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl
Methacrylate, methyl Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate,
methyl methyl methyl methyl methyl methyl methyl
Methacrylate, methyl Methacrylate, methyl
Acrylonitrile, a-perfluoropropylAcryloyl chloride Acryloyl chloride Allyl acetate Allyl acetate Allyl alcohol Allyl chloride Benzocyclobutane, a-methyleneBenzocyclobutene, 4-vinylBenzofuran, 2-vinylBenzophenone, 2-hydroxy4-(methacryloxy)Benzothiazole, vinylmercaptoBicyclo[2,2,l]hept-2-ene5,6-dicarboximide, TV-benzyl Bicyclo[2,2,l]hept-2-ene5,6-dicarboximide, TV-benzyl Butadiene Butadiene Butadiene Butadiene, 2,3-dichloroButadiene, 2-chloroButadiene, 2-fluoroCarbamate, TV-vinyl-f-butylCarbazole, TV-vinylCarbazole, TV-vinylCarbazole, TV-vinylCarbazole, TV-vinylCarbazole, TV-vinylCarbazole, TV-vinylCarbazole, TV-vinylCitraconimide, TV-(4-acetoxyphenyl)Citraconimide, TV-(4-chlorophenyl)Citraconimide, TV-(4-ethoxycarbonylphenyl)Citraconimide, TV-(4-methoxyphenyl)Citraconimide, TV-( 1 -menthylcarboxylatomethyl)Citraconimide, TV-benzylCitraconimide, TV-butylCitraconimide, TV-ethylCitraconimide, TV-hexylCitraconimide, TV-isobutylCitraconimide, TV-isopropylCitraconimide, TV-methyl Citraconimide, TV-phenyl Citraconimide, Af-propyl Citraconimide, N-tert-butylCitraconimide, TV-tolylCyclopentene, 4-,-1,3-dione Cyclopropane, l,l-bis(ethoxycarbonyl)-2-vinylCyclopropane, 1,1-bis(ethoxycarbonyl)-2-vinylDiallyl melamine Diallyl phthalate Diallyl phthalate Diallyl phthalate Diallylcyanamide Diallylcyanamide Dimethyleneheptanedioate, 2,6-dimethyl Ditiane, 2-methylene-l,3Ethylene
rx
±95%
r2
1.9 0.48 0.42 99.24 23 78.79
0.3
0 1.51 0.05 -2.42 0 -1.62
0.32 0.6 0.006 0.315 1.25 30.5
24.6 6.5
0.02 0.036 0.083
108 0.25 0.027 0.32 0.08 0.08 0.76 1.87 1.55 2.12 1.8 0.57 1.84 0.44 2.123 1.88 2.93 2.72
0.46 1.47 3.89 1.65 0.43 0
±95%
Conv.
0.05
37.66
N
2.9
N Y
0.617 0.114
N Y
0.14
Y
0
Refs. 926 508 776 210 470 210 204 1083 1085 1020 934 763 994 994
0.26 0.22 0.048 0.16 0.4 0.18
0.75 0.504 0.7 11.04 6.33 1.23 0.17 0.14 0.033 0.06 0.75 0.08 0.33 0.031 0.18 -0.01 -0.027
3.16 3.47
0.73 0.335
-0.1 0.109
0.19 0.115
Y Y
728 950
2.77 2.17 3.25 2.38 1.78 2.7 3.24 3.081 3.23 2.88 2.75 8.11 4.21
0.28 0.56 0.79 0.45 0.85 0.51
0.02 -0.12 -0.04 -0.18 -0.18 0.09 0.15 0.001 -0.03 0.038 0.003 0.094 0.223
0.14 0.36 0.33 0.28 0.42 0.27
Y Y Y Y Y Y
0.033 0.43 0.072 0.088 0.017 0.194
Y Y Y Y Y Y
714 714 714 714 714 714 460 728 714 714 728 95 1076
0.111
0.194
Y
1076
-0.001 0.029 0.076 0.04 0.04 0.53
0.011 0.026 0.006
Y Y Y Y
0.02
N
201 153 153 153 603 604 795
N
1031 41
0.004
0.77 0.2 0.16 0.14
0.074 0.98 0.19 0.19 0.38 0.905
18.3
2.5
26.56 22.73 21.52 25 25 2.36
1.98 1.48 0.39
0.08
0.25
1.77 0.1 0.03 0.015
N Y
0.05 0.18 0.022 0.13 0.18 0.084
N N Y Y Y Y
140 257 467 61 61 174 991 11 13 738 738 758 758 98 728 728 728
0.024
Y Y Y Y
4.12
References page II - 290
TABLE 1. cont'd Monomer 1 Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate,
Monomer 2 methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl
Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate,
methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl
rt
Ethylene, 1,1-diphenyl2.1 Ethylene, 1,1-diphenyl8.7 Ethylene, chlorotrifluoro51.36 Ethylene, tetrachloroEthylene, trichloro100 Fumarate, diethyl 40.3 Fumarate, diethyl 2.1 Fumarate, diisopropyl 23 Fumaronitrile 6.74 Furan, 2-vinyl-5-methyl 0.183 Hexatriene, tetrachloro0.504 Imidazole, 1-vinyl4.36 Imidazole, l-vinyl-2-methyl4 Imidazole, l-vinyl-2-methyl3.48 Isoprene 0.26 Isoprene 0.25 Isoprene 0.25 Isoprene, 3-acetoxy0.16 Isopropenyl acetate 17.36 Isopropenyl, 3-(l-cyclohexenyl), acetate 0.81 Isopropenylisocyanate 3.1 Isopropenyltoluene 0.68 Isopropenyltoluene 0.68 Itaconamate, Af-(4-chlorophenyl)-, ethyl 1.24 Itaconamate, Ar-(4-chlorophenyl)-, 1.26 propyl Itaconamate, N-(4-methoxyphenyl)-, 1.31 ethyl Itaconamate, A^-(4-carboethoxyphenyl)1.21 ethyl Itaconamate, Ar-(4-methylphenyl)-, ethyl 1.43 Itaconamate, iV-(4-methoxyphenyl)-, 1.03 propyl Itaconamate, A^-(4-methylphenyl)-, 1.11 propyl Itaconamate, Af-phenyl-, ethyl 1.32 Itaconamate, N-phenyl-, propyl 1.13 Itaconamate, Af-(4-carboethoxyphenyl)1 propyl Itaconate, dibutyl 1.33 Itaconate, dibutyl 0.8 Itaconate, dimethyl 3.34 Itaconate, dimethyl 1.2 Itaconate, monomethyl 1.1 Itaconic acid 1.23 Itaconic acid 1.14 Itaconic anhydride 0.155 Itaconimide, N-(2-chloroethyl)0 Itaconimide, N-benzyl0.46 Itaconimide, JV-ethyl0.486 Itaconimide, N-methyl0.38 Maleate, dibutyl tin 72.7 Maleate, diethyl 341 Maleate, diethyl 20 Maleate, diethyl 285.8 Maleic anhydride 4.18 Maleic anhydride 6.36 Maleic anhydride 0.46 Maleic anhydride 5.2 Maleic anhydride 3.1 Maleic anhydride 3.85 Maleic anhydride 3.4 Maleic anhydride 3.85 Maleimide 2.576 Maleimide 2.5
±95%
3.31 0.6 0.79 0.146 0.057 1.86 0.54 0.21
1.95
0.09 0.557 0.071 0.024 0.11 0.18 0.066 0.22 5.93 46 35.9 0.31 0.64 0.69 0.47
0.061
r2 0.09 O -0.074 0 0.04 0.05 0.17 -0.064 0.867 1.76 0.014 0.047 0.003 0.65 0.64 0.64 2.81 -0.09 0.4 0.14 0.04 0.04 0.36 0.31
±95%
Conv.
0.062
Y Y
0.004
N
0.096 0.292 0.28 0.03 0.088
Y Y Y Y Y
0.23
Y
0.12
Y
Refs. 65 901 236 204 470 28 394 1038 191 1105 5 364 364 479 302 698 704 770 100 770 434 688 722 678 678
0.43
678
0.48
678
0.63 0.4
678 678
0.28
678
0.47 0.15 0.53
678 678 678
0.717 0.4 -0.156 0.3 0.139 0 0 1.17 0.54 1.06 0.42 1.12 -0.095 -0.1 0 -0.02 -0.163 -0.019 0.08 0.02 0.01 0.01 0.01 0.02 0.166 0.17
0.11 0.02
Y
0.103
Y
0.33 0.39 0.75 0.13 0.73 0.199 0.05
Y Y Y Y Y Y N
0.015 0.027 0.026 1.77 0.004
Y Y Y N N
0.047
Y
1073 398 975 398 1010 260 408 1010 642 642 642 642 987 28 470 873 169 260 320 33 524 524 524 524 251 992
TABLE 1. cont'd Monomer 1
Monomer 2
Methacrylate, methyl Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate,
methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl
Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate,
methyl methyl methyl methyl methyl methyl methyl methyl methyl
Maleimide, 2,3-dimethylA^-(2-methacryloyloxyethyl) Maleimide, A^-(4-hydroxyphenyl)Maleimide, 7V-(2-hydroxyethyl)Maleimide, Af-(2,6-diethylphenyl)Maleimide, 7V-(2,6-diisopropylphenyl)Maleimide, AT-(2,6-dimethylphenyl)Maleimide, A^-(2-chlorophenyl)Maleimide, 7V-(2-methylphenyl)Maleimide, Af-(3,5-dimethylphenyl)Maleimide, 7V-(3-methylphenyl)Maleimide, AK3-trifluoromethylphenyl)Maleimide, 7V-(4-carboxyethylphenyl)a-chloroMaleimide, 7V-(4-chlorophenyl)-a-chloroMaleimide, Af-4-methoxyphenyl)a-chloroMaleimide, AK4-methylphenyl)Maleimide, A^-(4-methylphenyl)a-chloroMaleimide, AK|3-chloroethyl)-a-chloroMaleimide, AH (3-chloroethyl)-a-chloroMaleimide, N-[JV'-(a-methylbenzyl) aminocarbonylpenty 1] Maleimide, TV-benzyl Maleimide, TV-butyl Maleimide, 7V-cyclohexyl Maleimide, N-cyclohexyl Maleimide, Af-cyclohexyl Maleimide, AT-ethyl-a-chloroMaleimide, TV-hexylMaleimide, 7V-hydroxymethylMaleimide, 7V-methyl-a-chloroMaleimide, 7V-phenylMaleimide, 7V-phenylMaleimide, Af-phenyl-a-chloroMaleimide, N-phenylMethacrylate, 2-acetoxyethyl Methacrylate, cyanomethyl Methacrylate, diphenylmethyl Methacrylamide Methacrylamide Methacrylamide Methacrylamide Methacrylamide, Af-methoxymethylMethacrylamide, iV-p-bromophenyl~ Methacrylamide, N-p-tolylMethacrylamide, N-phenyl Methacrylamide, N-phenylMethacrylamide, 1-deoxy-D-glucitol Methacrylamide, N-/?-nitrophenylMethacrylate, tert-butyl Methacrylate, a,a-dimethylbenzyl Methacrylate, (2,2-dimethyl1,3-dioxolane) Methacrylate, 1,1-diphenylethyl Methacrylate, 1-naphthyl Methacrylate, 1-naphthyl Methacrylate, 1-naphthyl Methacrylate, 1-naphthyl Methacrylate, 2,2-dimethylaminoethyl Methacrylate, 2,3-epithiopropyl Methacrylate, 2,6-(diphenyl)phenyl Methacrylate, 2-(Ar,N-dimethylcarbamoyloxy)ethyl
/*i
±95%
r2
±95%
Conv.
0.51
1.66
1.1
3.58
Y
619
1.392 1.396 4.78 10.9 3.62 2.1 2.22 1.63 1.18 1.57 0.472
0.001 0.089
0.001 0.083
Y Y
0.114
0.345 0.201 0.05 0.02 0.07 0.1 0.09 0.28 0.22 0.1 -0.004
0.168
Y
323 323 992 992 992 992 992 992 992 992 973
0.562 0.556
0.025 0.145
0.02 0.064
0.03 0.189
Y Y
973 973
0.83 0.564
0.117
0.34 0.029
0.158
Y
992 973
0.94 0.59 1-37
0.06 0.06 0.291
0.05 0.11 0.582
0.04 0.05 0.359
Y
974 974 1009
1.28 1.41 1.35 1.31 2.26 0.53 1.9 1.745 0.63 0.98 0.91 0.657 1.014 0.94 0.399 0.81 1.57 1.7 1.39 1.65 1.678 3.48 1.43 1.95 1.42 4.2 5.05 0.96 0.81 0.9
0.23 0.19
0.23 0.16
Y Y
0.048 0.03 0.15 0.026 0.03
Y
0.72 0.77 0.809 0.851 0.61 0.42 0.83 1.42 0.59
0.066 0.04 0.2 0.03 0.34 0.083 0.06 0.02 0.019 0.11 0.04 0.074 0.048 0.2 0.2 0.2 0.096 0.2
0.14 0.078 0.084 0.02 0.06
0.03 -0.1 0.24 0.19 0.106 0.13 0.1 0.263 0.11 0.3 0.3 0.077 0.164 1.12 0.73 1.07 1.27 0.44 0.425 0.49 0.265 0.38 0.78 0.28 0.56 0.04 0.29 1.35 0.92 1.1 0.77 1.8 1.68 2.62 1.52 1.01 0.97 0.071 0.42
Y Y
0.098 0.065 0.06 0.11
Y Y N Y
0.24 0.06 0.085
N N Y
0.009 0.2 0.2 0.2 0.12
Y
Y
0.2
0.73 0.38 0.47
Y Y Y
0.54
N
0.004
Refs.
348 115 992 1100 348 974 348 323 974 323 992 973 328 346 625 761 316 316 54 55 227 968 968 968 352 258 968 761 761 807 761 752 752 752 761 691 787 1079 600
References page II - 290
TABLE 1. cont'd Monomer 1
Monomer 2
Methacrylate, methyl Methacrylate, methyl Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate,
methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl
Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate,
methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl
Methacrylate, 2-bromoethyl Methacrylate, 2-chloro2,3,3,3-fluoropropyl Methacrylate, 2-chloroethyl Methacrylate, 2-chloroethyl Methacrylate, 2-hydroxyethyl Methacrylate, 2-hydroxyethyl Methacrylate, 2-hydroxyethyl Methacrylate, 2-hydroxypropyl Methacrylate, 2-naphthyl Methacrylate, 2-naphthyl Methacrylate, 2-naphthyl Methacrylate, 2-naphthyl Methacrylate, 2-naphthyl Methacrylate, 2-phenylethyl Methacrylate, 3,5-dimethyladamantyl Methacrylate, 5-oxo-pyrrolidinylmethyl Methacrylate, N-a-benzothiazolonylmethyl Methacrylate, benzyl Methacrylate, benzyl Methacrylate, benzyl Methacrylate, benzylmethylaminoethyl Methacrylate, butyl Methacrylate, butyl Methacrylate, chloromethyl Methacrylate, diethylaminoethyl Methacrylate, dimethylaminoethyl Methacrylate, ethyl Methacrylate, ethyl Methacrylate, ethyl Methacrylate, glycidyl Methacrylate, glycidyl Methacrylate, glycidyl Methacrylate, glycidyl Methacrylate, isobutyl Methacrylate, isobutyl Methacrylate, isopropyl Methacrylate, methyl diphenylsilyl Methacrylate, methylthiomethyl Methacrylate, /?-acetylphenyl Methacrylate, /?-chlorophenyl Methacrylate, /?-methoxyphenyl Methacrylate, /7-tolyl Methacrylate, phenyl Methacrylate, phenyl Methacrylate, phenyl Methacrylate, phenyl Methacrylate, phenyl Methacrylate, propyl Methacrylate, sulfolanyl Methacrylate, f-butyl dimethylsilyl Methacrylate, f-butyl diphenylsilyl Methacrylate, tributyltin Methacrylate, tributyltin Methacrylate, trimethyltin Methacrylate, trimethyltin Methacrylic acid Methacrylic acid Methacrylic acid Methacrylic acid Methacrylic acid Methacrylic acid Methacrylic acid Methacrylic acid
/*i 0.79 0.984 1.156 0.55 0.824 0.192 0.75 0.402 0.602 0.581 0.532 0.614 0.623 0.75 0.68 0.421 0.5 0.808 0.93 0.78 0.523 0.52 1.27 0.477 0.843 0.699 0.81 1.08 1.16 0.71 0.726 0.8 0.688 0.62 0.92 0.89 0.438 0.639 0.47 0.54 0.72 0.59 0.53 0.58 0.56 0.66 0.55 1.21 1.07 0.897 0.636 0.58 0.62 0.63 0.6 0.63 0.1 0.78 0.31 0.27 0.1 0.78 0.32
±95%
0.395 0.082 0.01 0.09 0.017 0.059 0.023 0.055 0.051 0.048 0.16 0.04 0.033 0.01 0.03 0.134 0.07 0.029 0.128 0.051 0.22 0.19 0.08 0.042 0.076 0.08 0.15 0.075 0.057
2.48 0.05 0.014
0.03 0.01 0.03 0.02 0.03 0.01 0.03 0.02
r2
±95%
Conv.
Refs.
1.17
N
657 927
0.97 0.48 0.63 0.81 1.5 1.055 2.57 2.53 1.91 4.41 3.83 0.85 0.45 0.694 0.6
0.18
Y
0.076 1.02
Y Y
0.04 0.48 0.27 0.6 0.76 0.57 0.34 0.16 0.087 0.02
Y Y Y Y Y Y Y N Y
1.112 1.05 1.38 0.296 2.11 1.2 1.02 1.44 1.2 0.86 1.08 1 0.52 0.934 1.05 0.501 1.88 0.488 1.2 0.38 1.1 0.67 1.08 1.19 1.28 1.67 1.69 1.72 1.55 0.99 1.24 7.16 0.725 0.396 0.62 0.87 1.07 0.68 0.25 1.06 0.33 0.63 0.46 1.06 0.33 0.63
0.093
Y
0.123 0.08
Y N
0.16 0.085 0.154 0.12
Y Y Y N
0.09 0.06 0.085
N Y Y
0.027 0.07 0.029
Y N Y
0.178 0.356
Y Y
23.7 0.455 0.257
N Y Y
1.18 0.583
0.05 0.02 0.02 0.02 0.03 0.02 0.02 0.02
179 382 350 358 710 333 760 760 760 760 760 540 335 633 887 111 32 540 1081 30 844 712 1081 1081 32 844 87 113 226 463 639 30 639 541 1069 920 769 769 769 769 32 32 32 761 769 844 359 1069 1069 1082 1082 1082 1082 1071 1072 1072 1072 1072 1087 1087 1087
TABLE 1.
cont'd
Monomer 1 Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate,
Monomer 2 methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl
Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl
Methacrylic acid Methacrylic acid Methacrylic acid Methacrylic acid Methacrylic acid Methacrylic acid Methacrylic acid Methacrylic acid Methacrylic acid Methacrylic acid Methacrylic acid Methacrylic acid Methacrylic anhydride Methacrylophenone, aMethacrylophenone, aMethacryloyl chloride Methacryloyl chloride Methacryloyl fluoride Methacryloyl fluoride Methacryloyl isocyanate Methacryloyloxy-, o-, benzoic acid Methylenebutyrolactone Methyleneglutaronitrile, 2Methyleneglutaronitrile, 2Myrcene AW-divinylaniline W-Vinylimidazole N-Vinylpyrrolidone N-Vinylpyrrolidone iV-Vinylpyrrolidone Af-Vinylpyrrolidone Naphthalene, 1-vinylNorbornadiene Oxazolidone, N-vinylOxazolidone, Af-vinylOxazoline, 2-,2-isopropenyl 4,4-dimethyl Oxazoline, 2-,2-isopropenyl Oxazoline, 2-,4-acryloxymethyl 2,4-dimethyl Oxazoline, 2-,4-methacryloxy2,4-dimethyl Pentadiene, trans-1,3Pentenoate, 3-oxo-4-, ethyl Pentenoate, 3-oxo-4-, ethyl Pentenoate, 3-oxo-4-, ethyl Pentenoate, 3-oxo-4-, ethyl Pentenoate, 3-oxo-4-, ethyl Pentenoate, 3-oxo-4-, ethyl Pentenoate, 3-oxo-4-, ethyl Pentenoate, 3-oxo-4-, ethyl Pentenoate, 3-oxo-4-, ethyl Pentenoate, 3-oxo-4-, ethyl Pentenoate, 4-methyl-3-oxo-4-, ethyl Pentenoate, 4-methyl-3-oxo-4-, ethyl Pentenoate, 4-methyl-3-oxo-4-, ethyl Pentenoate, 4-methyl-3-oxo-4-, ethyl Pentenoate, 4-methyl-3-oxo-4-, ethyl Pentenoate, 4-methyl-3-oxo-4-, ethyl Pentenoate, 4-methyl-3-oxo-4-, ethyl Pentenoate, 4-methyl-3-oxo-4-, ethyl Pentenoate, 4-methyl-3-oxo-4-, ethyl Phosphate, 2-(acryloyloxy)ethyl diethyl Phosphate, 2-(acryloyloxy)ethyl diethyl Phosphate, 2-(acryloyloxy)ethyl diethyl
/*i
±95%
r2
±95%
Conv.
Refs.
0.87 1.81 0.56 0.29 1.28 0.77 0.36 1.18 0.55 0.209 1.25 0.48 0.22 1.79 1.74 0.45 0.45 0.405 0.53 0.75 0.908 0.6 1.36 1.27 0.256 1.06 4.306 4.78 5.93 2.07 4.04 0.321 14.68 6.75 9.46 0.53
0.05 0.16 0.23 0.04 0.1 0.05 0.08
2.16 1.63 0.99 1.18 0.48 1.84 1.38 0.63 1.55 1.26 0.78 0.68 1.58 0.11 0.119 0.2 0.2 0.43 0.9 0.35 1.37 1.67 0.12 0.12 0.448 0.005 0.663 0.006 0.014 0.027 0.066 0.574 - 0.5 0.04 0.027 0.82
0.28 6.25 0.55 0.19 0.1 0.24 0.27
N N Y N N N N
0.2
Y
0.06 0.02 0.009
N N Y
0.12 0.16
Y N
0.64
Y
0.74
N
0.06 0.018 0.104 2.29 0.899 0.062 3.96 0.073 0.52 0.13 0.008
Y Y Y
203 210 216 276 276 312 313 313 424 54 630 819 275 798 798 591 593 617 660 944 938 746 196 196 1062 45 879 1084 1084 1084 1084 967 267 102 36 596
0.05 0.02 0.07 0.22 0.037 0.06 0.252 0.28 0.013 0.18 0.185 0.236 0.198 0.247 0.956 0.096 16.78 0.37 0.39
N Y Y
0.69 0.41
0.99 0.11
862 596
1.17
0.19
596
0.404 0.555 0.424 0.591 0.443 0.34 0.57 0.606 0.269 0.715 0.528 0.597 0.38 0.513 0.43 0.474 0.581 0.616 0.663 0.528 2.37 2.23 1.87
0.038 0.032 0.022 0.046 0.032 0.031 0.023 0.045 0.027 0.048 0.02 0.03 0.034 0.022 0.034 0.023 0.025 0.024 0.023 0.02 0.046 0.047 0.086
0.379 3.39 2.02 3.06 1.67 1.24 1.72 1.69 0.72 1.55 1.09 2.56 0.748 1.14 0.952 1.67 1.04 1.05 0.725 1.09 0.486 0.521 0.946
0.013 0.263 0.141 0.349 0.183 0.168 0.123 0.236 0.12 0.224 0.09 0.218 0.155 0.109 0.164 0.143 0.111 0.108 0.08 0.09 0.088 0.138 0.436
Y N N N N N N N N N N N N N N N N N N N N N N
1058 1033 1033 1033 1033 1033 1033 1033 1033 1033 1033 1033 1033 1033 1033 1033 1033 1033 1033 1033 971 971 971
References page II - 290
TABLE 1. cont'd Monomer 1 Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate,
Monomer 2 methyl methyl methyl methyl methyl methyl
Methacrylate, methyl Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate,
methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl
Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate,
methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl
Phosphate, 2-(acryloyloxy)ethyl diethyl Phosphate, 2-(acryloyloxy)ethyl diethyl Phosphate, 2-(acryloyloxy)ethyl diethyl Phosphate, 2-(acryloyloxy)ethyl diethyl Phosphonate, a-bromovinyl-,diethyl Phosphonate, a-carboethoxyvinyl-, diethyl Phosphonate, a-carbomethoxyvinyl-, diethyl Phosphonate, isopropenyl-, dimethyl Phosphonate, vinyl-, bis(2-chloroethyl) Phosphonate, vinyl-, diethyl Phosphonic acid, a-phenylvinylPhthalimide,-N-)methacryloyloxy)Pinene, aPropene, 2,3-dichloroPropene, 2-chloro-3-hydroxyPropenyl, 2-chloro-, acetate Propenyl, 2-methyl, acetate Pyridazinone, 3-(2-vinyl)-6-methyl-4,5Pyridazinone 3-(2-vinyl)-6-methylPyridine, 2-methyl-5-vinylPyridine, 2-vinylPyridine, 2-vinylPyridine, 2-vinylPyridine, 2-vinylPyridine, 2-vinylPyridine, 2-vinyl-5-ethylPyridine, 4-vinylPyridine, 4-vinylPyrrolidone, l-benzyl-3-methylene5-methyl Pyrrolidone, N-vinylPyrrolidone, N-vinylPyrrolidone, A^-vinylPyrrolidone, N-vinylPyrrolidone, Af-vinylPyrrolidone, a-methylene-AT-methylSilane, y-methacryloxypropyltrimethoxyStyrene Styrene Styrene Styrene Styrene Styrene Styrene Styrene Styrene Styrene Styrene Styrene Styrene Styrene Styrene Styrene Styrene Styrene Styrene Styrene Styrene Styrene Styrene Styrene Styrene Styrene
rx 1.97 2.1 2.56 2.04 1.25 1
±95%
0.01
684
30 29.9 11.1 1.362 0.69 10 6.02 4.4 1 10 1.19 0.86 0.42 0.42 0.4 0.35 0.31 0.27 0.39 0.57 0.54 0.387
0.2 0.26
684 410 684 131 979 48 11 445 445 470 340 340 232 231 532 6 623 749 231 231 691 33
0.04 0.02 0.09 0.02 0.19 0.04 0.02 0.02 0.01 0.07
0.3 0.34 0.61 0.61 0.058 0.082
0.13 0.085 0.029 0.011 0.01
N N N N
Refs.
4.7
1.66
0.248 0.097 0.226 0.052
Conv.
0.05
0.04 0.084 0.048
1.16 0.42 0.258 0.0701
±95%
971 971 971 971 684 684
5.62 4.63 4.36 4.04 0.577 0.788 0.5 0.46 0.46 0.42 0.45 0.46 0.47 0.48 0.5 0.22 0.32 0.418 0.54 0.478 0.45 0.45 0.49 0.47 0.48 0.46 0.42 0.5 0.46 0.44 0.49 0.49
0.029 0.045 0.094 0.012 0.04
r2
-0.063 1.45 0.08 0.18 0 0 0 0.08 0.56 0.54 0.73 0.86 0.76 0.64 1.1 0.68 0.77 0.99 2.28
0.077 0.151
Y Y
0.1
N
0.03 0.04 0.19 0.06
N N N N
0.12
Y
0.08 0.06 0.07 0.18 0.47
N N N N Y
- 0.05 -0.032 -0.052 0.01 0.24 2.06 0.5 0.52 0.52 0.48 0.52 0.49 0.45 0.58 0.44 0.396 0.42 0.49 0.564 0.585 0.44 0.47 0.54 0.52 0.38 0.52 0.54 0.44 0.52 0.5 0.56 0.53
0.08 0.068 0.028 0.15 0.14 0.309
Y N Y Y N Y Y
0.048
Y
0.14 0.047 0.007 0.08
Y Y Y N
213 320 321 36 691 641 977 138 139 179 20 21 21 21 21 21 241 241 254 254 287 324 324 403 416 451 463 492 492 505 531 531 534
TABLE 1. cont'd Monomer 1 Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate, Methacrylate,
Monomer 2 methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl methyl
Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl
Styrene Styrene Styrene Styrene Styrene Styrene Styrene Styrene Styrene Styrene Styrene Styrene Styrene Styrene Styrene, 2,4,6-trimethylStyrene, 2,4,6-trimethylStyrene, 2,5-dichloroStyrene, 2,6-dichloroStyrene, 3-methyl Styrene, 3-methyl Styrene, 3-methyl Styrene, 3-tri-rc-butylstannylStyrene, 4-methylStyrene, a-methoxyStyrene, a-methylStyrene, a-methylStyrene, a-methylStyrene, a-methylStyrene, a-methylStyrene, a-methylStyrene, m-bromoStyrene, m-chloroStyrene, m-methylStyrene, m-nitroStyrene, /?-chloroStyrene, o-chloroStyrene, /?-l-(2-hydroxypropyl)Styrene, p-JVyV-dimethylaminoStyrene, p-bromoStyrene, /?-chloroStyrene, p-chloroStyrene, /7-chloroStyrene, /?-chloromethylStyrene,/?-cyanoStyrene, /?-methoxyStyrene, p-methylStyrene,/7-octylamine sulfonate Styrene, p-tert-buty\Styrene, pentachloroSuccinamete, potassium N-vinylSuccinimide, TV-vinylSuccinimide, N-vinylTetrazole, 1-VinylTetrazole, 2-methyl-5-vinylTetrazole, 2-phenyl-5(4/-vinyl) phenylThiophene, 3-vinyl Thioxanthone, 2-(acryloyloxy)Toluenesulfonamide, Af,N-methylvinylTriallyl cyanurate Triallyl isocyanurate Triazole, 1,2,3-, 1-p-bromophenyl4-vinyl Triazole, 1,2,3-, 4(5)-vinylUrea, TV-vinyl-AT'-ethyl-
r\ 0.409 0.504 0.611 0.59 0.6 0.63 0.58 0.64 0.41 0.454 0.464 0.422 0.41 0.314 1.511 1.45 0.44 1.98 0.48 0.38 0.41 0.69 0.345 2.5 0.48 0.55 0.55 0.5 0.42 0.47 0.48 0.512 0.35 0.5 0.46 0.26 0.204 0.4 0.334 0.42 0.43 0.408 0.22 0.29 0.4 0.6 0.44 3.65 1.1 9.94 0.01 7.13 1.026 0.7 0.563 1.36 1.87
±95% 0.02 0.026 0.028
0.072 0.16 0.13 0.16 0.04 0.03 0.04 0.008 0.39 0.02
0.036 0.11
r2 0.485 0.48 0.371 0.62 0.52 0.5 0.55 0.55 0.41 0.472 0.497 0.432 0.57 0.275 0.083 -0.01 2.66 -0.15 0.53 0.36 0.51 0.03 0.46 - 0.02 0.27 0.51 0.6 0.14 0.22 0.48 1.17
±95%
Conv.
Refs.
0.052 0.059 0.055
Y Y Y
0.045 0.11 0.38 0.27 0.04 0.06 0.05
Y Y Y N
0.022 0.04 0.07
Y N N
0.02 0.32
Y Y Y
0.016
Y
0.12
Y
0.15
Y
0.05 0.12 0.026 0.096 0.026 0.075
N Y Y Y Y Y
0.26
Y
751 751 751 753 753 753 753 753 753 824 824 824 835 860 58 58 3 324 1087 1087 1087 985 929 142 265 265 265 532 835 899 256 150 256 222 532 558 380 256 256 150 256 476 756 256 35 256 817 634 7 771 104 693 925 670 583 1000 986 80
0.19
0.486 0.8 1.37 1.34 1 0.101 1.1 0.77 0.89 0.47 0.91 1.41 0.32 0.44 2.6 0.5 0.3 -0.02 0.048 -0.059 0.262 0.486 0.4 0.25 0.5 -1.83
16.12 16.88 0.832
0.56 6.64 0.022
-0.005 -0.49 0.266
0.05 0.94 0.058
Y Y Y
201 201 670
0.839 1.85
0.055 0.23
0.27 -0.008
0.13 0.029
Y Y
670 101
0.022 0.016
0.038
0.85 0.17 0.27 0.031 0.093 0.029
References page II - 290
TABLE 1. cont'd Monomer 1 Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl
Monomer 2 Vinyl 2-chloroethyl ether Vinyl 4-chlorocyclohexyl ketone Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl benzoate Vinyl bromide Vinyl bromide Vinyl bromide Vinyl bromide Vinyl butyl ether Vinyl butyrate Vinyl chloride Vinyl chloromethyl ketone Vinyl ether Vinyl ethyl ether Vinyl ethyl ketone Vinyl ethyl oxalate Vinyl ethyl sulfide Vinyl ethyl sulfide Vinyl ethyl sulfoxide Vinyl isobutyl sulfide Vinyl isobutyl sulfide Vinyl isobutyl sulfide Vinyl isopropyl ketone Vinyl isopropyl ketone Vinyl isopropyl sulfide Vinyl isothiocyanate Vinyl m-cresyl ether Vinyl methyl sulfide Vinyl o-cresyl ether Vinyl /7-cresyl ether Vinyl phenyl ether Vinyl phenyl ether Vinyl phenyl ketone Vinyl phenyl sulfide Vinyl phenyl sulfide Vinyl propionate Vinyl sulfone Vinyl tert-butyl ketone Vinyl, 4-, dithiobenzoate, methyl Vinyl, /?-,benzylmethylcarbinol Vinyl-tris(trimethoxysiloxy)silane Vinylacetophenone, p Vinylanthracene, 9Vinylbenzoic acid, p Vinylbenzyl chloride Vinylene carbonate Vinylferrocene Vinylhydroquinone Vinylhydroquinone dibenzoate Vinylidene chloride Vinylidene chloride Vinylidene chloride Vinylidene chloride Vinylidene chloride Vinylidene chloride Vinylidene chloride Vinylidene chloride Vinylidene chloride Vinylidene chloride Vinylidene cyanide Vinylisocyanate
T1 18.8 0.77 2.71 137.5 26 28.6 22.21 20.3 14.11 17.1 25.1 19.84 25 8.99 0.121 4.9 37 0.42 4.74 1.03 2.7 11.17 0.89 0.985 0.88 0.81 0.54 0.822 0.85 3.3 1 1.8 2.6 11.34 2.8 0.71 0.79 0.85 24 4.5 1.21 0.151 0.24 34 0.33 4.068 0.398 0.46 126 1.22 0.49 0.34 2.6 2.38 2.16 2.5 2.5 2.1 1.8 2.83 1.23 2.77 3.3
±95%
0.25 5.9
0.67 0.88 2.58 2.97 0.021 0.99 0.17 2.95 0.11 0.48 0.01 0.077 0.02 0.22 0.064
5.76 0.6 0.06 0.49 0.11 0.092 0.26 0.36 0.04 0.097 298 0.21 0.02 0.06
0.95 0.06 0.012
r2 0 0.51 -0.2 -0.81 0.03 0.04 0.07 0.07 0.12 0.33 0.052 0.05 0.03 0.07 0.593 -0.15 0.01 0.65 -0.05 0.036 0.3 0.37 0.05 0.021 0.03 1.44 0.6 0.046 0.6 0.2 0.03 0.1 0 0.01 0 0.59 0.06 0.08 0.03 0.1 0.65 0.3 0.98 0.02 1.65 0.117 1.16 1.02 -0.04 0.52 0.02 0.41 0.3 0.36 0.18 0.5 0.34 0.09 0.094 0.19 0.02 0.27 0.01
±95%
Conv.
0.01 1.17
N
0.06
N
0.026 0.074
Y Y N
0.047 0.092 0.16
Y Y Y
0.42 0.44 0.017
Y Y Y
0.06 0.03 0.034 0.02
Y N Y N
0.47 0.025
Y Y
0.32
Y
1.9 0.09
Y N
0.16 0.15 0.29 0.28
Y Y Y Y
3.81 0.043 0.3
Y Y Y
0.85
Y
0.13
Y
0.03 0.18
Y N N
0.032
Y
0.01 0.013
N Y
Refs. 597 668 158 210 272 383 471 272 268 268 34 34 127 272 3 356 45 106 794 124 303 507 286 285 303 336 601 794 303 422 605 106 605 605 172 605 794 239 239 272 45 794 697 48 482 266 123 266 792 103 294 337 440 138 324 324 426 432 538 65 762 762 786 82 422
TABLE 1. cont'd Monomer 1 Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl diphenylsilyl Methacrylate, methylthiomethyl Methacrylate, methylthiomethyl Methacrylate, mono-,ethylene glycol Methacrylate, octyl Methacrylate, octyl Methacrylate, octyl Methacrylate, /?-(cinnamoylamino)phenyl Methacrylate, /?-acetylphenyl Methacrylate,/?-carbomethoxyphenyl Methacrylate, p-chlorophenyl Methacrylate, p-chlorophenyl Methacrylate, /?-methoxyphenyl Methacrylate, p-methoxyphenyl Methacrylate, p-methylphenyl Methacrylate, p-methylphenyl Methacrylate, p-tolyl Methacrylate, phenyl Methacrylate, phenyl Methacrylate, phenyl Methacrylate, phenyl Methacrylate, phenyl Methacrylate, phenyl Methacrylate, phenyl Methacrylate, phenyl Methacrylate, phenyl Methacrylate, phenyl Methacrylate, phenyl Methacrylate, phenyl Methacrylate, phenyl Methacrylate, phenyl Methacrylate, potassium Methacrylate, propargyl Methacrylate, propyl Methacrylate, propyl Methacrylate, sodium (2-sulphoxyethyl)Methacrylate, sulfolanyl Methacrylate, sulfolanyl Methacrylate, sufolanyl Methacrylate, f-butyl dimethylsilyl Methacrylate, f-butyl dimethylsilyl Methacrylate, f-butyl diphenylsilyl Methacrylate, terf-butyl Methacrylate, terf-butyl Methacrylate, tetra(2-hydroxypropyl)ethylenediamine Methacrylate, tetra(2-hydroxypropyl)ethylenediamine Methacrylate, tributyltin Methacrylate, tributyltin Methacrylate, tributyltin Methacrylate, tributyltin Methacrylate, tributyltin Methacrylate, tributyltin Methacrylate, triethyltin Methacrylate, trimethyltin Methacrylate, triphenyltin Methacrylic acid Methacrylic acid Methacrylic acid Methacrylic acid
Monomer 2
rx
Vinylphenyldimethylsilane 29.79 Vinyltrimethylsilane 35.66 Xanthate, 5-methacryloyl O-ethyl 0.76 Methacrylate, methyl 0.38 Methacrylate, methyl 1.1 Styrene 0.512 Acrylonitrile 1.5 Styrene 0.56 Styrene 0.68 Vinyl chloride 14 Styrene 0.31 Methacrylate, methyl 0.67 Styrene 0.178 Methacrylate, methyl 1.08 Styrene 0.243 Methacrylate, methyl 1.19 Styrene 0.244 Styrene 0.225 Styrene 0.185 Methacrylate, methyl 1.28 Acrylonitrile 0.46 Methacrylate, 2-chloroethyl 0.785 Methacrylate, benzyl 1.42 Methacrylate, methyl 1.67 Methacrylate, methyl 1.69 Methacrylate, methyl 1.72 Methacrylate, methyl 1.55 Methacrylate, methyl 0.99 Methacrylic, acid 1.89 Methacrylic, acid 0.589 N-Vinylpyrrolidone 4.17 Styrene 0.48 Styrene 0.55 Styrene 0.51 Acrylonitrile 0.203 Itaconic acid mono(/?-sulfamidoanilide) 1.65 Methacrylate, methyl 1.24 Styrene 0.38 Methacrylic, acid 1.2 Methacrylate methyl 7.16 Methacrylic, acid 0.81 Styrene -0.2 Acrylate, methyl 1.07 Methacrylate, methyl 0.725 Methacrylate, methyl 0.396 Methacrylate, methyl 1.35 Styrene 0.61 Methacrylate, hydroxyethyl 1.44
±95% 1.89 0.85 0.04 0.178 0.356 0.05
r2
0.51 1
-0.009 0.028 0.6 0.438 0.639 0.338 0.19 0.65 0.56 0.04 0.62 0.47 0.482 0.54 0.34 0.72 0.499 0.49 0.223 0.59 0.36 1.02 0.67 0.53 0.58 0.56 0.66 0.55 0.211 0.398 -0.026 0.246 0.247 0.26 0.226 0.58 1.21 0.565 0.78 1.07 0.81 0.2 0.288 0.897 0.636 0.96 0.545 0.606
0.16
0.027 0.022 0.026 0.04 0.039
0.083 0.09
0.17 0.081 0.756 0.23 0.33 0.086 0.02 0.11 0.19 23.7 0.24 2.46 0.21 0.455 0.257
±95%
Conv.
Refs.
Y Y
0.034 0.016 0.08 0.075 0.057 0.01
Y Y Y
0.1
Y
0.084
Y
0.11
Y
0.089 0.25 0.09
Y Y Y
0.21 0.06
Y N
0.018 0.019 0.032 0.049 0.064
Y Y Y Y Y
0.04 0.05
Y
0.081 0.08 2.48 0.03 0.1 0.057 0.05 0.014
Y N N N N Y Y Y
0.054 0.416
Y Y
482 482 1086 1069 920 920 682 179 463 511 685 769 177 769 177 769 177 177 177 769 363 179 32 32 32 32 761 769 88 88 1013 177 179 463 808 957 844 179 745 359 359 359 1069 1069 1069 761 179 996
Methacrylic acid
0.328
0.181
1.56
0.237
Y
996
Methacrylate, 2-ethoxyethyl Methacrylate, 2-hydroxypropyl Methacrylate, cyclohexyl Methacrylate, ethyl Methacrylate, hydroxyethyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Acrylamide Acrylamide Acrylamide Acrylate, butyl
0.2 0.728 0.395 0.299 0.282 0.62 0.87 1.07 0.68 1.63 4.4 0.15 1.25
0.444 0.517 0.428 0.607 0.424
0.53 1.81 0.891 0.601 2.33 0.58 0.62 0.63 0.6 0.57 0.58 0.56 0.31
0.16 0.275 0.136 0.123 0.185
N N N N N
0.1
N
945 945 945 945 945 1082 1082 1082 1082 1028 852 852 187
0.31
References page II - 290
TABLE 1. cont'd Monomer 1 Methacrylic Methacrylic Methacrylic Methacrylic Methacrylic Methacrylic Methacrylic Methacrylic
Monomer 2 acid acid acid acid acid acid acid acid
Methacrylic acid Methacrylic Methacrylic Methacrylic Methacrylic Methacrylic
acid acid acid acid acid
Methacrylic Methacrylic Methacrylic Methacrylic Methacrylic Methacrylic Methacrylic Methacrylic Methacrylic Methacrylic Methacrylic Methacrylic Methacrylic Methacrylic Methacrylic Methacrylic Methacrylic Methacrylic Methacrylic Methacrylic Methacrylic Methacrylic Methacrylic Methacrylic Methacrylic Methacrylic Methacrylic Methacrylic Methacrylic Methacrylic Methacrylic
acid acid acid acid acid acid acid acid acid acid acid acid acid acid acid acid acid acid acid acid acid acid acid acid acid acid acid acid acid acid acid
Methacrylic Methacrylic Methacrylic Methacrylic Methacrylic Methacrylic Methacrylic Methacrylic Methacrylic Methacrylic Methacrylic Methacrylic Methacrylic Methacrylic Methacrylic Methacrylic
acid acid acid acid acid acid acid acid acid acid acid acid acid acid acid acid
rx
Acrylate, ethyl Acrylic acid, 2-ethyl 1.12 Acrylic acid, 2-ethyl 2.29 Acrylic acid, 2-ethyl 1.14 Acrylonitrile 0.2 Acrylonitrile 2.38 Butadiene, 2-chloro-0.035 Diphenyl sulfone, 0.564 3,3 '-bisitaconimido-m,ra 'Maleimide, 2,3-dimethyl0.746 AH2-methacryl) Methacrylamide 2.73 Methacrylamide 1.55 Methacrylamide 2.006 Methacrylate, 2-hydroxypropyl 0.99 Methacrylate, N-methyl-N-phenyl2.16 2-amino Methacrylate, butyl 0.8 Methacrylate, butyl 0.73 Methacrylate, diethylaminoethyl 0.63 Methacrylate, ethyl 0.57 Methacrylate, glycidyl 0.98 Methacrylate, isopropyl 2.01 Methacrylate, methyl 0.25 Methacrylate, methyl 1.06 Methacrylate, methyl 0.33 Methacrylate, methyl 0.63 Methacrylate, methyl 0.46 Methacrylate, methyl 1.06 Methacrylate, methyl 0.33 Methacrylate, methyl 0.63 Methacrylate, methyl 2.16 Methacrylate, methyl 1.63 Methacrylate, methyl 0.99 Methacrylate, methyl 1.18 Methacrylate, methyl 0.48 Methacrylate, methyl 1.84 Methacrylate, methyl 1.38 Methacrylate, methyl 0.63 Methacrylate, methyl 1.55 Methacrylate, methyl 1.26 Methacrylate, methyl 0.78 Methacrylate, methyl 0.68 Methacrylate, phenyl 0.211 Methacrylate, phenyl 0.398 Methacrylate, sodium (2-sulphoxyethyl)- 0.78 Methacrylate, sulfolanyl 0.81 Methacrylate, tetra(21.56 hydroxypropyl)ethylenediamine Methacrylonitrile 1.74 Methacrylonitrile 0.54 7V-Vinylimidazole 1.384 Phosphonate, vinyl-, diethyl 1.9 Phosphonic acid, a-phenylvinyl1.49 Piperylene, cis0.4 Piperylene, trans0.38 Propene, 2,3-dichloro4 Propene, 2-chloro-3-hydroxy4.5 Pyridine, 2-methy 1-5-vinyl0.43 Pyridine, 2-vinyl0.58 Pyridine, 2-vinyl0.44 Styrene 0.55 Styrene 0.64 Styrene 0.66 Styrene 0.49
±95%
r2
±95%
Conv.
Refs. 1065 1004 1004 961 16 216 259 1042
0.027 0.04
0.26 0.29 0.058 0.032
0.194 0.069 0.23 0.04 0.092 2.52 0.015
0.13 0.06 0.2 0.058
N Y Y Y Y Y Y Y
0.059
1.33
0.1
Y
619
0.28
0.33 1.28 0.2 0.31 0.2
0.25
Y
0.014
Y
0.01
N
190 527 55 886 651
0.12 0.12 1.59
N N Y
0.1
N
0.03 0.01 0.03 0.02 0.03 0.01 0.03 0.02 0.05 0.16 0.23 0.04 0.1 0.05 0.08
N N Y N N N N
0.05
Y
0.17 0.081 0.19 0.24 0.181
Y Y N N Y
0.07 0.32 0.022
N N Y
0.3
Y
0.71
Y
0.02
N
0.04
N
0.132 0.417
0.09 0.18 0.16 0.2 1.47 0.16 0.05 0.02 0.02 0.02 0.03 0.02 0.02 0.02 0.28 6.25 0.55 0.19 0.1 0.24 0.27 0.2 0.018 0.019 0.08 0.03 0.237 0.1 3.71 0.034 0.16
0.21 0.66 0.08
1.26 1.15 2.34 0.71 1.2 0.47 0.63 0.1 0.78 0.31 0.27 0.1 0.78 0.32 0.87 1.81 0.56 0.29 1.28 0.77 0.36 1.18 0.55 0.209 1.25 0.48 1.89 0.589 1.2 0.81 0.328 0.64 0.52 0.145 0.15 0.17 0.38 0.33 0 0 0.85 1.69 1.38 0.21 0.22 0.2 0.15
187 224 16 820 224 847 1071 1072 1072 1072 1072 1087 1087 1087 203 210 216 276 276 312 313 313 424 54 630 819 88 88 745 359 996 44 85 879 431 130 773 773 445 445 552 15 498 166 166 203 312
TABLE 1. cont'd Monomer 1 Methacrylic Methacrylic Methacrylic Methacrylic Methacrylic Methacrylic Methacrylic Methacrylic Methacrylic Methacrylic Methacrylic Methacrylic Methacrylic Methacrylic
Monomer 2 acid acid acid acid acid acid acid acid acid acid acid acid acid acid
Methacrylic acid Methacrylic acid Methacrylic acid Methacrylic Methacrylic Methacrylic Methacrylic Methacrylic Methacrylic
acid acid acid acid acid acid
Methacrylic acid Methacrylic anhydride Methacrylic anhydride Methacrylic anhydride Methacrylic anhydride Methacrylic anhydride Methacrylic anhydride Methacrylic anhydride Methacrylic anhydride Methacrylic anhydride Methacrylonitrile Methacrylonitrile Methacrylonitrile Methacrylonitrile Methacrylonitrile Methacrylonitrile Methacrylonitrile Methacrylonitrile Methacrylonitrile Methacrylonitrile Methacrylonitrile Methacrylonitrile Methacrylonitrile Methacrylonitrile Methacrylonitrile Methacrylonitrile Methacrylonitrile Methacrylonitrile Methacrylonitrile Methacrylonitrile Methacrylonitrile Methacrylonitrile Methacrylonitrile Methacrylonitrile Methacrylonitrile Methacrylonitrile Methacrylonitrile
Styrene Styrene Styrene Styrene Styrene Styrene Styrene Styrene Styrene Styrene, 3-methyl Styrene, 3-methyl Styrene, 3-methyl Styrene, o-chloroSulfonic acid, o-methacryloylaminobenzeneSulfonic acid, o-methacryloylaminobenzeneSulfonic acid,/7-methacryloylaminobenzeneSulfonic acid, p-methacryloylaminobenzeneVinyl acetate Vinyl chloride Vinyl chloride Vinyl chloride Vinyl, mono-, diethyleneglycol ether Vinylethynyl-4-piperidinol, 1,2,5-trimethyl Vinylidene chloride Acrylate, methyl Allyl chloroacetate Allylurea Methacrylate, methyl Methacrylonitrile Styrene Styrene Vinyl benzyl sulfide Vinyl chloroethyl ether Acenaphthalene Acetylene, phenylAcrolein Acrolein Acrolein, methylAcrolein, methylAcrolein, methylAcrylate, 1,1,5-trihydroperfluoroamyl Acrylate, a-chloro-, ethyl Acrylate, oc-cyano-, methyl Acrylate, oc-phenyl-, methyl Acrylic anhydride Acrylonitrile Allylbenzene Butadiene Ethylene 1,1-diphenylFumarate, diisopropyl Itaconate, dimethyl Methacrylate, butyl Methacrylate, ethyl Methacrylate, isobutyl Methacrylate, isopropyl Methacrylate, octyl Methacrylic acid Methacrylic acid Methacrylic anhydride Phosphonic acid, a-phenylvinyl-
rx 0.56 0.28 0.602 0.85 0.631 0.6 0.44 0.39 0.12 0.35 0.18 0.51 0.622 0.203
±95%
±95%
Conv.
Refs.
0.04
N
0.092
Y
0.146 0.249 0.089 0.199 0.118 0.08 0.02 0.01 0.058 0.067
0.2 0.38 0.124 0.17 0.041 0.067 0.627 0.55 0.221 0.06 0.33 0.42 0.101 0.217
0.03 0.046 0.031 0.06 0.048 0.03 0.02 0.01 0.034 0.122
Y Y Y Y Y
Y Y
313 313 47 812 842 842 842 842 842 1087 1087 1087 6 1006
0.188
0.076
0.523
0.195
Y
1006
0.156
0.081
1.08
0.338
Y
1006
0.155
0.052
1.65
0.27
Y
1006
0.008 0.02
Y Y
0.047
Y
0.13 0.17 0.02 0.06 0.01
Y Y N N N
0.033
Y Y
0.12
N
0.07
N
0.01
N
0.13 0.04 0.03 0.15 0.11
N N Y Y N
0.07 0.05 0.05 0.12 0.05 0.1 3.71 0.18
N N N N N N N N
0.2 23.52 23.26 9.05 0 0.4 3.368 4.75 29.76 29.01 1.58 1.45 0.27 0.33 0.97 0.15 0.78 1.17 1.2 0.41 0.45 0.45 1.03 0.45 0.18 0.19 0.42 1.67 16.24 0.053 0.48 85 1.26 0.56 0.46 0.74 0.43 0.75 0.64 0.52 0.26 2.24
0.19
r2
0.088
0.98 0.96
0.098 13 18.48 0.06 0.18 0.02 0.27
0.05 0.01
0.01 0.04 0.12 1.36 0.016 0.1 0.15 0.04 0.07 0.08 0.04 0.07 0.32 0.06
0.01 0.064 -0.022 0.07 2.2 0.05 0.154 0.16 -0.01 -0.06 0.22 0.26 0.13 0.1 - 0.048 2.38 0.04 0.68 0.72 1.78 1.25 1.25 0.14 2 0.15 0.25 1 0.43 -0.061 0.39 -0.45 0 0.28 0.75 0.83 0.68 0.94 0.61 1.74 0.54 1.45 0
377 135 229 46 831 734 6 275 106 106 275 219 219 275 106 106 575 648 208 446 208 587 589 809 638 143 143 219 198 351 257 143 1038 398 44 44 44 44 44 44 85 219 590
References page II - 290
Next Page TABLE 1.
cont'd
Monomer 1 Methacrylonitrile Methacrylonitrile Methacrylonitrile Methacrylonitrile Methacrylonitrile Methacrylonitrile Methacrylonitrile Methacrylonitrile Methacrylonitrile Methacrylonitrile Methacrylonitrile Methacrylonitrile Methacrylonitrile Methacrylophenone, aMethacrylophenone, aMethacryloxymethylpentamethyldisiloxane Methacryloxypropyltrimethoxysilane Methacryloyl chloride Methacryloyl chloride Methacryloyl chloride Methacryloyl chloride Methacryloyl chloride Methacryloyl fluoride Methacryloyl fluoride Methacryloyl fluoride Methacryloyl fluoride, perfluoroMethacryloyl isocyanate Methacryloyl-P-hydroxyethyl3,5-dinitrobenzoate Methacryloyl-P-hydroxyethyl3,5-dinitrobenzoate Methacryloyl-P-hydroxyethyl3,5-dinitrobenzoate Methacryloylacetone Methacryloylacetone Methacryloylacetone Methacryloyloxy, 2-benzoate methyl Methacryloyloxy, 2-benzoate methyl Methacryloyloxy, 2-benzoic acid methyl Methacryloyloxy, 2-benzoic acid Methacryloyloxy, 4-,2,2,6,6-tetramethylpiperidine Methacryloyloxy-, o-, benzoic acid Methacryloyloxy-, o-, benzoic acid Methylenebutyrolactone Methylenebutyrolactone Methylenebutyrolactone Methylenebutyrolactone Methyleneglutaronitrile, 2Methyleneglutaronitrile, 2Methyleneglutaronitrile, 2Methyleneglutaronitrile, 2Methyleneglutaronitrile, 2Methyleneglutaronitrile, 2Methyleneglutaronitrile, 2Myrcene Myrcene Myrcene N-N-Divinylaniline N-TV-Divinylaniline JV-JV-Divinylaniline N-N-Divinylaniline TV-N-Divinylaniline
Monomer 2
rx
Styrene Styrene Styrene Styrene Styrene Styrene Styrene, oc-methoxyStyrene, a-methylStyrene, ochloroVinyl acetate Vinyl cinnamate Vinylidene chloride Vinylidene chloride Methacrylate, methyl Methacrylate, methyl Methacrylate, 2-hydroxyethyl Styrene Acrylonitrile Methacrylate, methyl Methacrylate, methyl Pyrrolidone, N-vinylVinyl chloride Methacrylate, methyl Methacrylate, methyl Styrene Vinylidene fluoride Methacrylate, methyl Acrylate, Af-(2-hydroxyethyl)carbazolyl
0.41 0.42 0.28 0.21 0.25 0.21 0.83 0.21 0.86 12 4.6 2.43 2.38 0.11 0.119 0.33 0.58 2.8 0.2 0.2 0.58 2 0.43 0.9 0.164 0.02 0.35 0.08
Acrylate, N-(2-hydroxyethyl)carbazolyl Methacrylate, N-ethyl-3-hydroxymethylcarbazolyl Acrylonitrile Pyrrolidone, TV-vinylStyrene Methacrylate, N-methyl-JV-phenyl2-amino ethyl Styrene Methacrylate, Af-methyl-7V-phenyl2-amino ethyl Styrene Styrene Methacrylate, methyl Vinylchloride Acrylamide Acrylonitrile Methacrylate, methyl Styrene Butadiene Methacrylate, methyl Methacrylate, methyl Styrene Styrene Styrene Vinyl methyl ketone Methacrylate, methyl Styrene Styrene/7-fluoroAcrylonitrile Methacrylate, methyl Styrene Styrene, p-methylVinyl acetate
±95%
r2
±95%
Conv.
Refs.
0.026
0.37 0.38 0.43 0.34 0.25 0.34 - 0.02 0.15 0.78 0.01 0.15 0.3 0.36 1.79 1.74 0.97 0.36 0.35 0.45 0.45 0.05 0.3 0.405 0.53 0.069 7.6 0.75 1.04
1.364
0.018
0.334
0.022
Y
719
0.554
0.019
0.729
0.051
Y
701
3.74 5.66 1.66 1.11
0.22 0.4 0.16 0.18
0.01 0.008 0.067 0.55
0.004 0.004 0.007 0.04
Y Y Y N
339 339 339 651
0.48 2.6
0.02 0.08
0.27 0.2
0.04 0.01
N N
651 651
1.17 0.32
0.03
0.15 0.6
0.04
N
651 687
1.37 11.26 2.85 1.1 1.67 0.7
0.64 3.5
0.908 0.004 0.3 0.09 0.6 0.09
0.252 0.052
Y Y
0.12 0.12 -0.02 0.02 0.25 1.24 0.448 1.38 0.87 -0.006 0.005 0.033 0.06 3.99
0.74
1.36 1.27 0.42 0.5 0.85 5.05 0.256 0.891 0.362 0.246 1.06 5.38 6.15 0.058
0.28
N N
0.52
N
0.013 0.015 0.022 0.014 0.18 0.36 0.16 0.009
Y Y Y Y Y Y Y Y
938 938 746 745 746 746 196 196 196 196 196 512 512 1062 1062 1062 45 45 45 45 45
0.04
0.1 0.05 0.02 0.009
0.12 0.16 0.045
1.3
0.06 0.081 0.143 0.07 0.018 0.067 0.03 0.12
0.005
N
0.1 0.05 0.07 0.22
N N N Y
0.037 0.06 0.014
Y N Y
0.14
Y
311 311 542 707 75 835 143 542 44 75 200 781 781 798 798 822 951 580 591 593 599 432 617 660 660 669 944 702
